Journal ArticleDOI
A temperature-controlled reversible ionic liquid - water two phase - single phase protocol for hydrogenation catalysis
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An ionic liquid system that undergoes a reversible two phase single phase transformation dependent upon temperature has been used as a novel medium for the transition-metal-catalyzed hydr... as discussed by the authors.Abstract:
An ionic liquid water system that undergoes a reversible two phase single phase transformation dependent upon temperature has been used as a novel medium for the transition-metal-catalyzed hydr...read more
Citations
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Ionic liquid (molten salt) phase organometallic catalysis.
TL;DR: The advent of water-soluble organometallic complexes, especially those based on sulfonated phosphorus-containing ligands, has enabled various biphasic catalytic reactions to be conducted on an industrial scale and might combine the advantages of both homogeneous and heterogeneous catalysis.
Journal ArticleDOI
Catalysis in ionic liquids
TL;DR: Hydrogenation of Alkenes and Arenes by Nanoparticles 2624 3.1.2.
Journal ArticleDOI
Ionic liquids and catalysis: Recent progress from knowledge to applications
TL;DR: In this paper, a survey on the latest most representative developments and progress concerning ionic liquids, from their fundamental properties to their applications in catalytic processes, is presented, highlighting their emerging use for biomass treatment and transformation.
Journal ArticleDOI
Ionic liquids in catalysis
TL;DR: The current state of the art of the application of ionic liquids in catalysis is reviewed in this article, where examples of the different ways in which ionic liquid have been applied in Catalysis, i.e. as the catalyst itself, as a co-catalyst or catalyst activator, as the source of a new ligand for a catalytic metal centre, or just as the solvent for the reaction.
Journal ArticleDOI
Air and water stable ionic liquids in physical chemistry
TL;DR: In this review article, a short overview on physicochemical aspects of ionic liquids, such as physical properties of ions, nanoparticles, nanotubes, batteries, spectroscopy, thermodynamics and catalysis of/in ions are given.
References
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Journal ArticleDOI
The use of new ionic liquids in two-phase catalytic hydrogenation reaction by rhodium complexes
TL;DR: The reaction of 1-n-butyl-3-methylimidazolium chloride (BMIC) with sodium tetrafluoroborate or sodium hexafluorophosphate produced the room temperature-, air-and water-stable molten salts (BMI+)(BF4−) (1) and (bMI+(PF6−)(2), respectively, in almost quantitative yield as discussed by the authors.
Journal ArticleDOI
A Novel Class of Versatile Solvents for Two-Phase Catalysis: Hydrogenation, Isomerization, and Hydroformylation of Alkenes Catalyzed by Rhodium Complexes in Liquid 1,3-Dialkylimidazolium Salts
BookDOI
Aqueous-Phase Organometallic Catalysis: Concepts and Applications
Boy Cornils,Wolfgang A. Herrmann +1 more
TL;DR: Aqueous-phase catalysts for aqueous chemistry: What Should be done in the future as mentioned in this paper... and what should not be done. But they do not discuss the role of catalysts in water as a special unit operation.