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Biokatalytische Oxidationsreaktionen - aus der Sicht eines Chemikers

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This article is published in Angewandte Chemie.The article was published on 2018-07-20 and is currently open access. It has received 97 citations till now.

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Journal ArticleDOI

Biocatalysis: Enzymatic Synthesis for Industrial Applications

TL;DR: A review of biocatalysis with a special focus on scalable chemical production using enzymes discusses the opportunities and limitations of enzymatic syntheses using distinct examples and provides an outlook on emerging enzyme classes.
Journal ArticleDOI

Broadening the Scope of Biocatalysis in Sustainable Organic Synthesis

TL;DR: This Review is aimed at synthetic organic chemists who may be familiar with organometallic catalysis but have no experience with biocatalysis, and seeks to provide an answer to the perennial question: if it is so attractive, why wasn't it extensively used in the past?
Journal ArticleDOI

Catalytic Aerobic Oxidation of C(sp3 )-H Bonds.

TL;DR: This review presents an overview of the most important catalytic systems recently described for aerobic oxidation, and the current insight in their reaction mechanism.
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Biocatalysis Fueled by Light: On the Versatile Combination of Photocatalysis and Enzymes

TL;DR: This review provides an overview of the wide variety of photo‐biocatalysis, ranging from the photochemical delivery of electrons required in redox bioc atalysis and photochemical cofactor and reagent (re)generation to direct photoactivation of enzymes enabling reactions unknown in nature.
References
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Journal ArticleDOI

Engineering the third wave of biocatalysis

TL;DR: Applications of protein-engineered biocatalysts ranging from commodity chemicals to advanced pharmaceutical intermediates that use enzyme catalysis as a key step are discussed.
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Aromatic hydrocarbon dioxygenases in environmental biotechnology

TL;DR: Aromatic hydrocarbon dioxygenases have a broad substrate specificity and catalyze enantiospecific reactions with a wide range of substrates and make them attractive synthons for the production of industrially and medically important chiral chemicals.
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Cytochrome P450 monooxygenases: an update on perspectives for synthetic application.

TL;DR: A short up-to-date overview of recent results on P450 engineering for technical applications including aspects of whole-cell biocatalysis with engineered recombinant enzymes and recently identified P450s with novel biotechnologically relevant properties are given.
Journal ArticleDOI

Artificial Biocatalytic Linear Cascades for Preparation of Organic Molecules

TL;DR: The review introduces a systematic classification of the cascades according to the number of enzymes in the linear sequence and differentiates between cascades involving exclusively enzymes and combinations of enzymes with non-natural catalysts or chemical steps.
Journal ArticleDOI

Flavin dependent monooxygenases.

TL;DR: An update of the classification of flavin-dependent monooxygenases is presented and the latest advances in the understanding of their catalytic and structural properties are summarized.
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