M
Malcolm L. H. Green
Researcher at University of Oxford
Publications - 800
Citations - 32440
Malcolm L. H. Green is an academic researcher from University of Oxford. The author has contributed to research in topics: Carbon nanotube & Cyclopentadienyl complex. The author has an hindex of 82, co-authored 800 publications receiving 31121 citations. Previous affiliations of Malcolm L. H. Green include Gas Technology Institute & University of Illinois at Urbana–Champaign.
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Formation of an η2-formaldehyde compound from methanol and its hydrogenation giving methanol
TL;DR: Addition of methanol to W(PMe3)4(η2-CH2PMe2)H gives the η 2-formaldehyde derivative W(Me3),4( η2 -CH2O)H2 which reacts sequentially with dihydrogen forming initially the methoxyhydrido compound W(MMe3,4(OMe)H3 and then W(ME3, 4 )H4 accompanied by the production of MeOH.
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A comparison of the rates of intramolecular hydrogen migration in the molecules [Mo(η-C7H8)2]n+ to give [Mo(η-C7H7)(η-C7H9)]n+, n= 0 or 1: crystal structures of [Mo(η-C7H8)2], [Mo(η-C7H7)(η-C7H9)], and [Mo(η-C7H8)2][BF4]
TL;DR: In this paper, the crystal structures of molybdenum atoms with cycloheptatriene were determined and the isomerization of (7), (8), and (9) to (10) were shown to be clean, first-order, intramolecular processes.
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Arene–osmium chemistry: synthesis via osmium atoms of [Os(η6-C6H6)(η4-C6H6)],[{OS(η6-C6H3Me3-1,3,5)}2(µ-H)2{µ-CH(C6H3Me2-3,5)}], [{OS(η6-C6H3Me3-1,3,5)}2(µ-CHC6H3Me2-3,5)], and [{OS(η6-C6H6)}3{µ3-(CH2)3CH}(µ-H)3]. X-Ray crystal structure of [{Os(η6-C6H3Me3-1,3,5)}2(µ-CHC6H3Me2-3,5)]
TL;DR: In this paper, the crystal structure of [{Os(η6-C6H3Me3-1,3,5)}2{µ-CH(C6C3Me2-3, 5)} has been determined.
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One- and two-dimensional inorganic crystals inside inorganic nanotubes
Sung You Hong,Ronen Kreizman,Rita Rosentsveig,Alla Zak,Jeremy Sloan,Andrey N. Enyashin,Gotthard Seifert,Malcolm L. H. Green,Reshef Tenne +8 more
TL;DR: In this article, a new synthetic strategy is presented allowing the formation of one dimensional (1D) inorganic crystals or core-shell nanotubular structures by using multiwall WS2 nanotubes as host templates.
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Replacement of terminal and bridging oxo groups by phenylimido groups in (η-C5H5)OMo(μ-O)2OMo(η-C5H5) giving (η-C5H5)(NPh)Mo(μ-NPh)2Mo(NPh)(η-C5H5)
TL;DR: In this article, arylimido-substituted complex (η-C 5 H 5 )(NPh)Mo(μ-O) 2 MoO(η -C 5H 5 ) with excess phenylisocyanate at reflux in tetrahydrofuran yields the (nPh)NPhMo(mO 2 Mo(nPh)-2 Mo( nPh), which has been characterized by elemental analysis, and mass, IR and 1 H NMR spectra.