Journal ArticleDOI
Aqueous Compatible Protocol to Both Alkyl and Aryl Thioamide Synthesis.
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TLDR
An efficient aqueous synthesis of thioamides through aldehydes, sodium sulfide, and N-substituted formamides has been developed and the late-stage modification of bioactive molecules and derivatives through this protocol has been established.About:
This article is published in Organic Letters.The article was published on 2016-01-06. It has received 86 citations till now. The article focuses on the topics: Formamides & Sodium sulfide.read more
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Uses of K2S2O8 in Metal-Catalyzed and Metal-Free Oxidative Transformations
TL;DR: A comprehensive review of carbon-carbon/carbon-heteroatom bond formation via oxidative transformations aided with K2S2O8 in the presence or absence of a transition-metal catalyst, critical assessment of the results, and underlying mechanisms is provided in this article.
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Transition-Metal-Free Diarylannulated Sulfide and Selenide Construction via Radical/Anion-Mediated Sulfur–Iodine and Selenium–Iodine Exchange
TL;DR: A facile, straightforward protocol was established for diarylannulated sulfide and selenide construction through S-I and Se-I exchange without transition metal assistance.
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New Design of a Disulfurating Reagent: Facile and Straightforward Pathway to Unsymmetrical Disulfanes by Copper‐Catalyzed Oxidative Cross‐Coupling
TL;DR: The scaled-up experiments further indicated the practicality of this protocol and showed the pH value of the system plays a key role in achieving highly selective cleavage of the C-S bond instead of a S-S Bond in the transformation.
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Controllable Sulfoxidation and Sulfenylation with Organic Thiosulfate Salts via Dual Electron- and Energy-Transfer Photocatalysis
TL;DR: In this paper, a facile variation of the atmosphere under photocatalyzed conditions was used for sulfoxidation and sulfenylation for pharmaceuticals and sugar derivatives and switchable formal syntheses of sulfoxide/sulfide-containing marketed pharmaceuticals were switchably implemented.
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Recent developments in sulfur-carbon bond formation reaction involving thiosulfates.
TL;DR: This Perspective summarized recent research on sulfur-carbon bond formation involving thiosulfates and showed unique properties in many transformations of sulfur-containing organic molecules.
References
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C-H bond activation enables the rapid construction and late-stage diversification of functional molecules
TL;DR: This Perspective highlights the potential of metal-catalysed C-H bond activation reactions, which now extend beyond the field of traditional synthetic organic chemistry, and are more atom- and step-economical than previous methods.
Book
Comprehensive organic functional group transformations II
TL;DR: In this article, the synthesis of carbon with no attached heteroatoms was studied, as well as carbon with two attached heteroams with at least one carbon-to-heteroatom multiple link.
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Green chemistry oriented organic synthesis in water
Marc‐Olivier Simon,Chao-Jun Li +1 more
TL;DR: This tutorial review briefly discusses organic synthesis in water with a Green Chemistry perspective.
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