There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

Two organolead halide perovskite nanocrystals, CH3NH3PbBr3 and CH3NH3PbI3, were found to efficiently sensitize TiO2 for visible-light conversion in photoelectrochemical cells. When self-assembled on mesoporous TiO2 films, the nanocrystalline perovskites exhibit strong band-gap absorptions as semiconductors. The CH3NH3PbI3-based photocell with spectral sensitivity of up to 800 nm yielded a solar energy conversion efficiency of 3.8%. The CH3NH3PbBr3-based cell showed a high photovoltage of 0.96 V with an external quantum conversion efficiency of 65%.

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

Single-layer metal dichalcogenides are two-dimensional semiconductors that present strong potential for electronic and sensing applications complementary to that of graphene.

/pdf/electronics-and-optoelectronics-of-two-dimensional-2jbqr1unvw.pdf

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides.

Although gold is the subject of one of the most ancient themes of investigation in science, its renaissance now leads to an exponentially increasing number of publications, especially in the context of emerging nanoscience and nanotechnology with nanoparticles and self-assembled monolayers (SAMs). We will limit the present review to gold nanoparticles (AuNPs), also called gold colloids. AuNPs are the most stable metal nanoparticles, and they present fascinating aspects such as their assembly of multiple types involving materials science, the behavior of the individual particles, size-related electronic, magnetic and optical properties (quantum size effect), and their applications to catalysis and biology. Their promises are in these fields as well as in the bottom-up approach of nanotechnology, and they will be key materials and building block in the 21st century. Whereas the extraction of gold started in the 5th millennium B.C. near Varna (Bulgaria) and reached 10 tons per year in Egypt around 1200-1300 B.C. when the marvelous statue of Touthankamon was constructed, it is probable that “soluble” gold appeared around the 5th or 4th century B.C. in Egypt and China. In antiquity, materials were used in an ecological sense for both aesthetic and curative purposes. Colloidal gold was used to make ruby glass 293 Chem. Rev. 2004, 104, 293−346

Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.

To use solar irradiation or interior lighting efficiently, we sought a photocatalyst with high reactivity under visible light. Films and powders of TiO 2- x N x have revealed an improvement over titanium dioxide (TiO 2 ) under visible light (wavelength 2 has proven to be indispensable for band-gap narrowing and photocatalytic activity, as assessed by first-principles calculations and x-ray photoemission spectroscopy.

/pdf/visible-light-photocatalysis-in-nitrogen-doped-titanium-np6nklr9gh.pdf

Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides

The quest for economic, large-scale hydrogen production has motivated the search for new materials and device designs capable of splitting water using only energy from the sun. Here we introduce an all solution-processed tandem water splitting assembly composed of a BiVO4 photoanode and a single-junction CH3NH3PbI3 hybrid perovskite solar cell. This unique configuration allows efficient solar photon management, with the metal oxide photoanode selectively harvesting high energy visible photons, and the underlying perovskite solar cell capturing lower energy visible-near IR wavelengths in a single-pass excitation. Operating without external bias under standard AM 1.5G illumination, the photoanode–photovoltaic architecture, in conjunction with an earth-abundant cobalt phosphate catalyst, exhibits a solar-to-hydrogen conversion efficiency of 2.5% at neutral pH. The design of low-cost tandem water splitting assemblies employing single-junction hybrid perovskite materials establishes a potentially promising new...

All solution-processed lead halide perovskite-BiVO4 tandem assembly for photolytic solar fuels production

Encapsulation with a nC60 cluster shell facilitates capture of photogenerated electrons from CdSe quantum dots following visible light excitation. Electrophoretic deposition of CdSe−C60 composite clusters on optically transparent electrodes (OTE/SnO2) produce photoactive films that exhibit photoelectrochemical activity. The observed photoconversion efficiency (IPCE) of ∼4% is significantly greater than those observed with CdSe or nC60 films.

Quantum dot solar cells. Electrophoretic deposition of CdSe-C60 composite films and capture of photogenerated electrons with nC60 cluster shell.

Making Gold Nanoparticles Glow: Enhanced Emission from a Surface-Bound Fluoroprobe

The influence of single-walled carbon nanotube (SWCNT) architectures for facilitating charge transport in mesoscopic semiconductor films has been probed using a TiO2/Ru(II) trisbipyridyl complex system. Both transient absorption and emission measurements indicate that the SWCNT network in the film has no noticeable influence on the charge injection process from the excited Ru(II) trisbipyridyl complex into TiO2 particles. However, it plays an important role in improving the charge separation, as the rate of back electron transfer between the oxidized sensitizer (Ru(III)) and the injected electrons becomes slower in the presence of the SWCNT scaffold. The beneficial aspect of charge collection by SWCNT has been further explored by carrying out photoelectrochemical measurements. The dye-sensitized solar cells constructed using this SWCNT scaffold show an improvement in the photocurrent generation. However, this improvement in photocurrent generation is neutralized by a lower photovoltage as the apparent Fer...

Single-Walled Carbon Nanotube Scaffolds for Dye-Sensitized Solar Cells

A membrane electrode assembly (MEA) for hydrogen fuel cells has been fabricated using single-walled carbon nanotubes (SWCNTs) support and platinum catalyst. Films of SWCNTs and commercial platinum (Pt) black were sequentially cast on a carbon fiber electrode (CFE) using a simple electrophoretic deposition procedure. Scanning electron microscopy and Raman spectroscopy showed that the nanotubes and the platinum retained their nanostructure morphology on the carbon fiber surface. Electrochemical impedance spectroscopy (EIS) revealed that the carbon nanotube-based electrodes exhibited an order of magnitude lower charge-transfer reaction resistance (Rct) for the hydrogen evolution reaction (HER) than did the commercial carbon black (CB)-based electrodes. The proton exchange membrane (PEM) assembly fabricated using the CFE/SWCNT/Pt electrodes was evaluated using a fuel cell testing unit operating with H2 and O2 as input fuels at 25 and 60 °C. The maximum power density obtained using CFE/SWCNT/Pt electrodes as b...

Prashant V. Kamat

Papers

All solution-processed lead halide perovskite-BiVO4 tandem assembly for photolytic solar fuels production

Quantum dot solar cells. Electrophoretic deposition of CdSe-C60 composite films and capture of photogenerated electrons with nC60 cluster shell.

Making Gold Nanoparticles Glow: Enhanced Emission from a Surface-Bound Fluoroprobe

Single-Walled Carbon Nanotube Scaffolds for Dye-Sensitized Solar Cells

Single-wall carbon nanotube-based proton exchange membrane assembly for hydrogen fuel cells.