Journal ArticleDOI
Asymmetric induction in the Claisen rearrangement of N-allylketene N,O-acetals
TLDR
In this article, the transposition of alkyl-4 allyl-3 phenethylidene-2 oxazolidines en alkykl-4 benzyl-1' butene-3' yl 2 oxazolines was studied.Abstract:
On etudie la transposition des alkyl-4 allyl-3 phenethylidene-2 oxazolidines en alkyl-4 benzyl-1' butene-3' yl-2 oxazolines-2read more
Citations
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Journal ArticleDOI
1,2-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis
Journal ArticleDOI
The chemistry of 2-oxazolines (1985–present)
Thomas G. Gant,Albert I. Meyers +1 more
TL;DR: The use of chiral oxazolines as ligands in asymmetric catalysis has been extensively studied in the literature as mentioned in this paper, with a large number of important publications detailing oxazoline-related chemistry, suggesting that research in this area, as in synthetic organic chemistry in general, has yet to mature.
Journal ArticleDOI
Improved Catalysts for the Palladium-Catalyzed Synthesis of Oxindoles by Amide α-Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric Transformations
Sunwoo Lee,John F. Hartwig +1 more
TL;DR: Mechanistic studies showed that the reaction involves rate-limiting oxidative addition of aryl halide, and use of new, optically active heterocyclic carbene ligands gave substantial enantioselectivity in formation of an alpha,alpha-disubstituted oxindole.
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