Central Electro Chemical Research Institute

About: Central Electro Chemical Research Institute is a facility organization based out in Karaikudi, Tamil Nadu, India. It is known for research contribution in the topics: Cyclic voltammetry & Electrocatalyst. The organization has 645 authors who have published 820 publications receiving 17826 citations. The organization is also known as: Central ElectroChemical Research Institute & CSIR-Central ElectroChemical Research Institute.

Precision and correctness in the evaluation of electrocatalytic water splitting: revisiting activity parameters with a critical assessment

Abstract: The number of research reports published in recent years on electrochemical water splitting for hydrogen generation is higher than for many other fields of energy research. In fact, electrochemical water splitting, which is conventionally known as water electrolysis, has the potential to meet primary energy requirements in the near future when coal and hydrocarbons are completely consumed. Due to the sudden and exponentially increasing attention on this field, many researchers across the world, including our group, have been exerting immense efforts to improve the electrocatalytic properties of the materials that catalyze the oxygen evolution reaction (OER) at the anode and the hydrogen evolution reaction (HER) at the cathode, aided by the recent revolutionary discovery of nanomaterials. However, the pressure on the researchers to publish their findings rapidly has caused them to make many unnoticed and unintentional errors, which is mainly due to lack of clear insight on the activity parameters. In this perspective, we have discussed the use and validity of ten important parameters, namely overpotential at a defined current density, iR-corrected overpotential at a defined current density, Tafel slope, exchange current density (j0), mass activity, specific activity, faradaic efficiency (FE), turnover frequency (TOF), electrochemically active surface area (ECSA) and measurement of double layer capacitance (Cdl) for different electrocatalytic materials that are frequently employed in both OER and HER. Experimental results have also been provided in support of our discussions wherever required. Using our critical assessments of the activity parameters of water splitting electrocatalysis, researchers can ensure precision and correctness when presenting their data regarding the activity of an electrocatalyst.

Origin of voltage decay in high-capacity layered oxide electrodes

Abstract: Although Li-rich layered oxides (Li1+xNiyCozMn1−x−y−zO2 > 250 mAh g−1) are attractive electrode materials providing energy densities more than 15% higher than today’s commercial Li-ion cells, they suffer from voltage decay on cycling. To elucidate the origin of this phenomenon, we employ chemical substitution in structurally related Li2RuO3 compounds. Li-rich layered Li2Ru1−yTiyO3 phases with capacities of ~240 mAh g−1 exhibit the characteristic voltage decay on cycling. A combination of transmission electron microscopy and X-ray photoelectron spectroscopy studies reveals that the migration of cations between metal layers and Li layers is an intrinsic feature of the charge–discharge process that increases the trapping of metal ions in interstitial tetrahedral sites. A correlation between these trapped ions and the voltage decay is established by expanding the study to both Li2Ru1−ySnyO3 and Li2RuO3; the slowest decay occurs for the cations with the largest ionic radii. This effect is robust, and the finding provides insights into new chemistry to be explored for developing high-capacity layered electrodes that evade voltage decay.

An overall aspect of electroless Ni-P depositions—A review article

Abstract: Literature on electroless Ni-P deposition, in recent decades, has dwelled primarily on surface engineering and corrosion-resistant applications. By contrast, we have many research articles devoted to the engineering aspects of the electroless Ni-P depositions and their technology. The present article deals with the development of electroless Ni-P bath, advantages and mechanisms of deposition, and applications of the Ni-P deposits. We also present a comparison of the properties of electroless Ni-P and Ni-B as well as the recent developments in nickel-phosphorous research. We attempt to review these in a detailed manner. We also briefly discuss the future developments of electroless Ni-P.

Effect of moisture absorption on the mechanical properties of randomly oriented natural fibers/polyester hybrid composite

Abstract: In this work, the variation of mechanical properties such as tensile, flexural, and impact strengths of roselle and sisal fibers hybrid polyester composite at dry and wet conditions were studied. The composites of roselle/sisal polyester-based hybrid composites with different weight% of fibers were prepared. Roselle and sisal fibers at a ratio of 1:1 had been incorporated in unsaturated polyester resin at various fiber lengths. When the fiber content and length of the roselle and sisal fibers were increased, the tensile and flexural strength of the composite increased. When the samples were subjected to moisture environment, decrease in tensile and flexural strength was observed. The maximum percentage of strength reductions in tensile and flexural strength were observed for the composites having the fiber length of 150 mm and 30 wt% fiber content. For impact strength, it was with the composites of 20 wt% and 150 mm at wet conditions compared to dry conditions. The percentage of strength reductions increased with fiber content and length in wet conditions. A scatter in the impact strength values was identified on both the conditions. The moisture absorption characteristics of the natural fibers are very important to produce the natural fiber hybrid composite materials with the positive hybrid effect. The experimental results are compared with theoretical and empirical or statistical results and found to be in good agreement.