Journal ArticleDOI
A highly strained planar-chiral platinacycle for catalytic activation of internal olefins in the Friedel-Crafts alkylation of indoles.
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This article is published in Angewandte Chemie.The article was published on 2009-01-05. It has received 127 citations till now. The article focuses on the topics: Friedel–Crafts reaction & Alkylation.read more
Citations
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Journal ArticleDOI
Catalytic Functionalization of Indoles in a New Dimension
Marco Bandini,Astrid Eichholzer +1 more
TL;DR: This Review emphasizes the achievements in the selective catalytic functionalization of indoles (C-C bond-forming processes) over the last four years.
Journal ArticleDOI
Transition-Metal-Catalyzed C–H Alkylation Using Alkenes
TL;DR: This Review summarizes transition-metal-catalyzed alkylations of various carbon-hydrogen bonds (addition of C-H bonds across olefins) using regular ole fins or 1,3-dienes up to May 2016.
Journal ArticleDOI
Katalytische Funktionalisierung von Indolen in einer neuen Dimension
Marco Bandini,Astrid Eichholzer +1 more
TL;DR: In this paper, the Fortschritte hinsichtlich der selektiven katalytischen Funktionalisierung von Indolen (durch C-C-Kupplung) aus den vergangenen vier Jahre zusammen.
Journal ArticleDOI
Enantioselective gold-catalyzed allylic alkylation of indoles with alcohols: an efficient route to functionalized tetrahydrocarbazoles.
Marco Bandini,Astrid Eichholzer +1 more
TL;DR: The working hypothesis deals with the choice of a suitable chiral Lewis acid promoter, which is capable of efficiently activating the hydroxy group as a leaving group without the formation of an allylic carbocationic species (SN1-type mechanism) that would preclude any stereochemical control in the course of the reaction.
Journal ArticleDOI
Chemoselective Asymmetric N‐Allylic Alkylation of Indoles with Morita–Baylis–Hillman Carbonates
TL;DR: The research group has reported that modified cinchona alkaloids are outstanding catalysts for the asymmetric allylic alkylation of a,a-dicyanoolefins with MBH carbonates and the deprotonation of the acidic NH group of the MBH base.
References
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Journal ArticleDOI
Gold-Catalyzed Organic Reactions
TL;DR: Important vinylgold intermediates, the transmetalation from gold to other transition metals, the development of new ligands for gold catalysis, and significant contributions from computational chemistry are other crucial points for the field highlighted here.
Journal ArticleDOI
Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
Alois Fürstner,Paul W. Davies +1 more
TL;DR: The ability of platinum and gold catalysts to effect powerful atom-economic transformations has led to a marked increase in their utilization and the application of platinum- and gold-catalyzed transformations in natural product synthesis is discussed.
Journal ArticleDOI
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
Martin Albrecht,Gerard van Koten +1 more
TL;DR: This review discusses the synthetic methodologies that are currently available for the preparation of platinum group metal complexes containing pincer ligands and especially emphasizes different applications that have been realized in materials science such as the development and engineering of sensors, switches, and catalysts.
Journal ArticleDOI
The potential of palladacycles: more than just precatalysts
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