Journal ArticleDOI
Additions of organocopper reagents to allylic epoxides
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This article is published in Journal of the American Chemical Society.The article was published on 1970-08-01. It has received 74 citations till now. The article focuses on the topics: Allylic rearrangement.read more
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Nucleophilic and organometallic displacement reactions of allylic compounds: stereo-and regiochemistry
TL;DR: In this paper, stereo and regiochemical aspects of three reaction types: the SN2' reaction (bimolecular nucleophilic substitution with allylic rearrangement); displacement reactions effected by organometallic reagents; the conversion of allylic alcohols into halides.
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Mechanisms of Nucleophilic Organocopper(I) Reactions
Naohiko Yoshikai,Eiichi Nakamura +1 more
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Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry.
Eiichi Nakamura,Seiji Mori +1 more
TL;DR: This review will summarize first the general structural features of organocopper compounds and the previous mechanistic arguments, and then describe the most recent mechanistic pictures obtained through high-level quantum mechanical calculations for three typical organocuprate reactions, carbocupration, conjugate addition, and S(N)2 alkylation.
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Regioselective 1,4‐addition of nucleophiles to 1,3‐diene monoepoxides catalyzed by palladium complex
TL;DR: In this paper, 1,3-Diene monoepoxides react with nucleophiles in the presence of palladium complex as a catalyst under neutral conditions to give 1,4-adducts selectively.
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Rhodium(III)-catalyzed C-C coupling of arenes with 2-vinyloxiranes: synthesis of allylic alcohols.
Songjie Yu,Xingwei Li +1 more
TL;DR: A rhodium(III)-catalyzed C-C coupling between 2-vinyloxiranes and arenes directed by different chelating groups and a series of benzoazepanes has been synthesized by following this coupling.