Warsaw University of Technology

About: Warsaw University of Technology is a education organization based out in Warsaw, Poland. It is known for research contribution in the topics: Microstructure & Optical fiber. The organization has 14293 authors who have published 34362 publications receiving 492211 citations. The organization is also known as: Warsaw Polytechnic & Politechnika Warszawska.

Centrality dependence of the nuclear modification factor of charged pions, kaons, and protons in Pb-Pb collisions at √sNN=2.76 TeV

Abstract: Transverse momentum (pT) spectra of pions, kaons, and protons up to pT=20GeV/c have been measured in Pb-Pb collisions at √sNN=2.76TeV using the ALICE detector for six different centrality classes covering 0%–80%. The proton-to-pion and the kaon-to-pion ratios both show a distinct peak at pT≈3GeV/c in central Pb-Pb collisions that decreases for more peripheral collisions. For pT>10GeV/c, the nuclear modification factor is found to be the same for all three particle species in each centrality interval within systematic uncertainties of 10%–20%. This suggests there is no direct interplay between the energy loss in the medium and the particle species composition in the hard core of the quenched jet. For pT<10GeV/c, the data provide important constraints for models aimed at describing the transition from soft to hard physics.

Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts: A Further Step toward an Optimum Balance between Antinomic Properties

Abstract: A 95% yield in the cross metathesis of acrylonitrile with a model olefin is achieved at 25 °C with only 3 mol % of the new air-stable ruthenium catalyst 1f shown in the enclosed structural diagram. Even more remarkable are the performances of its boosted version 1g incorporating an electron-withdrawing group. Both these new enhanced versions of Hoveyda catalyst are readily available from Grubbs second generation precatalyst upon reaction with a styrenyl ether the end group of which has been functionalized by an ester function. The latter acts as a weakly coordinating ligand allowing to reach a desirable balance between antinomic properties such as the catalyst's stability, a high activity for challenging substrates, and a high initiation rate.