M
Matthew D. Sampson
Researcher at University of California, San Diego
Publications - 22
Citations - 3101
Matthew D. Sampson is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Catalysis & Electrocatalyst. The author has an hindex of 16, co-authored 22 publications receiving 2600 citations. Previous affiliations of Matthew D. Sampson include University of Chicago & Argonne National Laboratory.
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Journal ArticleDOI
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO2
Idan Hod,Matthew D. Sampson,Pravas Deria,Clifford P. Kubiak,Clifford P. Kubiak,Omar K. Farha,Omar K. Farha,Joseph T. Hupp,Joseph T. Hupp +8 more
TL;DR: In this article, electrophoretic deposition of thin films of an appropriately chosen metal-organic framework (MOF) material is an effective method for immobilizing the needed quantity of catalyst.
Journal ArticleDOI
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis
Matthew D. Sampson,An D. Nguyen,Kyle A. Grice,Curtis E. Moore,Arnold L. Rheingold,Clifford P. Kubiak +5 more
TL;DR: IR-SEC experiments under CO2/H(+) indicate that reduction of a Mn(I)-CO2H catalytic intermediate may be the cause of this unusual "over-reduction" required to initiate catalysis.
Journal ArticleDOI
Manganese as a Substitute for Rhenium in CO2 Reduction Catalysts: The Importance of Acids
Jonathan M. Smieja,Matthew D. Sampson,Kyle A. Grice,Eric E. Benson,Jesse D. Froehlich,Clifford P. Kubiak +5 more
TL;DR: When compared to the analogous Re catalysts, the Mn catalysts operate at a lower overpotential and exhibit similar catalytic activities.
Journal ArticleDOI
Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal-Organic Framework.
TL;DR: The Mn-incorporated MOF catalyst largely retained its crystallinity throughout prolonged catalysis and was successfully reused over several catalytic runs, exceeding that of the homogeneous reference systems.
Journal ArticleDOI
Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide
Christoph Riplinger,Matthew D. Sampson,Andrew M. Ritzmann,Clifford P. Kubiak,Emily A. Carter +4 more
TL;DR: This study employs quantum chemistry combined with continuum solvation and microkinetics to examine the mechanism of CO2 reduction by each catalyst and finds that, at their respective operating potentials, the Mn catalyst is predicted to take a different reaction route than the Re catalyst.