Journal ArticleDOI
Ambient temperature Atom Transfer Radical copolymerization of tetrahydrofurfuryl methacrylate and methyl methacrylate: Reactivity ratio determination
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TLDR
In this paper, a tetrahydrofurfuryl methacrylate (THFMA) was polymerized by ambient temperature Atom Transfer Radical Polymerization (AT ATRP) using CuX/PMDETA/EBiB system.About:
This article is published in European Polymer Journal.The article was published on 2009-09-01. It has received 23 citations till now. The article focuses on the topics: Radical polymerization & Atom-transfer radical-polymerization.read more
Citations
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Polymers Based on Methacrylate Bearing Coumarin Side Group: Synthesis via Free Radical Polymerization, Monomer Reactivity Ratios, Dielectric Behavior, and Thermal Stabilities
TL;DR: The monomer reactivity ratios of MAOC and BMA were computed using Kelen-Tudos (K-T) and Fineman-Ross (F-R) methods and were found to be 𝑟1=0.45, 𝐟2=1.33, respectively, which is monomers reactivity ratio ofMAOC.
Journal ArticleDOI
Copper catalyzed atom transfer radical copolymerization of glycidyl methacrylate and 2-ethylhexyl acrylate
TL;DR: In this paper, the atom transfer radical copolymerization (ATRcP) of GMA and PEHA was carried out in bulk and in toluene at 70 °C at different molar feed ratios using CuCl as catalyst in combination with 2,2′-bypyridine (bpy) as a ligand.
Journal ArticleDOI
Tailoring of conducting polymers via copolymerization – A review
TL;DR: In this article, a review describes articles and patents concerning tailoring of conducting polymers via copolymerization to acquire scientific and technological information of these copolymers including their synthesis, unique properties, and wide applications over their respective homopolymers due to their chemical structure.
Journal ArticleDOI
SET-LRP of Bio- and Petroleum-Sourced Methacrylates in Aqueous Alcoholic Mixtures
Adrian Moreno,Nabil Bensabeh,Jaan Parve,Juan C. Ronda,Virginia Cádiz,Marina Galià,Lauri Vares,Gerard Lligadas,Virgil Percec +8 more
TL;DR: Efforts to expand the monomer scope for SET-LRP in "programmed" aqueous organic biphasic systems by targeting methacrylic monomers and polymers by synthesizing polymers of different targeted molar mass as well as quasi-block AB copolymers by "in situ" chain extension at high conversion are reported.
Journal ArticleDOI
Improving the polarization-holography performance of PQ/PMMA photopolymer by doping with THMFA.
Fenglan Fan,Ying Liu,Yifan Hong,Jinliang Zang,An’an Wu,Tianbo Zhao,Guoguo Kang,Xiaodi Tan,Tsutomu Shimura +8 more
TL;DR: New method for increasing the saturated dissolvability of photosensitizer PQ within polymeric media by introducing copolymerization monomer into the PQ/PMMA is reported on.
References
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Journal ArticleDOI
Effect of DMSO used as solvent in copper mediated living radical polymerization
TL;DR: In this article, the use of DMSO as solvent for transition metal mediated living radical polymerization was investigated using copper (I) bromide/N-(n-propyl)-2-pyridyl-methanimine catalyst system and ethyl-2-bromoisobyrate as initiator.
Journal ArticleDOI
Atom transfer radical polymerisation (ATRP) of methyl methacrylate in the presence of radical inhibitors
David M. Haddleton,Andrew J. Clark,Martin C. Crossman,David J. Duncalf,Alex M. Heming,Stuart R. Morsley,Andrew J. Shooter +6 more
TL;DR: In this paper, the atom transfer radical polymerisation of methyl methacrylate mediated by copper(I) bromide, alkyl bromides and N-pentyl-2-pyridylmethanimine has been shown to be enhanced by the addition of substituted phenols, traditionally used as radical inhibitors.
Journal ArticleDOI
Atom-Transfer Radical Copolymerization of Furfuryl Methacrylate (FMA) and Methyl Methacrylate (MMA): A Thermally-Amendable Copolymer
TL;DR: In this paper, the reactivity ratios of furfuryl methacrylate (FMA) and MMA were determined using the Finemann-Ross and Kelen-Tudos linearization methods.
Journal ArticleDOI
Controlled/“Living” Radical Polymerization of Glycidyl Methacrylate at Ambient Temperature
R. Krishnan,K. S. V. Srinivasan +1 more
Journal ArticleDOI
Copper mediated living radical polymerisation: interactions between monomer and catalyst
TL;DR: In this paper, the exact nature of the catalyst is not well understood due to rapid exchange of ligand and monomer at the copper center under the polymerisation conditions, which complicate the accepted mechanism of this new and important reaction.
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