Journal ArticleDOI
A new method for the simultaneous determination of the size and shape of pores: the thermoporometry
TLDR
In this paper, a thermodynamic study of the liquid-solid phase transformations in porous materials provides the relationships between the size of the pores in which solidification takes place and the temperature of the triple point of the divided liquid, on the one hand, and between this temperature and the apparent solidification energy on the other hand.About:
This article is published in Thermochimica Acta.The article was published on 1977-10-01. It has received 703 citations till now. The article focuses on the topics: Thermodynamic equilibrium & Porous medium.read more
Citations
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Changes in portlandite morphology with solvent composition: Atomistic simulations and experiment
TL;DR: In this article, a new analysis tool was developed to quantify the experimentally observed changes in morphology of portlandite, allowing the calculation of the relative surface energies of the crystal facets.
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Preparation and Characterization of Membranes Formed by Nonsolvent Induced Phase Separation: A Review
TL;DR: A review of nonsolvent induced phase separation membrane preparation and characterization for many commonly used membrane polymers is presented in this article, which includes membrane porosity and pore size distribution characterization, membrane physical and chemical properties characterization, and thermodynamic and kinetic evaluation of phase inversion process.
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Theory of Drying
TL;DR: In this paper, the authors examined the forces that produce shrinkage and the mechanisms responsible for transport of liquid, and a variety of strategies for avoiding fracture during drying were discussed, with the emphasis on the constant rate period (CRP) when the pores are full of liquid.
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Crystallization in pores
TL;DR: In this paper, the authors discuss the thermodynamics of crystallization within porous materials and the factors that influence stress development and cracking, including the pore size, the energy of the interface between pore wall and the crystal, and the yield stress or buckling strength of the crystal.
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The melting behavior of organic materials confined in porous solids
TL;DR: In this paper, the authors measured the solid-liquid phase transition temperatures and heats of fusion ΔH f of nonpolar organic solids confined in the pores of controlled pore glasses by differential scanning calorimetry.
References
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Determination of pore-size distribution from freezing-point depression
TL;DR: In this paper, the effect of interfacial curvature on the freezing point of liquids confined in capillaries is exploited to determine a pore-size distribution, from the curve of freezing-point against volume frozen.
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Determination of the Structure of Porous Media
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Capillary Cone Method for Determination of Surface Tension of Solids
A. Skapski,R. Billups,A. Rooney +2 more