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Book ChapterDOI

5.02 – Adsorption Properties

Y. Hattori, +1 more
- Vol. 5, pp 25-44
TLDR
In this paper, the difference between supercritical gas adsorption and supercritical vapor adorption is discussed in terms of surface excess adsorptive and absolute adsorbing, respectively.
Abstract
Adsorption-related concepts are explained together with important intermolecular interactions in physical adsorption. The vapor adsorption isotherms on flat surfaces or macropores, mesopores, and micropores are interpreted by multilayer adsorption, capillary condensation, and micropore filling, respectively. Recent studies on capillary condensation in small mesopores are described. The difference between vapor adsorption and supercritical gas adsorption is discussed in terms of surface excess adsorption and absolute adsorption. New aspects of physical adsorption are shown on water vapor adsorption in hydrophobic micropores, quantum molecular sieving effect, and gate adsorption and breathing phenomena on porous coordination polymers.

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Citations
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Book ChapterDOI

Biochar as an Adsorbent: A Short Overview

TL;DR: The change of lignocellulosic biomass into valuable products is gradually gaining research interest, not only because of their abundance, but also because of the quantity of cellulose, hemicellulose and lignin it contains as discussed by the authors.
Journal ArticleDOI

The Role of Interfaces in Ionic Liquid‐Based Hybrid Materials (Ionogels) for Sensing and Energy Applications

TL;DR: In this paper , the authors provide a synergetic comprehension, focusing on the interactive forces and factors affecting the conductivity, stability, and robustness of ionogels, including the implications of nanofiller incorporation on the electromechanical properties.
Journal ArticleDOI

Enhanced CO 2 adsorptivity of SWCNT by polycyclic aromatic hydrocarbon intercalation

TL;DR: In this article, the electronic properties of single wall carbon nanotube (SWCNT) with intercalation of naphthalene derivatives (NDs) having different electron donor or acceptor property in the SWCNT bundles were investigated.
Journal ArticleDOI

Modulating SWCNT–silica interactions for enhanced dispersibility and hybrid cryogel formation

TL;DR: In this paper, the authors show that silica nanoparticles with tunable surface energy can be used as an efficient aqueous dispersant for single walled carbon nanotubes (SWCNTs).
Journal ArticleDOI

X-ray Absorption Improvement of Single Wall Carbon Nanotube through Gadolinium Encapsulation

TL;DR: In this paper, a single-wall carbon nanotube (SWCNT) through gadolinium (Gd) encapsulation has been studied and the liquid phase adsorption using ethanol has been performed for the doping treatment.
References
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Journal ArticleDOI

Helical microtubules of graphitic carbon

Sumio Iijima
- 01 Nov 1991 - 
TL;DR: Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.
Journal ArticleDOI

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)

TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
Journal ArticleDOI

Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism

TL;DR: In this paper, the synthesis of mesoporous inorganic solids from calcination of aluminosilicate gels in the presence of surfactants is described, in which the silicate material forms inorganic walls between ordered surfactant micelles.
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