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Showing papers by "Georgia Institute of Technology published in 1999"


Journal ArticleDOI
TL;DR: Routing protocols for ad hoc networks are examined by providing an overview of eight different protocols by presenting their characteristics and functionality, and then a comparison and discussion of their respective merits and drawbacks are provided.
Abstract: An ad hoc mobile network is a collection of mobile nodes that are dynamically and arbitrarily located in such a manner that the interconnections between nodes are capable of changing on a continual basis. In order to facilitate communication within the network, a routing protocol is used to discover routes between nodes. The primary goal of such an ad hoc network routing protocol is correct and efficient route establishment between a pair of nodes so that messages may be delivered in a timely manner. Route construction should be done with a minimum of overhead and bandwidth consumption. This article examines routing protocols for ad hoc networks and evaluates these protocols based on a given set of parameters. The article provides an overview of eight different protocols by presenting their characteristics and functionality, and then provides a comparison and discussion of their respective merits and drawbacks.

4,278 citations


Journal ArticleDOI
TL;DR: In this paper, the surface plasmon absorption of noble metal nanoparticles was studied and the effects of size, shape, and composition on the plasman absorption maximum and its bandwidth were discussed.
Abstract: The field of nanoparticle research has drawn much attention in the past decade as a result of the search for new materials. Size confinement results in new electronic and optical properties, possibly suitable for many electronic and optoelectronic applications. A characteristic feature of noble metal nanoparticles is the strong color of their colloidal solutions, which is caused by the surface plasmon absorption. This article describes our studies of the properties of the surface plasmon absorption in metal nanoparticles that range in size between 10 and 100 nm. The effects of size, shape, and composition on the plasmon absorption maximum and its bandwidth are discussed. Furthermore, the optical response of the surface plasmon absorption due to excitation with femtosecond laser pulses allowed us to follow the electron dynamics (electron−electron and electron−phonon scattering) in these metal nanoparticles. It is found that the electron−phonon relaxation processes in nanoparticles, which are smaller than t...

3,635 citations


Book
01 Jan 1999
TL;DR: In this paper, the authors propose a theory of immediacy, hypermediacy and remediation mediation and network of remediation networks of networked self conclusion for virtual reality mediated spaces.
Abstract: Part 1 Theory: immediacy, hypermediacy and remediation mediation and remediation networks of remediation. Part 2 Media: computer games digital photography photorealistic graphics digital art film virtual reality mediated spaces television the World Wide Web ubiquitous computing convergence. Part 3 Self: the remediated self the virtual self the networked self conclusion.

3,393 citations


Journal ArticleDOI
TL;DR: The authors argue that working memory capacity and fluid intelligence reflect the ability to keep a representation active, particularly in the face of interference and distraction, and discuss the relationship of this capability to controlled attention, and the functions of the prefrontal cortex.
Abstract: A study was conducted in which 133 participants performed 11 memory tasks (some thought to reflect working memory and some thought to reflect short-term memory), 2 tests of general fluid intelligence, and the Verbal and Quantitative Scholastic Aptitude Tests. Structural equation modeling suggested that short-term and working memories reflect separate but highly related constructs and that many of the tasks used in the literature as working memory tasks reflect a common construct. Working memory shows a strong connection to fluid intelligence, but short-term memory does not. A theory of working memory capacity and general fluid intelligence is proposed: The authors argue that working memory capacity and fluid intelligence reflect the ability to keep a representation active, particularly in the face of interference and distraction. The authors also discuss the relationship of this capability to controlled attention, and the functions of the prefrontal cortex.

2,582 citations


Journal ArticleDOI
TL;DR: In this paper, the size and temperature dependence of the plasmon absorption of 9, 15, 22, 48, and 99 nm gold nanoparticles in aqueous solution were studied.
Abstract: The size and temperature dependence of the plasmon absorption is studied for 9, 15, 22, 48, and 99 nm gold nanoparticles in aqueous solution. The plasmon bandwidth is found to follow the predicted behavior as it increases with decreasing size in the intrinsic size region (mean diameter smaller than 25 nm), and also increases with increasing size in the extrinsic size region (mean diameter larger than 25 nm). Because of this pronounced size effect a homogeneous size distribution and therefore a homogeneous broadening of the plasmon band is concluded for all the prepared gold nanoparticle samples. By applying a simple two-level model the dephasing time of the coherent plasmon oscillation is calculated and found to be less than 5 fs. Furthermore, the temperature dependence of the plasmon absorption is examined. A small temperature effect is observed. This is consistent with the fact that the dominant electronic dephasing mechanism involves electron−electron interactions rather than electron−phonon coupling.

2,480 citations


Journal ArticleDOI
05 Mar 1999-Science
TL;DR: The methods developed here have been applied to a nanobalance for nanoscopic particles and also to a Kelvin probe based on nanotubes, which indicates a crossover from a uniform elastic mode to an elastic mode that involves wavelike distortions in the nanotube.
Abstract: Static and dynamic mechanical deflections were electrically induced in cantilevered, multiwalled carbon nanotubes in a transmission electron microscope. The nanotubes were resonantly excited at the fundamental frequency and higher harmonics as revealed by their deflected contours, which correspond closely to those determined for cantilevered elastic beams. The elastic bending modulus as a function of diameter was found to decrease sharply (from about 1 to 0.1 terapascals) with increasing diameter (from 8 to 40 nanometers), which indicates a crossover from a uniform elastic mode to an elastic mode that involves wavelike distortions in the nanotube. The quality factors of the resonances are on the order of 500. The methods developed here have been applied to a nanobalance for nanoscopic particles and also to a Kelvin probe based on nanotubes.

1,834 citations


Journal ArticleDOI
23 Jun 1999
TL;DR: This work describes the construction of color models for skin and non-skin classes from a dataset of nearly 1 billion labelled pixels and suggests that color can be a more powerful cue for detecting people in unconstrained imagery than was previously suspected.
Abstract: The existence of large image datasets such as photos on the World Wide Web make it possible to build powerful generic models for low-level image attributes like color using simple histogram learning techniques. We describe the construction of color models for skin and non-skin classes from a dataset of nearly 1 billion labeled pixels. These classes exhibit a surprising degree of separability which we exploit by building a skin pixel detector that achieves an equal error rate of 88%. We compare the performance of histogram and mixture models in skin detection and find histogram models to be superior in accuracy and computational cost. Using aggregate features computed from the skin detector we build a remarkably effective detector for naked people. We believe this work is the most comprehensive and detailed exploration of skin color models to date.

1,746 citations



Journal ArticleDOI
TL;DR: In this paper, a linear relationship was found between the absorption maximum of the longitudinal plasmon resonance and the mean aspect ratio as determined from TEM and it was shown that such a linear dependence is also predicted theoretically.
Abstract: Gold nanorods with different aspect ratios are prepared in micelles by the electrochemical method and their absorption spectra are modeled by theory. Experimentally, a linear relationship is found between the absorption maximum of the longitudinal plasmon resonance and the mean aspect ratio as determined from TEM. It is shown here that such a linear dependence is also predicted theoretically. However, calculations also show that the absorption maximum of the longitudinal plasmon resonance depends on the medium dielectric constant in a linear fashion for a fixed aspect ratio. Attempts to fit the calculations to the experimental values indicate that the medium dielectric constant has to vary with the aspect ratio in a nonlinear way. Chemically, this suggests that the structure of the micelle capping the gold nanorods is size dependent. Furthermore, comparison with the results obtained for rods of different aspect ratios made by systematic thermal decomposition of the long rods further suggests that the medi...

1,539 citations


Journal ArticleDOI
TL;DR: In this article, temperature-programmed reaction studies of the catalyzed combustion of CO on size-selected small monodispersed Aun (n ≤ 20) gold clusters supported on magnesia, and first-principle simulations reveal the microscopic origins of the observed unusual catalytic activity, with Au8 being the smallest catalytically active size.
Abstract: While inert as bulk material, nanoscale gold particles dispersed on oxide supports exhibit a remarkable catalytic activity. Temperature-programmed reaction studies of the catalyzed combustion of CO on size-selected small monodispersed Aun (n ≤ 20) gold clusters supported on magnesia, and first-principle simulations, reveal the microscopic origins of the observed unusual catalytic activity, with Au8 found to be the smallest catalytically active size. Partial electron transfer from the surface to the gold cluster and oxygen-vacancy F-center defects are shown to play an essential role in the activation of nanosize gold clusters as catalysts for the combustion reaction.

1,355 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present a theoretical exploration of the construct of corporate entrepreneurship and identify the various dimensions of firm-level entrepreneurial orientation identified in the literature, and propose a theoretical analysis of these dimensions.
Abstract: This paper presents a theoretical exploration of the construct of corporate entrepreneurship. Of the various dimensions of firm-level entrepreneurial orientation identified in the literature, it is...

Proceedings ArticleDOI
01 May 1999
TL;DR: This work introduces the concept of context widgets that mediate betweent the environment and the application in the same way graphicalwidgets mediate between the user and the applications.
Abstract: Context-enabled applications are just emerging and promise richer interaction by taking environmental context into account. However, they are difficult to build due to their distributed nature and the use of unconventional sensors. The concepts of toolkits and widget libraries in graphical user interfaces has been tremendously successtil, allowing programmers to leverage off existing building blocks to build interactive systems more easily. We introduce the concept of context widgets that mediate between the environment and the application in the same way graphical widgets mediate between the user and the application. We illustrate the concept of context widgets with the beginnings of a widget library we have developed for sensing presence, identity and activity of people and things. We assess the success of our approach with two example context-enabled applications we have built and an existing application to which we have added context-sensing capabilities.

Journal ArticleDOI
TL;DR: In this article, a co-reduction of chlorauric acid HAuCl4 and silver nitrate AgNO3 with sodium citrate is used to form homogeneous gold−silver alloy nanoparticles.
Abstract: Gold−silver alloy nanoparticles with varying mole fractions are prepared in aqueous solution by the co-reduction of chlorauric acid HAuCl4 and silver nitrate AgNO3 with sodium citrate. As the optical absorption spectra of their solutions show only one plasmon absorption it is concluded that mixing of gold and silver leads to a homogeneous formation of alloy nanoparticles. The maximum of the plasmon band blue-shifts linearly with increasing silver content. This fact cannot be explained by a simple linear combination of the dielectric constants of gold and silver within the Mie theory. On the other hand, the extinction coefficient is found to decrease exponentially rather than linearly with increasing gold mole fraction xAu. Furthermore, the size distribution of the alloy nanoparticles is examined using transmission electron microscopy (TEM). High-resolution TEM (HRTEM) also confirms the formation of homogeneous gold−silver alloy nanocrystals.

Book ChapterDOI
01 Apr 1999
TL;DR: In this paper, the authors argue that individual differences in controlled processing represent differences in functioning of the dorsolateral prefrontal cortex (PFC) and associated structures mediate the controlled processing functions of working memory.
Abstract: FIVE CENTRAL FEATURES OF THE THEORY Working memory is a system consisting of those long-term memory traces active above threshold, the procedures and skills necessary to achieve and maintain that activation, and limited-capacity, controlled attention. The specific features of our model include: (1) Domain-free, limited-capacity controlled attention. (2) Domain-specific codes and maintenance (phonological loop and visuospatial sketchpad are two examples but the potential number of such codes is large). (3) Individual differences in both 1 and 2, but individual differences in capacity for controlled processing are general and possibly the mechanism for general fluid intelligence. Although people can, with practice and expertise, circumvent the abiding limitations of controlled attention in quite specific situations, the limitations reemerge in novel situations and even in the domain of expertise if the situation calls for controlled processing. (4) Limited-capacity, controlled processing is required for maintaining temporary goals in the face of distraction and interference and for blocking, gating, and/or suppressing distracting events. (5) The dorsolateral prefrontal cortex (PFC) and associated structures mediate the controlled processing functions of working memory. We also argue that individual differences in controlled processing represent differences in functioning of the PFC. A number of intellectual influences have served to shape our thinking about working memory (WM) and its evolution as a construct separate from that of short-term memory (STM).


Book ChapterDOI
TL;DR: The Aware Home project is introduced and some of the technology-and human-centered research objectives in creating the Aware Home are outlined, to create a living laboratory for research in ubiquitous computing for everyday activities.
Abstract: We are building a home, called the Aware Home, to create a living laboratory for research in ubiquitous computing for everyday activities. This paper introduces the Aware Home project and outlines some of our technology-and human-centered research objectives in creating the Aware Home.

Journal ArticleDOI
TL;DR: In this paper, a systematic experimental investigation of two-phase flow patterns in microchannels was the objective of this study, using air and water, experiments were conducted in circular micro channels with 1.1 and 1.45mm inner diameters, and in semi-triangular (triangular with one corner smoothed) cross-sections with hydraulic diameters 1.09 and 149mm.

Journal ArticleDOI
01 Aug 1999
TL;DR: In this article, current and proposed protocols for mobility management for public land mobile network (PLMN)-based networks, mobile Internet protocol (IP) wireless asynchronous transfer mode (ATM) and satellite networks are discussed in the context of the next evolutionary step of wireless communication networks.
Abstract: This paper describes current and proposed protocols for mobility management for public land mobile network (PLMN)-based networks, mobile Internet protocol (IP) wireless asynchronous transfer mode (ATM) and satellite networks. The integration of these networks will be discussed in the context of the next evolutionary step of wireless communication networks. First, a review is provided of location management algorithms for personal communication systems (PCS) implemented over a PLMN network. The latest protocol changes for location registration and handoff are investigated for mobile IP followed by a discussion of proposed protocols for wireless ATM and satellite networks. Finally, an outline of open problems to be addressed by the next generation of wireless network service is discussed.

Journal ArticleDOI
TL;DR: Edgebreaker improves upon the storage required by previously reported schemes, most of which can guarantee only an O(t log(t) storage cost for the incidence graph of a mesh of t triangles, and supports fully general meshes by using additional storage per handle and hole.
Abstract: Edgebreaker is a simple scheme for compressing the triangle/vertex incidence graphs (sometimes called connectivity or topology) of three-dimensional triangle meshes. Edgebreaker improves upon the storage required by previously reported schemes, most of which can guarantee only an O(t log(t)) storage cost for the incidence graph of a mesh of t triangles. Edgebreaker requires at most 2t bits for any mesh homeomorphic to a sphere and supports fully general meshes by using additional storage per handle and hole. For large meshes, entropy coding yields less than 1.5 bits per triangle. Edgebreaker's compression and decompression processes perform identical traversals of the mesh from one triangle to an adjacent one. At each stage, compression produces an op-code describing the topological relation between the current triangle and the boundary of the remaining part of the mesh. Decompression uses these op-codes to reconstruct the entire incidence graph. Because Edgebreaker's compression and decompression are independent of the vertex locations, they may be combined with a variety of vertex-compressing techniques that exploit topological information about the mesh to better estimate vertex locations. Edgebreaker may be used to compress the connectivity of an entire mesh bounding a 3D polyhedron or the connectivity of a triangulated surface patch whose boundary need not be encoded. The paper also offers a comparative survey of the rapidly growing field of geometric compression.

Journal ArticleDOI
TL;DR: In this article, the effective thermal conductivity, elastic modulus, and coefficient of thermal expansion of epoxy resins filled with ceramic fillers like silica, alumina, and aluminum nitride were determined.
Abstract: The effective thermal conductivity, elastic modulus, and coefficient of thermal expansion of epoxy resins filled with ceramic fillers like silica, alumina, and aluminum nitride were determined. The data obtained was compared with theoretical and semitheoretical equations in the literature that are used to predict the properties of two phase mixtures. It was found that Agari's model provided a good estimate of the composite thermal conductivity. The Hashin-Shtrikman lower bound for composite modulus fits the modulus data fairly well at low concentrations of the filler. Also, it was found that the coefficients of thermal expansion of the filled composites lie in between Schapery's upper and lower bounds. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 3396–3403, 1999

Journal ArticleDOI
TL;DR: The approach is to extend the standard hidden Markov model method of gesture recognition by including a global parametric variation in the output probabilities of the HMM states by forming an expectation-maximization (EM) method for training the parametric HMM.
Abstract: A method for the representation, recognition, and interpretation of parameterized gesture is presented. By parameterized gesture we mean gestures that exhibit a systematic spatial variation; one example is a point gesture where the relevant parameter is the two-dimensional direction. Our approach is to extend the standard hidden Markov model method of gesture recognition by including a global parametric variation in the output probabilities of the HMM states. Using a linear model of dependence, we formulate an expectation-maximization (EM) method for training the parametric HMM. During testing, a similar EM algorithm simultaneously maximizes the output likelihood of the PHMM for the given sequence and estimates the quantifying parameters. Using visually derived and directly measured three-dimensional hand position measurements as input, we present results that demonstrate the recognition superiority of the PHMM over standard HMM techniques, as well as greater robustness in parameter estimation with respect to noise in the input features. Finally, we extend the PHMM to handle arbitrary smooth (nonlinear) dependencies. The nonlinear formulation requires the use of a generalized expectation-maximization (GEM) algorithm for both training and the simultaneous recognition of the gesture and estimation of the value of the parameter. We present results on a pointing gesture, where the nonlinear approach permits the natural spherical coordinate parameterization of pointing direction.

Journal ArticleDOI
TL;DR: The Classroom 2000 project at the Georgia Institute of Technology as mentioned in this paper was the first large-scale experiment with a living, ubiquitous computing environment, and the results of extended evaluations of the effect of automated capture on the teaching and learning experience.
Abstract: One potentially useful feature of future computing environments will be the ability to capture the live experiences of the occupants and to provide that record to users for later access and review. Over the last three years, a group at the Georgia Institute of Technology has designed and extensively used a particular instrumented environment: a classroom that captures the traditional lecture experience. This paper describes the history of the Classroom 2000 project and provides results of extended evaluations of the effect of automated capture on the teaching and learning experience. There are many important lessons to take away from this long-term, large-scale experiment with a living, ubiquitous computing environment. The environment should address issues of scale and extensibility, it should continuously be evaluated for effectiveness, and the ways in which the environment both improves and hinders the activity that it aims to support—in our case, education—need to be understood and acted upon. In d escribing our experiences and lessons learned, we hope to motivate other researchers to take more seriously the challenge of ubiquitous computing—the creation and exploration of the everyday use of computationally rich environments.

Journal ArticleDOI
TL;DR: In this article, the authors used a commercial finite element (FE) code to study the propagation characteristics of ultrasonic waves in annular structures and demonstrated the potential of the FE method for problems when an analytical solution is not possible because of complicated component geometry.
Abstract: This paper reports on the application of guided waves techniques to nondestructively determine the structural integrity of engineering components. Specifically, this research uses a commercial finite element (FE) code to study the propagation characteristics of ultrasonic waves in annular structures. In order to demonstrate the accuracy of the proposed FE technique, the propagation of guided waves in a flat plate is examined first. Next, the propagation of guided waves in thick ring structures is investigated. Finally, these FE results are compared to analytical and experimental results. The results of this study clearly illustrate the effectiveness of using the FE method to model guided wave propagation problems and demonstrate the potential of the FE method for problems when an analytical solution is not possible because of “complicated” component geometry.

Journal ArticleDOI
TL;DR: Schapery and Park as discussed by the authors presented an approximate analytical interconversion method for linear viscoelastic material functions based on a Prony series representation using experimental data from selected polymeric materials.

Journal ArticleDOI
TL;DR: New convection models have been developed to predict clinical from platelet thrombosis in diseased arteries, and future hemodynamic studies should address the complex mechanics of flow-induced, large-scale wall motion and convection of semisolid particles and cells in flowing blood.
Abstract: The cardiovascular system is an internal flow loop with multiple branches circulating a complex liquid. The hallmarks of blood flow in arteries are pulsatility and branches, which cause wall stresses to be cyclical and nonuniform. Normal arterial flow is laminar, with secondary flows generated at curves and branches. Arteries can adapt to and modify hemodynamic conditions, and unusual hemodynamic conditions may cause an abnormal biological response. Velocity profile skewing can create pockets in which the wall shear stress is low and oscillates in direction. Atherosclerosis tends to localize to these sites and creates a narrowing of the artery lumen--a stenosis. Plaque rupture or endothelial injury can stimulate thrombosis, which can block blood flow to heart or brain tissues, causing a heart attack or stroke. This small lumen and elevated shear rate in a stenosis create conditions that accelerate platelet accumulation and occlusion. The relationship between thrombosis and fluid mechanics is complex, especially in the post-stenotic flow field. New convection models have been developed to predict clinical from platelet thrombosis in diseased arteries. Future hemodynamic studies should address the complex mechanics of flow-induced, large-scale wall motion and convection of semisolid particles and cells in flowing blood.


Journal ArticleDOI
TL;DR: Delivering a large number of mesenchymal stem cells to a wound site can significantly improve its biomechanical properties by only 4 weeks but produce no visible improvement in its microstructure.
Abstract: Mesenchymal stem cells (MSCs) were isolated from bone marrow of 18 adult New Zealand White rabbits. These cells were culture expanded, suspended in type I collagen gel, and implanted into a surgically induced defect in the donor s right patellar tendon. A cell-free collagen gel was implanted into an identical control defect in the left patellar tendon. Repair tissues were evaluated biomechanically (n = 13) and histomorphometrically (n = 5) at 4 weeks after surgery. Compared to their matched controls, the MSC-mediated repair tissue demonstrated significant increases of 26% (p < 0.001), 18% (p < 0. 01), and 33% (p < 0.02) in maximum stress, modulus, and strain energy density, respectively. Qualitatively, there appeared to be minor improvements in the histological appearance of some of the MSC- mediated repairs, including increased number of tenocytes and larger and more mature-looking collagen fiber bundles. Morphometrically, however, there were no significant left-right differences in nuclear aspect ratio (shape) or nuclear alignment (orientation). Therefore, delivering a large number of mesenchymal stem cells to a wound site can significantly improve its biomechanical properties by only 4 weeks but produce no visible improvement in its microstructure.

Journal ArticleDOI
TL;DR: This work significantly improves upon existing DP stereo matching methods by showing that while some cost must be assigned to unmatched pixels, sensitivity to occlusion-cost and algorithmic complexity can be significantly reduced when highly-reliable matches, or ground control points, are incorporated into the matching process.
Abstract: A method for solving the stereo matching problem in the presence of large occlusion is presented. A data structure—the disparity space image—is defined to facilitate the description of the effects of occlusion on the stereo matching process and in particular on dynamic programming (DP) solutions that find matches and occlusions simultaneously. We significantly improve upon existing DP stereo matching methods by showing that while some cost must be assigned to unmatched pixels, sensitivity to occlusion-cost and algorithmic complexity can be significantly reduced when highly-reliable matches, or ground control points, are incorporated into the matching process. The use of ground control points eliminates both the need for biasing the process towards a smooth solution and the task of selecting critical prior probabilities describing image formation. Finally, we describe how the detection of intensity edges can be used to bias the recovered solution such that occlusion boundaries will tend to be proposed along such edges, reflecting the observation that occlusion boundaries usually cause intensity discontinuities.

Journal ArticleDOI
TL;DR: Radiative transfer calculations suggest that regional haze in China is currently depressing optimal yields of approximately 70% of the crops grown in China by at least 5-30%, which could potentially result in a significant increase in crop yields and help the nation meet its growing food demands in the coming decades.
Abstract: The effect of atmospheric aerosols and regional haze from air pollution on the yields of rice and winter wheat grown in China is assessed. The assessment is based on estimates of aerosol optical depths over China, the effect of these optical depths on the solar irradiance reaching the earth’s surface, and the response of rice and winter wheat grown in Nanjing to the change in solar irradiance. Two sets of aerosol optical depths are presented: one based on a coupled, regional climate/air quality model simulation and the other inferred from solar radiation measurements made over a 12-year period at meteorological stations in China. The model-estimated optical depths are significantly smaller than those derived from observations, perhaps because of errors in one or both sets of optical depths or because the data from the meteorological stations has been affected by local pollution. Radiative transfer calculations using the smaller, model-estimated aerosol optical depths indicate that the so-called “direct effect” of regional haze results in an ≈5–30% reduction in the solar irradiance reaching some of China’s most productive agricultural regions. Crop-response model simulations suggest an ≈1:1 relationship between a percentage increase (decrease) in total surface solar irradiance and a percentage increase (decrease) in the yields of rice and wheat. Collectively, these calculations suggest that regional haze in China is currently depressing optimal yields of ≈70% of the crops grown in China by at least 5–30%. Reducing the severity of regional haze in China through air pollution control could potentially result in a significant increase in crop yields and help the nation meet its growing food demands in the coming decades.

Journal ArticleDOI
TL;DR: It is proposed that radical cations form self-trapped polarons that migrate by thermally activated hopping and falls off exponentially with distance from the quinone, necessitating reinterpretation of mechanisms proposed for radical cation migration in DNA.
Abstract: An anthraquinone-linked duplex DNA oligomer containing 60 base pairs was synthesized by PCR. The strand complementary to the quinone-containing strand has four isolated GG steps, which serve as traps for a migrating radical cation. Irradiation of the quinone leads to electron transfer from the DNA to the quinone forming the anthraquinone radical anion and a base radical cation. The radical cation migrates through the DNA, causing reaction at GG steps revealed as strand breaks. The efficiency of strand cleavage falls off exponentially with distance from the quinone (slope = −0.02 Å−1). This finding necessitates reinterpretation of mechanisms proposed for radical cation migration in DNA. We propose that radical cations form self-trapped polarons that migrate by thermally activated hopping.