Alkenes from acids by oxidative decarboxylation

doi:10.1016/0040-4020(68)88124-4

Journal ArticleDOI

Alkenes from acids by oxidative decarboxylation

John D. Bacha, +1 more

- 01 Jan 1968 -

Tetrahedron

- Vol. 24, Iss: 5, pp 2215-2226

Chats0

TLDR

In this paper, the effects of acid, PbIV and catalysts on the rates of decarboxylation and conversions of acids are examined and a convenient preparation of ω-alkenoic acids from dibasic acids such as 6-heptenoic acid from suberic acid is described.

About:

This article is published in Tetrahedron.The article was published on 1968-01-01. It has received 123 citations till now. The article focuses on the topics: Decarboxylation & Oxidative decarboxylation.

Citations

PDF

Open Access

More filters

Journal ArticleDOI

Free-radical cyclizations

Marc Julia

- 01 Nov 1971 -

Accounts of Chemical Research

TL;DR: In this article, the main types of reactions which free radicals undergo to generate new carbon-carbon bonds are discussed, including the addition of free radicals to unsaturated bonds and aromatic substitution reactions.

...read moreread less

Journal ArticleDOI

Catalytic dehydrogenative decarboxyolefination of carboxylic acids

Xiang Sun, +2 more

- 08 Oct 2018 -

Nature Chemistry

TL;DR: It is shown how abundant fatty acids can be converted to alpha-olefins, and the method is expanded to include structurally complex carboxylic acids, giving access to synthetically versatile intermediates.

...read moreread less

Journal ArticleDOI

Magnetic exchange interactions in transition-metal dimers. 12. Structural and magnetic characterization of the di-.mu.(1,3)-azido complex [Cu2(Me5dien)2(N3)2](BPh4)2 and similar di-.+-.(1,3)-azido copper(II) dimers. Unusual zero-field splitting in the electron paramagnetic resonance spectra

Timothy R. Felthouse, +1 more

- 01 Feb 1978 -

Inorganic Chemistry

Journal ArticleDOI

C-linked galactosyl serine AFGP analogues as potent recrystallization inhibitors.

Suhuai Liu, +1 more

- 12 May 2005 -

Organic Letters

TL;DR: Analysis of antifreeze protein-specific activity revealed that only analogue 2a (n = 1) was a potent recrystallization inhibitor and thus has potential medical and industrial applications.

...read moreread less

Journal ArticleDOI

Decarboxylative cross-nucleophile coupling via ligand-to-metal charge transfer photoexcitation of Cu(ii) carboxylates

Qi Li, +8 more

- 01 Jan 2022 -

Nature Chemistry

TL;DR: In this article , a copper-mediated, net-oxidative decarboxylative coupling of carboxylic acids with diverse nucleophiles under visible-light irradiation is reported.

...read moreread less