Journal ArticleDOI
Alternating copolymerisations of dioxaphospholane and dioxaphosphorinane with γ-butyrolactone and ethylene oxide
TLDR
In this paper, a copolymer containing phosphorus was prepared from 2-phenyl-1,3,2-dioxaphospholane and 4-oxo-5,6-benzo with ethylene oxide and γ-butyrolactone.About:
This article is published in European Polymer Journal.The article was published on 1982-01-01. It has received 3 citations till now. The article focuses on the topics: Ethylene oxide.read more
Citations
More filters
Journal ArticleDOI
Why δ-Valerolactone Polymerizes and γ-Butyrolactone Does Not
TL;DR: The overall results indicate that the lack of polymerizability of gamma-butyrolactone should be attributed to the low strain of the ring, which shows much less geometric distortion in the ester group than delta-valerolactone, and the notable stability of the coiled conformations found in model compounds of poly-4-hydroxybutyrate.
Journal ArticleDOI
Spontaneous zwitterionic copolymerisation: An undervalued and efficacious technique for the synthesis of functional degradable oligomers and polymers
TL;DR: The spontaneous zwitterionic copolymerisation (SZWIP) of compatible nucleophilic and electrophilic monomers is a relatively unknown and unexplored method for the synthesis of (predominantly alternating) degradable co- and terpolymers as mentioned in this paper.
Journal ArticleDOI
Cycloexpansion Reactions in Benzo[e]-1,3,2-diheterophosphorin-4-ones and 4-Oxo-1,3,2-dioxaphospholanes
Vladimir F. Mironov,Liliya M. Burnaeva,G. A. Ivkova,L. M. Abdrakhmanova,Mudaris N. Dimukhametov,I. V. Konovalova +5 more
TL;DR: In this article, a review of the reactions of 2-R-benzo[d]-1,3,2-dioxaphosphorin-4-ones with unsaturated compounds is presented.
References
More filters
Journal ArticleDOI
Polymerization via Zwitterion. 21. Alternating Copolymerizations of Cyclic Acyl Phosphonite and Phosphite with p-Benzoquinones
Journal ArticleDOI
Polymerization via zwitterion. 24. Copolymerization of a cyclic acyl phosphonite with aromatic aldehydes
TL;DR: In this article, spontaneous copolymerizations of 2-phenyl-4-oxo-5, 6-benzo-1,3,2-dioxaphosphorinane, a new cyclic acyl phosphonite, (MN) with p- and o-substituted aromatic aldehydes (ME) gave 1∶2 (MN ∶ ME) alternating copolymers.
Journal ArticleDOI
Synthesis and Polymerization of Spiro Oxyphosphoranes
Takeo Saegusa,Shiro Kobayashi +1 more
TL;DR: In this paper, the first isolated instance of spiro acyloxyphosphoranes was described emphasizing the significance of the isolated instances of these new species, and the no-catalyst alternating copolymerization of the combinations of cyclic phosphorus(III) compounds with acrylic acid derivatives and with α-keto acids (electrophilic monomer, ME) are mentioned.
Journal ArticleDOI
Polymerization via zwitterion. 23. Terpolymerization among 2-phenyl-1,3,2-dioxaphospholane, methyl acrylate, and carbon disulfide
TL;DR: In this article, the terpolymerization involving 2-phenyl-1,3,2-dioxaphospholane, methyl acrylate, and carbon disulfide was described without any added initiator in benzonitrile or dimethylformamide.