Mexican Institute of Petroleum

About: Mexican Institute of Petroleum is a government organization based out in Mexico City, Mexico. It is known for research contribution in the topics: Catalysis & Asphaltene. The organization has 3273 authors who have published 4170 publications receiving 87269 citations.

Revisiting the phase diagram of hard ellipsoids

Abstract: In this work the well-known Frenkel-Mulder phase diagram of hard ellipsoids of revolution [Mol. Phys. 55, 1171 (1985)] is revisited by means of replica exchange Monte Carlo simulations. The method provides good sampling of dense systems and so, solid phases can be accessed without the need of imposing a given structure. At high densities, we found plastic solids and fcc-like crystals for semi-spherical ellipsoids (prolates and oblates), and SM2 structures [Phys. Rev. E 75, 020402 (2007)] for x:1-prolates and 1:x-oblates with x>=3. The revised fluid-crystal and isotropic-nematic transitions reasonably agree with those presented in the Frenkel-Mulder diagram. An interesting result is that, for small system sizes (100 particles), we obtained 2:1 and 1.5:1-prolate equations of state without transitions, while some order is developed at large densities. Furthermore, the symmetric oblate cases are also reluctant to form ordered phases.

Two perspectives on equipartition in diffuse elastic fields in three dimensions

Abstract: The elastodynamic Green function can be retrieved from the cross correlations of the motions of a diffuse field. To extract the exact Green function, perfect diffuseness of the illuminating field is required. However, the diffuseness of a field relies on the equipartition of energy, which is usually described in terms of the distribution of wave intensity in direction and polarization. In a full three dimensional (3D) elastic space, the transverse and longitudinal waves have energy densities in fixed proportions. On the other hand, there is an alternative point of view that associates equal energies with the independent modes of vibration. These two approaches are equivalent and describe at least two ways in which equipartition occurs. The authors gather theoretical results for diffuse elastic fields in a 3D full-space and extend them to the half-space problem. In that case, the energies undergo conspicuous fluctuations as a function of depth within about one Rayleigh wavelength. The authors derive diffuse energy densities from both approaches and find they are equal. The results derived here are benchmarks, where perfect diffuseness of the illuminating field was assumed. Some practical implications for the normalization of correlations for Green function retrieval arise and they have some bearing for medium imaging.

Coke Characterization on Pt/Al2O3−β-Zeolite Reforming Catalysts

Abstract: The amount and nature of carbon deposits on platinum catalysts supported on a mixture of alumina−β-zeolite, non neutralized and neutralized with cesium, were investigated and compared with those of...