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Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product

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TLDR
In this paper, the effect of the parameters such as pH, initial dye concentration and temperature on the removal of an anionic dye, tartrazine, from aqueous solutions has been investigated.
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This article is published in Arabian Journal of Chemistry.The article was published on 2017-05-01 and is currently open access. It has received 525 citations till now. The article focuses on the topics: Freundlich equation & Langmuir.

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Synthesis, Characterization and Sorption Properties of Biochar, Chitosan and ZnO-Based Binary Composites towards a Cationic Dye

TL;DR: In this paper , Moringa oleifera seed-derived biochar composites, e.g., Biochar-Chitosan (BC), Biochar ZnO (BZ), and Chitos-ZnO(CZ), were produced and characterized.
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Recent progress in nanomaterial-functionalized membranes for removal of pollutants

TL;DR: In this paper , a review of the progress of nanomaterial-modified membranes for wastewater treatment applications is presented, and the importance of functionalization strategies to prepare thin-film nanocomposite hybrid membranes and their effect on eliminating pollutants is discussed.
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Enhanced separation of base metal sulfides in flotation systems using Chitosan-grafted-Polyacrylamides

TL;DR: In this article , a chitosan-grafted polyacrylamide (Chi-g-PAM), a synthetic biocompatible polymer was investigated as a selective depressant of iron sulfide minerals [i.e., pyrite (FeS2)] in the flotation process of base metal sulfide mines.
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Tea Stem as a Sorbent for Removal of Methylene Blue from Aqueous Phase

Abstract: The potentiality of tea stem for the adsorption of methylene blue (MB) from aqueous phase was investigated. A series of operating factors, including the initial MB concentration, contact time, pH of solution, dose of tea stem, and ionic strength of solution, were conducted to understand the effect of adsorption of MB onto tea stem. Adsorption isotherm, kinetic models, thermodynamic investigation, and regenerability of tea stem were systematically investigated in this study. The experiment results revealed that the removal efficiency decreased with MB concentration and the equilibrium time of adsorption at different initial MB concentrations was approximately at 60 min. The appropriate dose of tea stem powder was found to be 4 g/L. The pHzpc of tea stem was evaluated and was observed to be 6.0 ± 0.2. The removal efficiency increased with pH ranging from 3.0 to 5.0 and remained constantly at the pH range of 5.0–11.0. The pH affected the adsorption because of the repellent power between H+ and dye cation. The ionic strength was found to have a negligible effect on the adsorption. The Langmuir and Temkin isotherm models were found to be the best isotherm models to elucidate the adsorption mechanism between MB and tea stem powder. The maximum adsorption capacity of 103.09 mg/g derived from the Langmuir model was much close to the experimental result. From the kinetic analysis, the pseudo-second-order model was found to be the suitable model to describe the adsorption behavior. The calculated adsorption capacities at different temperatures derived from the pseudo-second-order model ranging from 68.91 to 69.8 mg/g were well close to the experimental data. The intraparticle diffusion of MB molecules into pore structures of tea stem powder is the rate-limiting step for the adsorption process in this study. Evaluation of thermodynamic parameters including changes in enthalpy, entropy, and Gibb’s free energy indicated the adsorption mechanism between MB and tea stem powder was a spontaneous and exothermic process. The regeneration/adsorption experiments indicated that the tea stem powder efficiently remained more than 97% after five cycles using NaOH as a desorbing agent and thus be used for many times. On the basis of experimental results obtained, it is concluded that the tea stem has a considerable potential as a low-cost sorbent for removing MB from the aqueous phase.
References
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Journal ArticleDOI

The adsorption of gases on plane surfaces of glass, mica and platinum.

TL;DR: In this article, the absorption index at the wave length of the band maximum was found to be proportional to the total concentration of metal at shorter wave lengths, however, deviations were observed, the absorption increasing more rapidly with concentration than Beers' law would demand.
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Kinetics of Adsorption on Carbon from Solution

TL;DR: In this paper, it was shown that the rate of adsorption of persistent organic compounds on granular carbon is quite low and the rate is partially a function of the pore size distribution of the adsorbent, of the molecular size and configuration of the solute, and of the relative electrokinetic properties of adsorbate and adsorbents.
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Sorption of dye from aqueous solution by peat

TL;DR: In this paper, the sorption of two dyes, namely Basic Blue 69 and Acid Blue 25 onto peat has been studied in terms of pseudo-second order and first order mechanisms for chemical sorption as well as an intraparticle diffusion mechanism process.
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