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Malcolm L. H. Green

Researcher at University of Oxford

Publications -  800
Citations -  32440

Malcolm L. H. Green is an academic researcher from University of Oxford. The author has contributed to research in topics: Carbon nanotube & Cyclopentadienyl complex. The author has an hindex of 82, co-authored 800 publications receiving 31121 citations. Previous affiliations of Malcolm L. H. Green include Gas Technology Institute & University of Illinois at Urbana–Champaign.

Papers
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Journal ArticleDOI

Synthesis and electrochemistry of di-η5-cyclopentadienyltungsten(IV) and -molybdenum(IV) crown ether complexes

Enqin Fu, +3 more
- 01 Mar 1988 - 
TL;DR: In this article, the metalla-crown ether complex [W{SCH2(CH2OCH2)3CH2S}(η-C5H5)2] (M = Mo, 5; M = W, 6) were prepared by the reaction of the sodium salt of 4thiobenzo-15crown-5 with [M(∆, C5H 5)2Cl2] or 2, respectively.
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Synthesis, structure and reactivity of new low-valent mono(η-arene)niobium compounds

Malcolm L. H. Green, +3 more
- 01 Jan 1991 - 
TL;DR: The new compounds [Nb(η-C6H5Me)(PMe3)3] as discussed by the authors have been prepared and evidence for the anions are presented.
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Synthesis and reactions of η-cycloheptatrienyl derivatives of molybdenum

Malcolm L. H. Green, +3 more
- 01 Jan 1993 - 
TL;DR: An improved route to [Mo(η-C7H7)Mo(µ-X)3 was found which involves the reduction of MoCl5 with sodium amalgam in the presence of cycloheptatriene followed by thermolysis as discussed by the authors.
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Studies on bis(η-indenyl)niobium complexes

Malcolm L. H. Green, +1 more
- 01 Jan 1992 - 
TL;DR: In this paper, the activation barrier to olefin hydride exchange has been determined by coalescene methods to be ΔG‡= 70.0 ± 2 kJ mol−1 at 50 °C, which is significantly lower than that for the analogous η-C5H5 and ηC5Me5 complexes.
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Synthesis, reactions, and crystal structures of cyclo-η5-[1-(disubstituted methyl)cyclopentadienyl](η-arene)-molybdenum and -tungsten compounds

Malcolm L. H. Green, +4 more
- 01 Jan 1983 - 
TL;DR: In this paper, the arene rings of W(η-C6H5Me) and Mo( η-c6H6) are readily displaced by the fulvenes C5H4CR2(R = Me or Ph) giving the binuclear [Mo(Ω-PriC5H 4µ-Cl2]2 whose crystal structure has been determined and which is a convenient precursor to mono-cyclopentadienylmolybdenum derivatives.