다중혈관 관상동맥 환자에서 y-문합을 이용하여 양쪽 내흉동맥만을 사용한 우회술의 조기 성적

[신간의 별자리x] 우리/미술, 그리고 ‘슬픔의 박물관’

The family of 2D transition metal carbides, carbonitrides and nitrides (collectively referred to as MXenes) has expanded rapidly since the discovery of Ti3C2 in 2011. The materials reported so far always have surface terminations, such as hydroxyl, oxygen or fluorine, which impart hydrophilicity to their surfaces. About 20 different MXenes have been synthesized, and the structures and properties of dozens more have been theoretically predicted. The availability of solid solutions, the control of surface terminations and a recent discovery of multi-transition-metal layered MXenes offer the potential for synthesis of many new structures. The versatile chemistry of MXenes allows the tuning of properties for applications including energy storage, electromagnetic interference shielding, reinforcement for composites, water purification, gas- and biosensors, lubrication, and photo-, electro- and chemical catalysis. Attractive electronic, optical, plasmonic and thermoelectric properties have also been shown. In this Review, we present the synthesis, structure and properties of MXenes, as well as their energy storage and related applications, and an outlook for future research. More than twenty 2D carbides, nitrides and carbonitrides of transition metals (MXenes) have been synthesized and studied, and dozens more predicted to exist. Highly electrically conductive MXenes show promise in electrical energy storage, electromagnetic interference shielding, electrocatalysis, plasmonics and other applications.

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2D metal carbides and nitrides (MXenes) for energy storage

On September 14, 2015 at 09:50:45 UTC the two detectors of the Laser Interferometer Gravitational-Wave Observatory simultaneously observed a transient gravitational-wave signal. The signal sweeps upwards in frequency from 35 to 250 Hz with a peak gravitational-wave strain of 1.0×10(-21). It matches the waveform predicted by general relativity for the inspiral and merger of a pair of black holes and the ringdown of the resulting single black hole. The signal was observed with a matched-filter signal-to-noise ratio of 24 and a false alarm rate estimated to be less than 1 event per 203,000 years, equivalent to a significance greater than 5.1σ. The source lies at a luminosity distance of 410(-180)(+160)  Mpc corresponding to a redshift z=0.09(-0.04)(+0.03). In the source frame, the initial black hole masses are 36(-4)(+5)M⊙ and 29(-4)(+4)M⊙, and the final black hole mass is 62(-4)(+4)M⊙, with 3.0(-0.5)(+0.5)M⊙c(2) radiated in gravitational waves. All uncertainties define 90% credible intervals. These observations demonstrate the existence of binary stellar-mass black hole systems. This is the first direct detection of gravitational waves and the first observation of a binary black hole merger.

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The Observation of Gravitational Waves from a Binary Black Hole Merger

Weyl and Dirac semimetals are three-dimensional phases of matter with gapless electronic excitations that are protected by topology and symmetry. As three-dimensional analogs of graphene, they have generated much recent interest. Deep connections exist with particle physics models of relativistic chiral fermions, and, despite their gaplessness, to solid-state topological and Chern insulators. Their characteristic electronic properties lead to protected surface states and novel responses to applied electric and magnetic fields. The theoretical foundations of these phases, their proposed realizations in solid-state systems, and recent experiments on candidate materials as well as their relation to other states of matter are reviewed.

Weyl and Dirac semimetals in three-dimensional solids

By means of first-principles calculations and crystal structure searching techniques, we predict that a new NaCaBi family crystallized into the ZrBeSi-type structure (\ie $P6_{3}/mmc$) are strong topological insulators (STIs). Taking $P6_{3}/mmc$ NaCaBi as an example, the calculated band structure indicates that there is a band inversion between two opposite-parity bands at the $\Gamma$ point. In contrast to the well-known Bi$_2$Se$_3$ family, the band inversion in the NaCaBi family has already occured even without spin-orbit coupling (SOC), giving rise to a nodal ring surrounding $\Gamma$ in the $k_z=0$ plane (protected by $M_z$ symmetry). With time reversal symmetry $(\cal T)$ and inversion symmetry $(\cal I)$, the spinless nodal-line metallic phase protected by $[{\cal TI}]^2=1$ is the weak-SOC limit of the spinful topological insulating phase. Upon including SOC, the nodal ring is gapped, driving the system into a STI. Besides inversion symmetry, the nontrivial topology of NaCaBi can also be indicated by $\bar{6}$ symmetry. More surprisingly, the SOC-induced band gap in NaCaBi is about 0.34 eV, which is larger than the energy scale of room temperature. Four other compounds (KBaBi, KSrBi, RbBaBi and RbSrBi) in the family are stable at ambient pressure, both in thermodynamics and lattice dynamics, even though the gaps of them are smaller than that of NaCaBi. Thus, they provide good platforms to study topological states both in theory and experiments.

Topological insulators in the NaCaBi family with large SOC gaps


 One of the greatest triumph of condensed matter physics in the past ten years is the classification of materials by the principle of topology. The existence of topological protected dissipationless surface state makes topological insulators great potential for applications and hotly studied. However, compared with the prosperity of strong topological insulators, theoretical predicted candidate materials and experimental confirmation of weak topological insulators (WTI) are both extremely rare. In this work, by combining systematic first principles calculation and angle-resolved photoemission spectroscopy (ARPES) measurements, we have studied the electronic structure of the dark surface of the WTI candidate Zintl Ba3Cd2Sb4 and another related material Ba3Cd2As4. The existence of two Dirac surface states (SSs) on specific side surfaces predicted by theoretical calculations and the observed two band inversions in the Brillouin zone give strong evidence to prove that the Ba3Cd2Sb4 is a WTI. The spectroscopic characterization of this Zintl Ba3Cd2N4 (N = As and Sb) family materials will facilitate the application of their novel topological properties.

Electronic Structure of the Weak Topological Insulator Candidate Zintl Ba3Cd2Sb4

The quadratic band crossing points (QBCPs) at the Fermi level in two dimensions have been proposed to be unstable under electron-electron interactions. The possible interaction-driven states include the quantum anomalous Hall (QAH) state and various nematic ordered states. In this paper, motivated by the discovery of ferromagnetic van der Waals layered metal-organic framework ${\mathrm{CrCl}}_{2}{(\mathrm{pyrazine})}_{2}$, we theoretically propose that a single layer of ${\mathrm{CrCl}}_{2}{(\mathrm{pyrazine})}_{2}$ might realize one or some of these interaction-driven states based on the QBCP protected by ${C}_{4}$ symmetry. By introducing short-range density-density type repulsion interactions into this system, we have found the phase diagram depending on different interaction ranges and strengths. The exotic phases include the staggered chiral flux state manifesting the QAH effect, the site-nematic insulator, and the site-nematic Dirac semimetal state. The QAH state is robust against perturbations breaking the QBCP but it is weakened by increasing temperature. The metal-organic framework is tunable by changing the transition-metal elements, which might improve the gap size and stability of this interaction-induced QAH state. 

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Interaction-driven topological phase transition in monolayer 
<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi mathvariant="normal">CrCl</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>
(pyrazine)
<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mrow 

RTGW2020: An efficient implementation of the multi-orbital Gutzwiller method with general local interactions

The quadratic band crossing points (QBCPs) at Fermi level in two-dimension have been proposed to be unstable under electron-electron interaction. The possible interaction driven states include quantum anomalous Hall (QAH) state and various nematic ordered states. In this work, motivated by the discovery of ferromagnetic van der Waals layered metal-organic framework CrCl 2 (pyrazine) 2 , we theoretically propose that the single layer of CrCl 2 (pyrazine) 2 might realize one or some of these interaction driven states based on the QBCP protected by C 4 symmetry. By introducing the short-range density-density type repulsion interactions into this system, we have found the phase diagram depending on diﬀerent interaction range and strength. The exotic phases include the staggered chiral ﬂux state manifesting QAH eﬀect, the site-nematic insulator and the site-nematic Dirac semimetal state. The QAH state is robust against perturbations breaking the QBCP but it is weakened by increasing temperature. The metal-organic framework is tunable by changing the transition-metal elements, which might improve the gap size and stability of this interaction induced QAH state.

Hongming Weng

Papers

Topological insulators in the NaCaBi family with large SOC gaps

Electronic Structure of the Weak Topological Insulator Candidate Zintl Ba3Cd2Sb4

Interaction-driven topological phase transition in monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi mathvariant="normal">CrCl</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math> (pyrazine) <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mrow

RTGW2020: An efficient implementation of the multi-orbital Gutzwiller method with general local interactions

Interaction Driven Topological Phase Transition in Monolayer CrCl$_2$(pyrazine)$_2$