Journal ArticleDOI
Ambient temperature Atom Transfer Radical copolymerization of tetrahydrofurfuryl methacrylate and methyl methacrylate: Reactivity ratio determination
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In this paper, a tetrahydrofurfuryl methacrylate (THFMA) was polymerized by ambient temperature Atom Transfer Radical Polymerization (AT ATRP) using CuX/PMDETA/EBiB system.About:
This article is published in European Polymer Journal.The article was published on 2009-09-01. It has received 23 citations till now. The article focuses on the topics: Radical polymerization & Atom-transfer radical-polymerization.read more
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Journal ArticleDOI
Tailor-made polymethacrylate bearing bicyclo-alkenyl functionality via selective ATRP at ambient temperature and its post-polymerization modification by ‘thiol–ene’ reaction
TL;DR: In this article, a facile synthetic route for the preparation of tailor-made polymers bearing reactive pendant bicyclo-alkenyl functionality via selective atom transfer radical polymerization at ambient temperature (AT-ATRP) was reported.
Journal ArticleDOI
Emulsifier-free synthesis of crosslinkable ABA triblock copolymer nanoparticles via AGET ATRP
TL;DR: In this paper, a crosslinkable ABA triblock copolymer was synthesized from allylic methacrylate (AMA) monomer using a poly(ethylene oxide)-based macromolecule as both an initiator and emulsifier.
Journal ArticleDOI
Synthesis and characterization of new copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate: Determination of reactivity ratios
TL;DR: In this article, the authors used free radical polymerization in toluene at 70±1 °C using benzoyl peroxide (BPO) as an initiator to synthesize copolymers from different feed compositions of GMA and tetrahydrofurfuryl acrylate.
Journal ArticleDOI
Copolymers of a new methacrylate monomer bearing oxime ester and ether with methyl methacrylate: Synthesis, characterization, monomer reactivity ratios, and biological activity
Ibrahim Erol,Sait Kolu +1 more
TL;DR: In this article, the free-radical copolymerization of 2-metil-1-{[(1{4]-(4-nitrobenzil)oksi]fenil}etilidene)amino]oksi}prop-2-en-1on (NBOEMA) with methyl methacrylate (MMA) was carried out in 1,4-dioxane at 65 ± 1°C.
Journal ArticleDOI
Determination of Homopolymerization Kinetics of 10-(N-Methylacrylamido)-decylphosphonic acid, Its Diethyl ester, and 10-(Methacryloyloxy)-decylphosphonic acid, and Their Copolymerization with Methyl methacrylate
References
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Journal ArticleDOI
Metal-catalyzed living radical polymerization.
Journal ArticleDOI
Linear method for determining monomer reactivity ratios in copolymerization
Morton A. Fineman,Sidney D. Ross +1 more
Journal ArticleDOI
Polymerization shrinkage of methacrylate esters.
TL;DR: The polymerization shrinkage of a range of poly(n-alkyl methacrylates) in the range C1 to C16, some of their isomers and the polymers of cyclic and heterocyclic methacylates have been measured using densitometry to reflect the fact that the change in molar volume on polymerizing a methacRYlate ester is reasonably constant at 22 cc/mol irrespective of the geometry of the substituent group.
Journal ArticleDOI
Polymerization of n-Butyl Acrylate by Atom Transfer Radical Polymerization. Remarkable Effect of Ethylene Carbonate and Other Solvents
TL;DR: In this paper, atom transfer radical polymerization (ATRP) of n-butyl acrylate with the homogeneous catalyst, CuIBr/4,4‘-di(5-nonyl)-2,2'bipyridine (dNbpy), in benzene, afforded well-defined poly(n- butyl acylate) with predetermined molecular weights and low polydispersities, Mw/Mn = 1.1.
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