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A Direct View on Ni Substitution in Sc2Ir6-xNixB as probed by NMR

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TLDR
In this article , the effect of Ir substitution by Ni on the boron arrangement of these borides, primarily due to its weak scattering factor, was investigated using 11B-NMR.
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This article is published in Materials Research Bulletin.The article was published on 2023-06-01 and is currently open access. It has received 0 citations till now. The article focuses on the topics: Valence (chemistry) & Intermetallic.

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Journal ArticleDOI

Atomic Screening Constants from SCF Functions. II. Atoms with 37 to 86 Electrons

TL;DR: In this article, minimal basis set atomic functions for ground state atoms from Rb(Z=37) to Rn(Z =86) are presented, in order to obtain systematic data for the screening constants and atomic radii following the work initiated by Slater.
Journal ArticleDOI

NMR nomenclature. Nuclear spin properties and conventions for chemical shifts(IUPAC Recommendations 2001)

TL;DR: In this paper, a unified scale is recommended for reporting the NMR chemical shifts of all nuclei relative to the 1 H resonance of tetramethylsilane (TMS) in dilute solution (volume fraction, φ < 1%).
Journal ArticleDOI

Superconductivity in the non-oxide perovskite MgCNi3.

TL;DR: The high relative proportion of Ni in MgCNi3 suggests that magnetic interactions are important, and the lower Tc of this three-dimensional compound—when compared to the LnNi2B2C family—contrasts with conventional ideas regarding the origins of superconductivity.
Journal ArticleDOI

Rediscovering the Crystal Chemistry of Borides.

TL;DR: The aim of this review is to reintroduce to the scientific community the developments in boride crystal chemistry over the past 60 years, and tie structures to material properties, and furthermore, elaborate on convenient synthetic routes toward preparing borides.
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