scispace - formally typeset
Search or ask a question

Showing papers by "Wan Ramli Wan Daud published in 2009"


Journal ArticleDOI
TL;DR: An overview on the possibilities for using the direct methanol fuel cell as portable electronic devices power source along with some views on current and future trends in DMFC development, economic analysis and presents the current problems and solutions by DMFC researchers are given.

670 citations


Journal ArticleDOI
TL;DR: In this paper, a Nafion-SiO 2 -PWA nanocomposite membrane using sol-gel reaction was synthesized to improve the performance of proton exchange membrane fuel cell.

124 citations


Journal ArticleDOI
TL;DR: In this paper, the performance of an integrated PV-wind hydrogen energy production system is described, which consists of photovoltaic array, wind turbine, PEM electrolyser, battery bank, hydrogen storage tank, and an automatic control system for battery charging and discharging conditions.

107 citations


Journal ArticleDOI
TL;DR: In this paper, a passive, air-breathing polymethyl methacrylate (PMMA) based single-cell and a multi-cell stack micro-direct methanol fuel cell with 1.0 cm 2 active area with a novel cathode plate structure and assembly layer are designed, fabricated and tested.

96 citations


Journal ArticleDOI
TL;DR: In this article, a compact pressure swing adsorption (CPSA) system was designed to produce purified hydrogen for use in fuel cell, which achieved the required specifications of hydrogen purity for fuel cell applications.

87 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the hydrogen demand in Peninsular Malaysia as a function of total vehicle numbers, average total distance traveled and vehicle fuel economy, and concluded that liquefied hydrogen produced by natural gas steam reforming and delivered via tanker trucks is the optimum hydrogen supply chain method due to the minimum cost.

72 citations


Journal ArticleDOI
TL;DR: In this article, the effect of drying air temperature and humidity on the drying kinetics of Lemon grass was investigated with a fixed air velocity of 1 m sec-1.5 msec.
Abstract: Problem statement: The thin- layer drying experiments were conducted to examine the effect of drying air temperature and humidity on the drying kinetics. Approach: A model to estimate the drying behavior of Lemon grass was developed). Results: Four different thin-layer drying models were compared with respect to their coefficient of determination (R2), Mean Bias Error (MBE) and Root Mean Square Error (RMSE). The one with highest (R2) and lowest (MBE) and (RMSE) was selected to better estimate the drying curves. Three temperatures (35, 45 and 55°C) and three humidities (30, 40 and 50%) were investigated with a fixed air velocity of 1 m sec-1. Conclusion/Recommendation: The increase in the drying air temperature increased the drying process and decreased the Equilibrium Moisture Content (EMC) of Lemon grass. The drying process decreased as the air humidity increases. The effect was less than that of the temperature. The EMC have high values with high relative humidity.

48 citations


Journal Article
TL;DR: The rate of substrate consumption in the anaerobic compartment indicated that Saccharomyces cerevisiae had the great potential to generate electrons, and maximum voltage generated in the microbial fuel cell was 0.39v.
Abstract: 2 Abstract: Biological fuel cell converts chemical energy exists in chemical bonds of organic substrates to electrical energy. The living cells in the anode chamber utilize substrate for the growth maintenance; as a result electrons are supplied. In this research paper, a dual chamber of microbial fuel cell was used. Several microorganisms such as Pseudomonas putida, Saccharomyces cerevisiae, Lactobacillus bulgaricus, Escherichia coli and Aspergillus niger were cultured in an anaerobic chamber for the generation of electrons. The system was started with initial glucose concentration of 30gl and the substrate consumption -1 was monitored for the incubation period of 48 hours. The rate of substrate consumption in the anaerobic compartment indicated that Saccharomyces cerevisiae had the great potential to generate electrons. Maximum voltage generated in the microbial fuel cell was 0.39v. The generated current was quite stable for the duration of 48 hours.

39 citations


Journal ArticleDOI
TL;DR: In this article, an experimental investigation was carried out at quasi-steady and relatively elevated wall temperatures to better represent industrial operation of spray drying, and the results indicated that lower wall surface energy does reduce the deposition of amorphous particles, further illustrating the applicability of this approach in industrial condition.

34 citations


Journal ArticleDOI
TL;DR: In this paper, the rheological behavior of Josapine pineapple juice with at various maturity stages was studied at a wide range of temperature (5 −65 °C) and concentration (4 −14 °Brix) using a rotational rheometer as the measuring system.
Abstract: The rheological behaviour of Josapine pineapple juice with at various maturity stages was studied at a wide range of temperature (5–65 °C) and concentration (4–14 °Brix) using a rotational rheometer as the measuring system. The results show that josapine pineapples juice demonstrated a Newtonian behavior and is influenced by maturity stage, temperature and concentration. The Arrhenius typed equation successfully describe the effect of temperature on the viscosity, on the other hand, the effect of concentration can be described better using exponential equation. Finally, an equation describing the combined effect of temperature and concentration on viscosity at different stages of maturity was successfully developed.

32 citations


Journal ArticleDOI
TL;DR: In this paper, a mathematical model was developed to evaluate moisture profiles of hydrogen and air flows in the flow field channels of both the anode and the cathode of a single fuel cell.

Journal ArticleDOI
TL;DR: Sun drying of ciku (Manilkara zapota) was carried out on different sample sizes to investigate the effects on drying kinetics as mentioned in this paper, and it was found that the maximum drying rates of sun-dried ciku decreased with larger product size.
Abstract: Sun drying of ciku (Manilkara zapota) was carried out on different sample sizes to investigate the effects on drying kinetics. It was found that the maximum drying rates of sun-dried ciku decreased with larger product size. Three sunny days are needed to dry the ciku slabs to an average final moisture content of 0.2 g H2O/g dry mass. The results showed that hardness and chewiness of the dried samples were significantly different (p 0.05) compared to fresh ciku slabs. In addition, sun-dried ciku retained a total polyphenol content (TPC) that was relatively low (p < 0.05) compared to fresh ciku.

Journal ArticleDOI
TL;DR: In this paper, the surface of diffusion layer (PTFE/C) and catalyst layer of electrode was analyzed using X-ray photoelectron spectroscopy and scanning electron microscopy.

Journal ArticleDOI
TL;DR: In this article, the effect of chamber aspect ratio and operating conditions on flow stability within a short form spray dryer without the inclusion of droplet injection was numerically investigated, and it was observed that changes in the expansion ratio primarily affect the amplitude of the 'noise' region in the frequency spectrum.
Abstract: This paper numerically investigated the effect of chamber aspect ratio and operating conditions on flow stability within a short form spray dryer without the inclusion of droplet injection. Extensive analysis using different mesh configurations led to a new finding on the effect of expansion ratio on flow stability. A larger expansion ratio produces a more stable flow, which is due to the limitation of the jet fluctuation by the outlet geometry constriction. However, the flow might not be completely steady as fluctuations are magnified at higher inlet velocities, which can be explained by the confined jet feed-back mechanism. Fast Fourier Transform (FFT) analysis of the computed instantaneous velocity at selected spatial locations in the chamber revealed the effect of the chamber expansion ratio on periodicity of the flow structure. It is observed that changes in the expansion ratio primarily affect the amplitude of the 'noise' region in the frequency spectrum.

Journal ArticleDOI
TL;DR: In this article, an unsteady-state model was developed for a liquid-feed Direct Methanol Fuel Cell (DMFC) delivery considering two-phase system considering mass and heat transport in the feed delivery system attached to the anode and cathode of the fuel cell.

Journal ArticleDOI
TL;DR: In this article, an examination of the aqueous solution solubility and batch crystallization kinetics of l-isoleucine at the 250 mL scale size under a poly-and isothermal process condition is presented.
Abstract: An examination of the aqueous solution solubility and batch crystallization kinetics of l-isoleucine at the 250 mL scale size under a poly- and isothermal process condition is presented. Solubility data determined are consistent with the existence of two l-isoleucine polymorphic forms, in which both forms have different solubility and they are enantiotropically related. These polymorphs (A and B) can be recovered at different cooling rates of cooling crystallization. Crystal characterization using optical microscopy, differential scanning calorimetry, X-ray powder diffraction, and Fourier transform IR microscopy confirm this polymorphic behavior. Polythermal crystallization kinetic studies revealed the crystallization temperature increases with cooling rate and solute concentration, which results in a decrease of the metastable zone width (MSZW) with a decreasing cooling/heating rate. The study also revealed that cooling rates affect the polymorph formation, where at cooling rates of 0.25−0.75 °C/min, for...

Journal ArticleDOI
TL;DR: In this paper, the effects of steam temperature and steam velocity on the quality of steam-dried EFB fibers were investigated and three quality parameters of the EFB fiber, the color, strength, and microstructure, were used to assess the changes in EFB fibre quality as a result of superheated steam drying.
Abstract: Conventional drying of the fibers from oil palm empty fruit bunches (EFB) using flue gas from diesel burners frequently causes browning and dust explosion. Replacing the drying medium with superheated steam is expected to improve the quality of EFB fibers as well as improve the safety of the dryer operation. In this study, the effects of steam temperature and steam velocity on the quality of steam–dried EFB fibers was investigated. The drying experiment was carried out at atmospheric pressure with steam superficial velocity in the range of 0.3 to 0.49 m s−1 and temperature in the range of 135 to 200°C. Three quality parameters of the EFB fibers, the color, strength, and microstructure, were used to assess the changes in EFB fiber quality as a result of superheated steam drying. The color of the EFB fiber was either improved or not significantly degraded. The strength of the superheated steam–dried EFB fibers was higher than that of undried and hot air–dried EFB fibers. The microstructure of fresh undried ...

Journal ArticleDOI
TL;DR: In this article, the performance of a solar-assisted chemical heat pump dryer has been studied under the meteorological conditions of Malaysia, where the reaction (CaCl 2 --NH 3 ) has been used in this study.
Abstract: The performance of a solar-assisted chemical heat pump dryer has been studied under the meteorological conditions of Malaysia. The system consists of four mean components: solar collector (evacuated tubes type), storage tank, solid--gas chemical heat pump (CHP) unit and dryer chamber. A solid--gas CHP unit consists of a reactor, condenser and evaporator. The reaction (CaCl 2 --NH 3 ) has been used in this study. A series of experiments have been performed on the system under varied conditions for two days. The maximum values of solar fraction from the experiments on clear and cloudy days are 0.713 and 0.322, respectively; whereas the coefficient of performance of CHP (COP-super-h) maximum values of 2 and 1.42 are obtained from the experiments on clear and cloudy days, respectively. The total system energy output from the experiment on a clear day is 51 kWh against 25 kWh on a cloudy day. Any reduction of energy at the condenser as a result of decrease in solar radiation will decrease the coefficient of performance as well as the efficiency of drying. Copyright The Author 2009. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oxfordjournals.org, Oxford University Press.

Journal Article
TL;DR: In this paper, the physical-mechanical properties of the pineapple fruit from the Josapine variety, namely the weight of the fruit (with and without peel), pulp to peel ratio, diameter of the whole fruit and length of the crown were studied using the standard method at seven stages of maturity during storage at 25°C and 52% (RH).
Abstract: The physico-mechanical properties data of fruits are important in the design of various handling, packing, and storage and transportation system. The physical-mechanical properties of pineapple fruit from the Josapine variety, namely the weight of the fruit (with and without peel), pulp to peel ratio, diameter of the whole fruit (with and without peel), at three different positions along the longitudinal axis of the fruit, length of the fruit (with and without peel) and the length of crown were studied using the standard method at seven stages of maturity during storage at 25°C and 52% (RH). The effect of fruit maturity on the firmness of each fruit at three different locations was measured using a cylindrical die of 6 mm in diameter with the Instron Universal Testing Machine. The results indicated that the average total weight of a single fruit is 886.86±49.67 g. The average pulp to peel ratio is 1.91. The average diameter (with and without peel) was 86.83±5.24 mm and 80.95±4.15 mm (top section), 100.77±3.84 mm and 90.19±3.73 mm (middle section) and 97.17±3.49 mm and 73.30±5.11 mm (bottom section), respectively. The average length of the fruit (with and without peel) was 126.65 mm and 113.64 mm, respectively. The average length of crown was 89.13 mm. The firmness of the fruits was found to decrease with the stage of maturity. These data are important in determining the optimum stage of maturity for fruit processing.

Journal ArticleDOI
TL;DR: In this article, the x-y robotic spraying technique developed in the Universiti Kebangsaan Malaysia is capable of fabricating various sizes of thickness and porosity of gas diffusion layer (GDL) used in the proton exchange membrane fuel cell (PEMFC), these parameters are obtained by varying the characteristic spray numbers of the robotic spraying machine.

01 May 2009
TL;DR: In this paper, a simulation has been done under the meteorological conditions of Malaysia, where the solar assisted chemical heat pump drying system for tropical region has been studied and the monthly efficiency for evacuated tube solar collector has been predicted to be between the range (59 - 64%) with the deference between mean collector temperature and ambient temperature 20 oC.
Abstract: Solar assisted chemical heat pump drying system for tropical region has been studied. A simulation has been done under the meteorological conditions of Malaysia. The system consists of four mean components, solar collector (evacuated tubes type), storage tank, chemical heat pump units and dryer chamber. The monthly efficiency for evacuated tube solar collector has been predicted to be between the range (59 - 64%) with the deference between mean collector temperature and ambient temperature 20 oC. The solar fraction as a function of solar collector area has been studied. It was found that as the collector area increases the loss increases and hence the solar fraction increases. A monthly coefficient of performance for heating (COP h ) for chemical heat pump has been predicted and the maximum value of 1.8 as function for solar collector area 10 m 2 and storage tank size 0.2 m 3 were found. Any reduction of energy at condenser as a result of the decrease in solar radiation which in the final decrease the coefficient of performance as well as decrease the efficiency of drying.

Journal ArticleDOI
TL;DR: In this article, a multimedia model was developed to predict the overall fate and transport of non-volatile organic chemicals (NVOCs) dynamic in the agro-ecosystem.



Journal Article
TL;DR: In this article, a multi-composition Cu-Zn-Al (CZA) catalyst system supported on aluminosilicate zeolite (ZSM-5) was prepared by the impregnation method.
Abstract: Multi-composition Cu-Zn-Al (CZA) catalyst system supported on aluminosilicate zeolite (ZSM-5) was prepared by the impregnation method. The experiments were performed by varying the metal composition using statistical experimental design method namely Simplex Centroid Design. A series of catalysts were prepared by varying the different metal content in the composition up to 15 % supported on 85% ZSM-5. BrunauerEmmett-Teller method (BET) was adopted to characterise the surface area of the prepared catalyst. The reduction properties of the catalyst were ascertained using temperature programmed reduction (TPR) technique. The CO adsorption capabilities of the catalysts at 60, 200, 225, 250, 275 and 300 °C have been investigated using chemisorption method. Xray diffraction (XRD) technique was adopted to evaluate the structure of the catalysts. The shape and morphology of the catalysts were analysed using scanning electron microscopy– energy dispersive x-ray (SEM-EDX). The multifunctional Cu, Zn and Al catalyst supported on ZSM-5 showed a high BET surface area of about 132 ~ 196 m 2 /g. The TPR profiles showed the occurrence of reduction in a temperature range of 230 – 260oC. The performance of the catalyst in stream reforming methanol (SRM) and auto thermal steam reforming methanol (ATRM) processes suggested that, a maximum hydrogen yield of 73.09 and 76.88 mol% could be obtained with Cu6Zn7Al2/ZSM-5 catalyst in SRM and



Journal ArticleDOI
TL;DR: In this paper, the effects of air temperature and product size on drying kinetics, retained total polyphenol content (TPC), hardness kinetics and total colour change (.E) of ciku (Manilkara zapota) were investigated.
Abstract: The effects of air temperature and product size on drying kinetics, retained total polyphenol content (TPC), hardness kinetics and total colour change (.E) kinetics of ciku (Manilkara zapota) were investigated. In addition, five terms of the theoretical model were used to estimate the effective diffusivity values during drying at temperatures from40OC to 70OC. The drying rates of dried ciku were increased with increasing temperature and decreasing product size. It was found that hardness of ciku dried at temperature higher than 60OC increased significantly, when the moisture content was reduced toless than 0.5 g H2O/g DM (dry basis). In terms of nutritional value, the retained total polyphenol content (TPC) of dried ciku in hot air drying also increasing with temperature. The highest retained TPC was 141 mg GAE/ 100g of samples, which can be obtained from drying at 70OC.

Patent
02 Jan 2009
TL;DR: In this paper, a compact pressure swing adsorption system for gas separation and purification, comprising an absorption chamber, means for pressurizing the ad-ption chamber with a gas stream fed by an inputting means; means for adsorbing impurity gas (58) from the gas stream (60) and conveying purified gas (56) to an outputting means, and means for depressurizing an adsorization chamber to regenerate absorbed impurity gases (58); and means that purging any remaining adsorbed impuritygas (58), by a purge gas
Abstract: A compact pressure swing adsorption system for gas separation and purification, comprising an absorption chamber, means for pressurizing the adsorption chamber with a gas stream (60) fed by an inputting means; means for adsorbing impurity gas (58) from the gas stream (60) and conveying purified gas (56) to an outputting means; means for depressurizing the adsorption chamber to regenerate absorbed impurity gas (58); and means for purging any remaining adsorbed impurity gas (58) by a purge gas (55); wherein the adsorption chamber comprises a plurality of separate cells, each cell having adsorbent bed (51, 52, 53, 54), and the inputting and outputting means are connected to each cell with means for switching between the cells so that only one cell at a time is connected to the inputting means and another cell is connected to the outputting means, by a network of pipes and valves (57).

Proceedings Article
24 Feb 2009
TL;DR: In this paper, a solar assisted chemical heat pump dryer has been designed, fabricated and tested under the meteorological conditions of Malaysia, and the performance of the system has been studied under the weather conditions.
Abstract: A solar assisted chemical heat pump dryer has been designed, fabricated and tested. The performance of the system has been studied under the meteorological conditions of Malaysia. The system consists of four mean components: solar collector (evacuated tubes type), storage tank, solid – gas chemical heat pump units and dryer chamber. A solid gas chemical heat pump unit consists of reactor, condenser and evaporator. The reaction used in this study (CaCL2-NH3). The maximum experimental value of the COP for the solid-gas chemical heat pump of 2 was found, and the total system energy output is 51 kWh over drying time about 9 hours. The results show that any reduction of energy at condenser as a result of a decrease in solar radiation which in the final decrease the coefficient of performance as well as decrease the efficiency of drying.