Journal ArticleDOI
Acid-Base Studies in Gaseous Systems. II. The Anomalous Base Strength of the Methylamines; A New Manifestation of Steric Strain1,2
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This article is published in Journal of the American Chemical Society.The article was published on 1944-03-01. It has received 94 citations till now. The article focuses on the topics: Methylamines & Steric effects.read more
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Aromatic Nucleophilic Substitution Reactions.
Journal ArticleDOI
Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
TL;DR: The difference between the covalent and the dative bond becomes apparent only after the orbital coefficients have been analyzed as discussed by the authors, which may explain why many structural chemists seem reluctant to distinguish between the two types of bonds.
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Cationic tricoordinate boron intermediates: borenium chemistry from the organic perspective.
TL;DR: The focus of this review is on the reactivity of cationic, tricoordinated boron electrophiles, and on recent applications that rely on intermediates having sextet bor on and net positive charge, including selected historical aspects of reactivity, some of which have not appeared in prior reviews.
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Ruthenium complexes bearing bidentate Schiff base ligands as efficient catalysts for organic and polymer syntheses
TL;DR: In this article, a concise overview is given on mononuclear and dinuclear, bidentate Schiff base ruthenium complexes with different additional ligands and their applications in various chemical transformations such as Kharasch addition, enol-ester synthesis, alkyne dimerization, olefin metathesis and atom transfer radical polymerization.
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The tetrahedral character of the boron atom newly defined—a useful tool to evaluate the N→B bond
TL;DR: The tetrahedral character at the boron atom in borsin complexes with a coordinative N→B bond has been evaluated on the basis of 144 solid state and gas phase molecular structures in order to obtain additional information on the van der Waals versus covalent relationship of the Borsin-nitrogen bond as discussed by the authors.