Journal ArticleDOI
A C1 mechanism for methane oxidation on platinum
Preeti Aghalayam,Young K. Park,N.E. Fernandes,Vasilis Papavassiliou,A.B. Mhadeshwar,Dionisios G. Vlachos +5 more
TLDR
In this article, a multistep methodology was applied to construct a C1 surface reaction mechanism for methane oxidation on platinum, which is capable of capturing the physics of methane oxidation over a wide range of operating conditions.About:
This article is published in Journal of Catalysis.The article was published on 2003-01-01. It has received 123 citations till now. The article focuses on the topics: Reaction rate & Chemical reaction.read more
Citations
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Journal ArticleDOI
A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts
TL;DR: In this article, an extensive table on contributions to catalytic partial oxidation of methane over transition metal catalysts in the literature is provided, and both theoretical and experimental evidence pointing to inherent differences in the reaction mechanism over transition metals.
Journal ArticleDOI
Comprehensive review of methane conversion in solid oxide fuel cells: Prospects for efficient electricity generation from natural gas
TL;DR: A comprehensive review of the state of the art in the field of solid oxide fuel cells (SOFCs) can be found in this article, where the authors present an in-depth review with emphasis on electronic structure, charge transport and catalysis.
Journal ArticleDOI
Steam and dry reforming of methane on Rh : Microkinetic analysis and hierarchy of kinetic models
Matteo Maestri,Matteo Maestri,Dionisios G. Vlachos,Alessandra Beretta,Gianpiero Groppi,Enrico Tronconi +5 more
TL;DR: In this article, a thermodynamically consistent micro-kinetic model for CH4 steam reforming and dry reforming on Rh has been analyzed using a comprehensive, thermodynamic-consistent model, which pointed out mechanistic analogies between the two processes.
Journal ArticleDOI
Kinetics of the water-gas shift reaction on Pt catalysts supported on alumina and ceria
A.A. Phatak,N.A. Koryabkina,S. Rai,Joshua L. Ratts,Wolfgang F. Ruettinger,Robert J. Farrauto,Gary Blau,W.N. Delgass,Fabio H. Ribeiro +8 more
TL;DR: The kinetic parameters for the water-gas shift (WGS) reaction on Pt catalysts supported on ceria and alumina under fuel reformer conditions for fuel cell applications were reported in this article.
Reference EntryDOI
Heterogeneous Catalysis and Solid Catalysts
TL;DR: In this paper, the authors present an overview of the chemical properties of catalysts and their application in the industrial domain of catalytic cycle and show that they can be classified into three classes: simple binary oxides, complex multicomponent oxides and metal catalysts.
References
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Book
Chemical Engineering Kinetics
TL;DR: In this paper, chemical engineering kinetics was studied in terms of kinetics in the context of Chemical Engineering kinetics and its application in the field of chemical engineering. But they did not discuss the application of the kinetics of protein kinetics.
Journal ArticleDOI
Production of Syngas by Direct Catalytic Oxidation of Methane
TL;DR: Rhodium was considerably superior to platinum in producing more H2 and less H2O, which can be explained by the known chemistry and kinetics of reactants, intermediates, and products on these surfaces.
Book
The Microkinetics of heterogeneous catalysis
TL;DR: Microkinetic analysis and catalytic reaction synthesis Microkinetic analyses as discussed by the authors have been used for the analysis of catalytic reactions in a wide range of chemical reactions, such as: hydrogenation, catalyzed by platinum ammonia synthesis, metamolybdenum, and vanadium oxides.
Journal ArticleDOI
Steps in CH4 oxidation on Pt and Rh surfaces: High‐temperature reactor simulations
TL;DR: In this article, a 19-elementary-step model of adsorption, desorption and surface reaction steps with reaction parameters from the literature or from fits to previous experiments was used to simulate the direct oxidation of CH4 to H2 and CO in O2 and in air at high temperatures over alumina foam monoliths.
Journal ArticleDOI
Modeling the partial oxidation of methane in a short‐contact‐time reactor
TL;DR: In this paper, a tube wall catalytic reactor was simulated as a model for a single pore of the monolithic catalyst using a 2-D flow field description coupled with detailed reaction mechanisms for surface and gas-phase chemistry.