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Showing papers in "Acta Metallurgica Sinica (english Letters) in 2007"


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the high temperature oxidation behavior of FGH96 P/M superalloy in air at temperatures ranging from 600 to 1000°C by means of isothermal oxidation testing X-ray diffraction, SEM (scanning electron microscopy), and EDS (energy dispersive Xray spectroscopy) analyses, the oxidation kinetics as well as the composition and morphology of scales were investigated.
Abstract: High temperature oxidation behaviors of FGH96 P/M superalloy have been studied in air at temperatures ranging from 600 to 1000°C By means of isothermal oxidation testing X-ray diffraction, SEM (scanning electron microscopy), and EDS (energy dispersive X-ray spectroscopy) analyses, the oxidation kinetics as well as the composition and morphology of scales were investigated Thermodynamic calculations were used to explain the oxidation mechanism The results showed that as the oxidation temperature increased, the oxidation rate, the scale thickness, and scale spallation increased FGH96 P/M superalloy exhibits good oxidation resistance at temperature below 800°C The oxidation kinetics follows an approximately parabolic rate law, and the oxide layer was mainly composed of Cr 2 O 3 , TiO 2 , and a little amount of NiCr 2 O 4 The oxidation is controlled by the transmission of chromium, titanium, and oxygen through the oxide scale

36 citations


Journal ArticleDOI
Lei Zhang1, J.B. Pei1, Q.Z. Zhang1, C.D. Liu1, W.H. Zhu, S. Qu, Jun Wang 
TL;DR: In this article, the transient temperature distribution during the inertia friction welding process of two similar workpieces of GH4169 alloy is calculated and the temperature at some position near the welding interface was measured using this system.
Abstract: The inertia friction welding process is a non-linear process because of the interaction between the temperature field and the material properties as well as the friction force. A thermo-mechanical coupled finite element model is established to simulate the temperature field of this process. The transient temperature distribution during the inertia friction welding process of two similar workpieces of GH4169 alloy is calculated. The region of the circular cross-section of the workpiece is divided into a number of four-nodded isoparametric elements. In this model, the temperature dependent thermal properties, time dependent heat inputs, contact condition of welding interface, and deformation of the flash were considered. At the same time, the convection and radiation heat losses at the surface of the workpieces were also considered. A temperature data acquisition system was developed. The temperature at some position near the welding interface was measured using this system. The calculated temperature agrees well with the experimental data. The deformation of the flash and the factor affecting the temperature distribution at the welding interface are also discussed.

28 citations


Journal ArticleDOI
TL;DR: In this paper, the precipitation behavior of M 2 N and the microstructural evolution in a Cr-Mn austenitic stainless steel with a high nitrogen content of 0.43mass% during isothermal aging has been investigated using optical microscopy (OM), scanning electron microscopy, and transmission electron microscope (TEM).
Abstract: The precipitation behavior of M 2 N and the microstructural evolution in a Cr-Mn austenitic stainless steel with a high nitrogen content of 0.43mass% during isothermal aging has been investigated using optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The aging treatments have led to the decomposition of nitrogen supersaturated austenitic matrix through discontinuous cellular precipitation. The precipitated cells comprise alternate lamellae of M 2 N precipitate and austenitic matrix. This kind of precipitate morphology is similar to that of pearlite. However, owing to the non-eutectoidic mechanism of the reaction, the growth characteristic of the cellular precipitates is different from that of pearlite in Fe-C binary alloys. M 2 N precipitate in the cell possesses a hexagonal crystal structure with the parameters a = 0.4752nnm and c = 0.4429nm, and the orientation relationship between the M 2 N precipitates and austenite determined from the SADP is [0110] M2N //[101]γ, [2110] M2N //[010]γ,

25 citations


Journal ArticleDOI
TL;DR: In this paper, the effects of transformation of slag composition and additive agents on the morphology, the precipitation behavior, the crystal growth, and the volume fraction of perovskite (CaO·TiO2) crystal in the Ti-bearing blast furnace slags were investigated.
Abstract: The effects of transformation of slag composition and additive agents on the morphology, the precipitation behavior, the crystal growth, and the volume fraction (VF) of perovskite (CaO·TiO2) crystal in the Ti-bearing blast furnace slags were investigated As the morphology of perovskite is dispersed in molten slags, the crystal growth mechanism of the melting of fine dendrites and the coarsening of large grains exist throughout the solidification of molten slags With the increase of CaO and Fe2O3 content, VF of perovskite obviously increases However, high basicity leads to the viscosity of slag, which results in the reduction of the average equivalent diameter (AED) The experimental results showed that the presence of the additives CaF2 and MnO efficiently decreased the viscosity of the slags, and obviously improved the morphology of perovskite and promoted its growth

23 citations


Journal ArticleDOI
S.Y. Gao1, Y.Z. Zhang, L.K. Shi, B.L. Du1, M.Z. Xi, H.Z. Ji1 
TL;DR: In this paper, the effect of the laser scanning track on the internal soundness of the deposited part was discussed and the mechanical properties of the Ti-6Al-4V alloy, fabricated by LDD, were obtained using the tension test, and the oxygen content of used powders and deposited specimens were measured.
Abstract: Laser direct deposition (LDD) of metallic components is an advanced technology of combining CAD/CAM (computer aided design/computer aided manufacturing), high power laser, and rapid prototyping. This technology uses laser beam to melt the powders fed coaxially into the molten pool by the laser beam to fabricate fully dense metallic components. The present article mainly studies the LDD of Ti-6Al-4V alloy, which can be used to fabricate aircraft components. The mechanical properties of the Ti-6Al-4V alloy, fabricated by LDD, are obtained using the tension test, and the oxygen content of used powders and deposited specimens are measured. In the present article, it can be seen that the mechanical properties obtained using this method are higher than the ones obtained by casting, and equal to those got by wrought anneal. One aircraft part has been made using the LDD process. Because of this aircraft part, with sophisticated shape, the effect of the laser scanning track on the internal soundness of the deposited part was discussed.

18 citations


Journal ArticleDOI
TL;DR: In this paper, a traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed.
Abstract: Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K 2 CrO 4 and Fe 2 O 3 , increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.

18 citations


Journal ArticleDOI
TL;DR: In this article, laser cladded coatings of TiCN were produced on the surface of titanium and the results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings.
Abstract: Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs (OM). The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm/s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm−2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2, and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80μm, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.

16 citations


Journal ArticleDOI
TL;DR: In this paper, the influence of cold rolling reduction on microstructure and mechanical properties of the TWIP (ttwinning induced plasticity) steel was investigated, and the results indicated that the steel had better comprehensive mechanical properties when cold-rolling reduction was about 65.0% and the annealing temperature was 1000°C.
Abstract: The influence of cold rolling reduction on microstructure and mechanical properties of the TWIP (ttwinning induced plasticity) steel was investigated. The results indicated that the steel had better comprehensive mechanical properties when cold rolling reduction was about 65.0% and the annealing temperature was 1000°C. The tensile strength of the steel is about 640MPa and the yield strength is higher than 255MPa, while the elongation is above 82%. The microstructure is composed of austenitic matrix and annealing twins at room temperature, at the same time, a significant amount of annealing twins and stacking faults are observed by transmission electron microscopy (TEM). Mechanical twins play a dominant role during deformation, and result in excellent mechanical properties.

15 citations


Journal ArticleDOI
TL;DR: In this paper, the effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated.
Abstract: The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lucke.

15 citations


Journal ArticleDOI
TL;DR: In this paper, a magnetic state equation of the MnFeP0.45As0.55 compound has been obtained by minimizing the Gibbs free energy with respect to the volume and the magnetization based on the Bean-Rodbell model.
Abstract: A magnetic state equation of the MnFeP0.45As0.55 compound has been obtained by minimizing the Gibbs free energy with respect to the volume and the magnetization based on the Bean-Rodbell model. The isothermal magnetization of the compound has been calculated using this equation. The magnetic entropy change of the compound was determined from the surface area between the two adjacent isothermal magnetization curves divided by the average temperature. A comparison and an error analysis of the calculated magnetic entropy change and the one determined from the experimental data were given.

15 citations


Journal ArticleDOI
TL;DR: In this paper, a two-dimensional transient coupled finite element model has been developed to compute the temperature and stress profile in beam blank continuous casting, where the enthalpy method was used in the heat conduction equation.
Abstract: The aim of this study was to simulate the solidification process of beam blank continuous casting, and then find the reasons for the typical defects of the beam blank. A two-dimensional transient coupled finite element model has been developed to compute the temperature and stress profile in beam blank continuous casting. The enthalpy method was used in the heat conduction equation. The thermo-mechanical property in the mushy zone was taken into consideration in this calculation. It is shown that at the mold exit the thickness of the shell had its maximum value at the flange tip and its minimum value at the fillet. The temperature had a great fluctuation on the surface of the beam blank in the secondary cooling zone. At the unbending point, the surface temperature of the web was in the brittleness temperature range under the present condition. To ensure the quality, it is necessary to weaken the intensity of secondary cooling. At the mold exit the equivalent stress and strain have higher values at the flange tip and at the web. From the spray 1 to the unbending point, the maximum values of stress and strain gradually moved to the internal section of the flange tip and the web. However, whenever, there were bigger stress and strain values near the flange tip and the web than in the other parts, it must be very easy to generate cracks at those positions. Now, online verification of this simulation has been developed, which has proved to be very useful and efficient to instruct the practical production of beam blank continuous casting.

Journal ArticleDOI
TL;DR: In this article, the possibilities of the fuzzy regression method to predict the bead geometry, such as bead width, bead height, bead penetration and bead area in the robotic GMA (gas metal arc) welding process is presented.
Abstract: Recently, there has been a rapid development in computer technology, which has in turn led to develop the fully robotic welding system using artificial intelligence (Al) technology. However, the robotic welding system has not been achieved due to difficulties of the mathematical model and sensor technologies. The possibilities of the fuzzy regression method to predict the bead geometry, such as bead width, bead height, bead penetration and bead area in the robotic GMA (gas metal arc) welding process is presented. The approach, a well-known method to deal with the problems with a high degree of fuzziness, is used to build the relationship between four process variables and the four quality characteristics, respectively. Using these models, the proper prediction of the process variables for obtaining the optimal bead geometry can be determined.

Journal ArticleDOI
TL;DR: The compaction of pure Cu powder was carried out through a series of experiments using dynamic magnetic pulse compaction, and the effects of process parameters, such as Jiscfiarge energy and compacting direction, on the homogeneity and the compaction density of compacted specimens were presented and discussed.
Abstract: The compaction of pure Cu powder was carried out through a series of experiments using dynamic magnetic pulse compaction, and the effects of process parameters, such as Jiscfiarge energy and compacting direction, on the homogeneity and the compaction density of compacted specimens were presented and discussed. The results indicated that the compaction density of specimens increased with the augment of discharge voltage and time. During unidirectional compaction, there was a density gradient along the loading direction in the compacted specimen, and the minimum compaction density was localized to the center of the bottom of the specimen. The larger the aspect ratio of a powder body, the higher the compaction density of the compacted specimen. And high conductivity drivers were beneficial to the increase of the compaction density. The iterative and the double direction compaction were efficient means to manufacture the homogeneous and high density powder parts.

Journal ArticleDOI
TL;DR: In this article, a new design technique for the long life hot forging die has been proposed, which can greatly increase the service life because the use of multi-materials can alleviate the thermal stress in hot forging dies.
Abstract: A new design technique for the long life hot forging die has been proposed. By finite element analysis, the reason for the failure of hot forging die was analyzed and it was concluded that thermal stress is the main reason for the failure of hot forging die. Based on this conclusion, the whole hot forging die was divided into the substrate part and the heat-resistant part according to the thermal stress distribution. Moreover, the heat-resistant part was further subdivided into more zones and the material of each zone was reasonably selected to ensure that the hot forging die can work in an elastic state. When compared with the existing techniques, this design can greatly increase the service life because the use of multi-materials can alleviate the thermal stress in hot forging die.

Journal ArticleDOI
Wenchun Jiang1, Jianming Gong1, Jianqun Tang1, Hu Chen1, S.T. Tu1 
TL;DR: In this paper, the effect of welding residual stress on hydrogen diffusion has been discussed using a 3-D sequential coupling finite element analysis procedure complied by Abaqus code, and the hydrogen diffusion coefficient in weld metal, the heat affected zone (HAZ), and the base metal of the 16MnR steel weldment were measured using the electrochemical permeation technique.
Abstract: The hydrogen distribution of 16MnR steel weldment in hydrogen contained environment was calculated using the finite element method (FEM). The effect of welding residual stress on hydrogen diffusion has been discussed using a 3-D sequential coupling finite element analysis procedure complied by Abaqus code. The hydrogen diffusion coefficient in weld metal, the heat affected zone (HAZ), and the base metal of the 16MnR steel weldment were measured using the electrochemical permeation technique. The hydrogen diffusion without the effect of stress was also calculated and compared. Owing to the existence of welding residual stress, the hydrogen concentration was obviously increased and the hydrogen would diffuse and accumulate in the higher stress region.

Journal ArticleDOI
C.G. Xu, G.H. Liu, G.S. Ren, Z. Shen, C.P. Ma, W.W. Ren 
TL;DR: In this paper, a flexible technique of hot working of bars by axial feed rolling was introduced, and the process deformation, strain field, stress field, and temperature field of the parts were analyzed by finite element method (FEM)-simulation software DEFORM-3D.
Abstract: A flexible technique of hot working of bars by axial feed rolling was introduced. The process deformation, strain field, stress field, and temperature field of the parts are analyzed by finite element method (FEM)-simulation software DEFORM-3D. The material flow rule and tool load have been investigated.

Journal ArticleDOI
TL;DR: In this paper, a series of numerical simulations are made to analyze the flow patterns in melt steel using finite volume method based on structured body fitted coordinate grids, and then it is developed to study the effect of operational parameters on fluid flow in thin slab caster, two operational parameters, SEN (submerged entry nozzle) depth, are mainly considered for numerical analysis.
Abstract: In recent years, thin slab continuous casting technology has been widely used to improve the quality of the product and to reduce the cost. One of the challenges faced by this technology is to design reasonable flow patterns, which strongly affect the surface and inner properties of the final slab in the mold. With the fixed scales and complex geometrical structures of nozzle and funnel type mold a series of numerical simulations are made to analyze the flow patterns in melt steel using finite volume method based on structured body fitted coordinate grids. The CFD (computational fluid dynamics) package is validated first using one typical case described in previously published studies, and then it is developed to study the effect of operational parameters on fluid flow in thin slab caster. Two operational parameters, casting speed and SEN (submerged entry nozzle) depth, are mainly considered for numerical analysis. On the basis of present simulations, the reasonable SEN submergence depths corresponding to different casting speeds are suggested according to fluid flow characteristics like, flow jet impingement on the narrow side of the mold, flow speed of the melt steel beneath the meniscus and the recirculation region. This is the first stage of study on the numerical analysis of the whole thin slab casting process with electromagnetic brake.

Journal ArticleDOI
G.J. Zhou1, Shengming Jin1, Li-zhu Liu1, Huayun Liu1, Z.P. Jin1 
TL;DR: In this article, phase relations in the Fe-Ti-Zr ternary system at 1 173 K were investigated by means of diffusion-triple approach together with electron probe microanalysis (EPMA) technique.
Abstract: Phase relations in the Fe-Ti-Zr ternary system at 1 173 K were investigated by means of diffusion-triple approach together with electron probe microanalysis(EPMA) technique. A series of tie lines and tie-triangles were determined and the isothermal section at 1 173 K was established, which consists of four three-phase fields: β(Ti, Zr)+FeZr2+FeTi, FeZr2+FeTi+Fe2Zr, FeTi +Fe2Zr +Fe2Ti and Fe2Zr +Fe2Ti +Fe. The results show that the largest solubility of Ti in Fe2Zr is about 11.3%(mole fraction) and the solid solubility of Ti in FeZr2 is about 26.9%, the solid solubility of Zr in Fe2Ti is about 8.1% and the solid solubility of Zr in FeTi is 7.2%. The binary compound FeZr2 is nearly a linear compound. No ternary compound is found.

Journal ArticleDOI
TL;DR: In this article, the microstructure formation and mechanical property involving icosahedral quasicrystal (I-phase) in the Y-rich Mg-Zn-Y alloy have been studied.
Abstract: The microstructure formation and mechanical property involving icosahedral quasicrystal (I-phase) in the Y-rich Mg-Zn-Y alloy have been studied. The equilibrium formation of I-phase from the Y-rich Mg-Zn-Y melt is through a peritectic reaction between the Y-rich melt and the primary W-phase, which is discussed in detail. The independent nucleation and coupling growth mechanism between the W-phase and the I-phase, from the melt, are revealed, which is significant for understanding the peritectic reaction process involving icosahedral quasicrystal in the Mg-Zn-Y alloy. The mechanism of the quasicrystal phase strengthened magnesium alloys is also discussed here.

Journal ArticleDOI
TL;DR: Wang et al. as discussed by the authors used graded sintering under ultra-high pressure (GSUHP) to extract functionally gradient materials (FGMs) containing 1%La2O3 and 1%TiC.
Abstract: W/Cu functionally gradient materials (FGMs) containing 1%La2O3 and 1%TiC were prepared using graded sintering under ultra-high pressure (GSUHP). The specimens have been found to exhibit low porosity (11.57% and 11.35%, respectively). Shearing strength of the specimens between layers is good. Moreover, the specimens have still demonstrated good performance in testing thermal-shock resistance. When power density of laser is 200MWm−2, the specimens have been tested for thermal-shock resistance (1000 times); the specimens that contained 1%La2O3 were not subjected to damage, whereas those that contained 1%TiC began to crack. Finally. effect of additives on thermal-shock resistance was also preliminarily discussed.

Journal ArticleDOI
TL;DR: In view of the periodic bending deformation of solid-liquid interface in the solidification process for continuous casting slab, the variation of temperature gradient and dendritic spacing in the front edge of the solid liquid interface, and the nucleation and propagation process of crack were studied in this paper.
Abstract: In view of the periodic bending deformation of solid-liquid interface in the solidification process for continuous casting slab, the variation of temperature gradient and dendritic spacing in the front edge of the solid-liquid interface, and the nucleation and propagation process of crack were studied. It is shown that the bending deformation of the interface results in the temperature field change in the front edge of solid-liquid interface, and the occurrence of temperature gradient along drawing direction results in the growth of secondary dendrites. The initial crack formed during the middle and final stage of solidification may extend to the surface of the casting slab and become an internal crack. The results of the theoretical analysis are basically in agreement with that of the experiment.

Journal ArticleDOI
TL;DR: The microstructure of a composite coating system, which was composed of an inner layer of Fe-Cr-Al and an outer layer of aluminum, was studied after it was respectively oxidized and sulfurdized at elevated temperatures as discussed by the authors.
Abstract: The microstructure of a composite coating system, which was composed of an inner layer of Fe-Cr-Al and an outer layer of aluminum, was studied after it was respectively oxidized and sulfurdized at elevated temperatures. Apart from the Al 2 O 3 scale formed on the surface, the microstructure of the composite coatings exposed at 900°C in air for 4h was a three-layer structure. The first layer consisted of a solid solution of Cr and Fe in α aluminum and an intermetallic compound FeAl 3 , while the second layer was a single phase of the aluminide and the third layer still remained the same appearance as the original Fe-Cr-Al coating. The microstructural observation of the specimen tested at 850 −900°C at low oxygen pressure and high sulfur pressure for 576h revealed that the surface coatings of the specimen had transformed into a duplex structure containing an outer layer and a thicker aluminide layer beneath. X-ray diffraction results showed that the out layer was composed of Al 2 S 3 and Al 2 O 3 and that AlCrFe 2 was the main phase composition of the aluminide layer, with a few of Al 2 S 3 and Al 2 O 3 accompanied.

Journal ArticleDOI
TL;DR: In this article, the corrosion behavior of carbon steel in the medium of marine microorganisms was investigated by electrochemical impedance spectra, polarization curves, and so on, and it was shown that the corrosion potential of the carbon steel moved in a negative direction in the unpurified marine microorganism solution, and the polarization style of the cathodic process did not change.
Abstract: The corrosion behavior of carbon steel in the medium of marine microorganisms was investigated by electrochemical impedance spectra, polarization curves, and so on. Experimental results showed that the corrosion potential of carbon steel moved in a negative direction in the unpurified marine microorganism solution, and the polarization style of the cathodic process did not change. The electrochemical impedance spectra showed that the impedance value of the electrode decreased in the medium with bacteria, which indicated that the existence of microorganism could accelerate the corrosion progress of carbon steel.

Journal ArticleDOI
TL;DR: In this article, an ab initio method has been performed to explore the elastic and optical properties of Al 3 Sc compound, based on a plane wave pseudopotential method, and the calculated equilibrium lattice parameter and elastic constants are in reasonable agreement with the previous experimental data.
Abstract: The ab initio method has been performed to explore the elastic and optical properties of Al 3 Sc compound, based on a plane wave pseudopotential method. It can be seen that the calculated equilibrium lattice parameter and elastic constants are in reasonable agreement with the previous experimental data. The elastic constants satisfy the requirement for mechanical stability in the cubic structure of the Al 3 Sc compound. The optical property calculations show that a strong absorptive peak exists from 0 - 15eV and a relative small absorptive peak exists around 30eV. The form is caused by the optical transitions between high s, p, and d bands, and the latter results from the optical transitions from high s, p, and d bands to the low 2p band.

Journal ArticleDOI
TL;DR: The superplasticity and diffusion bonding of IN718 superalloy were studied in this article, where the strain rate sensitivity index m was obtained at different temperatures and various initial strain rates using the tensile speed mutation method; m readied its maximum value 0.53 at an inititil strain rate of 1×10−4s−1 at 1253K.
Abstract: The superplasticity and diffusion bonding of IN718 superalloy were studied in this article. The strain rate sensitivity index m was obtained at different temperatures and various initial strain rates using the tensile speed mutation method; m readied its maximum value 0.53 at an inititil strain rate of 1×10−4s−1 at 1253K. The diffusion bonding parameters, including the bonding temperature T, pressure p, and time t, affected the mechanism of joints. When the bonded specimen with 25μm thick nickel foil interlayer was tensile at room temperature, the shear fracture of the joints with nickel foil interlayer took place at the IN718 part. Microstructure study was carried out with the bonded samples. The microstructure shows an excellent bonding at the interfaces. The optimum parameters for the diffusion bonding are: T=1273-1323K, p=20-30MPa, t=45-60min.

Journal ArticleDOI
Bo Li1, H.M. Du1, Xin Wang1, E.Y. Jiang1, Zhi-Qing Li1, P. Wu1 
TL;DR: In this paper, the microstructure and magnetic properties of Fe-N thin films were investigated with the increase of the substrate temperature (T s and the annealing temperature(T a ).
Abstract: Fe-N thin films were fabricated on both 100 si and NaCl substrates by RF magnetron sputtering under low nitrogen partial pressure. The microstructure and magnetic properties of Fe-N thin films were investigated with the increase of the substrate temperature (T s and the annealing temperature (T a ). It is more difficult for nitrogen atoms to enter the Fe lattice under higher T s above 150°C. The phase evolution is visible at higher T a above 200°C. The phase transformation of α ″ -Fe 16 N 2 occurred at 400°C. The change of crystal size with T a was clearly visible from bright and dark field images. The clear high-resolution electron microscope (HREM) images cf 110 α 111 γ , 112 α and 200 α , phases were observed. The interplanar distances from TEM (transmission electron microscope) and HREM match the calculated values very well. From the results of the vibrating sample magnetometer (VSM), the good magnetic properties of Fe-N films were obtained at 150°C of T s and 200°C of T α respectively.

Journal ArticleDOI
TL;DR: In this article, the corrosion resistance of pure magnesium with surface alloying layer obtained by a solid diffusion alloying technique has been analyzed, and it is shown that the treated ones possess a better corrosion resistance than the untreated ones.
Abstract: The corrosion resistance of pure magnesium with surface alloying layer obtained by a solid diffusion alloying technique has been analyzed. To establish the optimum treatment time, the experiments were performed at 480°C for different solid diffusion time (8, 16, and 24h). The diffusion interaction effectiveness between Zn, Al mix powder and the sample surface, depending on the treatment time for diffusion at given temperatures, has an obvious influence on corrosion resistance and corrosion mechanism. Corrosion properties were studied using the constant immersion test (in 3.0% NaCl solution, temperature is (28±1)°C, and time is 96h). Optical microscopy (OM) and EDS (energy dispersive spectrum) composition analysis were used to examine the cross-sectional microstructural characteristics of alloyed layer of treated samples. It is shown that in comparison with the untreated samples, the treated ones possess a better corrosion resistance. The Al5Mg11Zn4 phase, which formed as a continuous phase due to the diffusion of Al, Zn, and Mg elements and subsequent interaction on the outermost layer of diffusion alloying zones (especially the samples treated for 24h at 480°C), was inert to the chloride solution compared with pure magnesium and acted as a corrosion barrier, and therefore the best corrosion resistance was obtained. This protective action of Al5Mg11Zn4 phase was found to change with its amount, which was controlled by the diffusion time at given temperature. It was concluded that the continuous Al5Mg11Zn4 phase (WP-zone) of the reacted layer in pure magnesium was beneficial from the point of view of corrosion resistance.

Journal ArticleDOI
TL;DR: In this paper, an impedance analyzer was used to investigate the high-temperature AC magnetic properties of the Fe 73.5 Co 0.5 Si 13.5 B 9 alloy.
Abstract: High-temperature AC magnetic properties for (Fe 0.5 Co 0.5 ) 73.5 Cu 1 Nb 3 Si 13.5 B 9 alloy annealed at various temperatures have been investigated using an impedance analyzer. Annealing temperature T a has obvious effects on high-temperature AC magnetic properties of the alloy. The Hopkinson peak appears only in the amorphous alloy when T a ≤ 703K. As T a increases above 733K, the real part of the complex initial permeability β i ' descends gradually, β i ' decreases more slowly with temperature in the high temperature range. The high-temperature (about 750K) AC initial permeability for the alloy annealed at T a =763K has been found to maintain a stable high value of 950 up to a frequency of ∼ 1 × 10 5 Hz. Partial substitution of Co for Fe in the Fe 73.5 Cu 1 Nb 3 Si 13.5 B 9 alloy leads to an increase of around 110K of the Curie temperature of the amorphous phase, much higher than Ge-containing Finemet alloy.

Journal ArticleDOI
TL;DR: In this paper, a model GM (grey model) (1, 1) for forecasting the rate of copper extraction during the bio-leaching of primary sulphide ore was established on the basis of the mathematical theory and the modeling process of grey system theory.
Abstract: A model GM (grey model) (1, 1) for forecasting the rate of copper extraction during the bioleaching of primary sulphide ore was established on the basis of the mathematical theory and the modeling process of grey system theory. It was used for forecasting the rate of copper extraction from the primary sulfide ore during a laboratory microbial column leaching experiment. The precision of the forecasted results were examined and modified via “posterior variance examination”. The results show that the forecasted values coincide with the experimental values. GM (1, 1) model has high forecast accuracy; and it is suitable for simulation control and prediction analysis of the original data series of the processes that have grey characteristics, such as mining, metallurgical and mineral processing, etc. The leaching rate of such copper sulphide ore is low. The grey forecasting result indicates that the rate of copper extraction is approximately 20% even after leaching for six months.

Journal ArticleDOI
TL;DR: The principle of the stretch reducing process is analyzed, three models of pass design are established, and three kinds of database including the material database, pass design database, and product database are devised using Microsoft Access.
Abstract: The principle of the stretch reducing process is analyzed and three models of pass design are established. The simulations are done about variables, such as, stress, strain, the stretches between the stands, the size parameters of the steel tube, and the roll force parameters. According to its product catalogs the system can automatically divide the pass series, formulate the rolling table, and simulate the basic technological parameters in the stretch reducing process. All modules are integrated based on the developing environment of VB6. The system can draw simulation curves and pass pictures. Three kinds of database including the material database, pass design database, and product database are devised using Microsoft Access, which can be directly edited, corrected, and searched.