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Open AccessJournal ArticleDOI

A novel dual-layer bicomponent electrospun nanofibrous membrane for desalination by direct contact membrane distillation

TLDR
In this article, a bicomponent nanofibrous composite membrane was fabricated by electrospinning and was tested for desalination by direct contact membrane distillation (DCMD).
About
This article is published in Chemical Engineering Journal.The article was published on 2014-11-15 and is currently open access. It has received 137 citations till now. The article focuses on the topics: Membrane distillation & Membrane.

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Citations
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Journal ArticleDOI

Fouling and its control in membrane distillation-A review

TL;DR: In this paper, a review of different fouling mechanisms in the membrane distillation process, their possible mitigation and control techniques, and characterization strategies that can be of help in understanding and minimizing the fouling problem.
Journal ArticleDOI

A review on electrospinning for membrane fabrication: Challenges and applications

TL;DR: In this paper, the authors present a review on the preparation and application of electrospun nanofiber membranes as the barrier layer for water treatment, with emphasis on the reinforcement and post-treatment of electro-spun polymer membranes.
Journal ArticleDOI

Wetting phenomena in membrane distillation: Mechanisms, reversal, and prevention

TL;DR: A broad review is carried out on wetting incidence in membrane distillation processes and describes the wetting mechanisms, wetting causes, and wetting detection methods, as well as hydrophobicity measurements of MD membranes.
Journal ArticleDOI

Superhydrophobic nanofiber membrane containing carbon nanotubes for high-performance direct contact membrane distillation

TL;DR: In this paper, superhydrophobic, robust, mixed matrix polyvinylidene fluoride-co-hexafluoropropylene (PcH) nanofiber membranes were fabricated incorporating different concentrations of carbon nanotubes (CNTs) as nanofillers to impart additional mechanical and hydrophobic properties.
Journal ArticleDOI

Principles and applications of direct contact membrane distillation (DCMD): A comprehensive review

TL;DR: In this paper, the current and most recent applications of direct contact membrane distillation (DCMD) are discussed and the fundamentals of the DCMD and governing equations (from heat and mass transfer principles) that describe performance parameters are first explained.
References
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Journal ArticleDOI

A framework for better understanding membrane distillation separation process

TL;DR: In this paper, the most important aspects of the membrane distillation process are presented in a simple manner for a glance understanding the effects of different factors and operating variables on the productivity of each MD configuration.
Journal ArticleDOI

Membranes and theoretical modeling of membrane distillation: a review.

TL;DR: A comprehensive MD state-of-the-art review covering a wide range of commercial membranes, MD membrane engineering, their MD performance, transport mechanisms, experimental and theoretical modeling of different MD configurations as well as recent developments in MD is offered.
Journal ArticleDOI

Superhydrophobic modification of TiO2 nanocomposite PVDF membranes for applications in membrane distillation

TL;DR: In this paper, the anti-fouling performance of virgin and modified membranes were examined in a direct contact membrane distillation (DCMD) process using sodium chloride and humic acid solution as a model feed.
Journal ArticleDOI

Fabrication of polyvinylidene fluoride (PVDF) nanofiber membranes by electro-spinning for direct contact membrane distillation

TL;DR: In this article, the polyvinylidene fluoride (PVDF) nanofiber membranes for membrane distillation were optimized to examine their effects on pore size distribution and inorganic additives were added into the dope to improve the electro-spinability of diluted polymer dopes.
Journal ArticleDOI

Flux enhancement in membrane distillation by fabrication of dual layer hydrophilic–hydrophobic hollow fiber membranes

TL;DR: In this article, the effect of different non-solvents on the morphology of the PVDF membranes was investigated and it was found that weak coagulants such as water/methanol (20/80, w/w) can induce a three-dimensional porous structure on PVDF membrane with high surface and bulk porosities, big pore size, sharp pore sizes, high surface contact angle and high permeability but rather weak mechanical properties.
Related Papers (5)
Frequently Asked Questions (16)
Q1. What is the effect of the triple-layer membrane on the membrane?

The triple-layer membrane showed increased hydrophobicity and wetting resistance (i.e., high liquid entry pressure (LEP)), which resulted to increased flux, salt rejection and long term performance of the membrane. 

In this paper, a triple-layer membrane composed of a PVDF nanofiber layer, a polyethylene terephthalate ( PET ) support layer was investigated on its performance in air gap membrane distillation ( AGMD ). 

Some reports have indicated that support layers that are thick, less hydrophobic, and with big pore sizes could lead to pore wetting [13]. 

The improvement in flux performance for dual-layer membranes is attributed to: (a) increased top surface hydrophobicity, thereby decreasing the potential wetting of the membrane; (b) higher porosity of the top surface which increases the available surface area for evaporation; (c) and the structure of thinner more hydrophobic surface layer (i.e., PH) (DL2) and thicker less hydrophobic layer (i.e., PAN), which decreases the mass transfer resistance [23]. 

Electrospinning involves the use of high electric fields applied on a polymer solution forming elongated and stretched nanofibers and collected on a grounded collector. 

There are two kinds of dual-layer membranes that were fabricated: 50/50 PH-PAN and 25/75 PH-PAN referred herein as DL1 and DL2 membranes, respectively. 

The authors used PVDF-co-HFP because it was reported to have superior hydrophobicity and high free volume compared to PVDF [18]; while PAN has good mechanical and thermal stability, and excellent solvent resistance, and is commonly used for microfiltration and ultrafiltration applications. 

The continuous overlapping of the nanofibers forming layers upon layers of fibers results to interconnected pores throughout the depth of the membrane. 

the presence of some beads-on-string has added to the roughness of the membrane [22], thus enhancing its hydrophobicity. 

(5) Further optimization of the membranes needs to be carried out by altering the different electrospinning parameters to improve the DCMD flux performance and salt rejection. 

The thickness of the different membrane layers were controlled by manipulating the electrospinning time duration between 1.5 and 6 h. 

(3) Through DCMD tests, the dual-layer PVDF-co-HFP/PAN with 25/75 thickness ratio showed the highest permeate flux of 30 LMH using 35 g L 1 NaCl feed solution. 

DW and 35 g L 1 NaCl solutions werercialized flat-sheet membrane in DW water as feed, and (b) final flux values of the erature = 60 C, flow rate = 400 ml min 1; permeate: inlet temperature = 20 C, flowused as feed. 

The electrical conductivity of the solutionswere constantly monitored using a portable conductivity meter (HQ40d, Hach), and the change in weight of the permeate solution was automatically recorded through a data acquisition system attached to the digital balance (PGW 4502e, Adam) throughout the duration of the test. 

The high LEP of PTFE membrane is mainly attributed to its small average pore size and smaller surface area for penetration (many dense areas) as observed on its morphological structure in Fig. S3a (SI). 

The following can be deduced from this study:(1) The PVDF-co-HFP nanofibers showed highly porous structure ( 90% porosity) with interconnecting pores.