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Journal ArticleDOI

Brønsted acid ionic liquid-catalyzed reductive Friedel–Crafts alkylation of indoles and cyclic ketones without using an external reductant

TLDR
In the absence of an external reductant, C3-cycloalkylated indole could be synthesized through reductive alkylation of indole with cyclic ketone using a sulfonyl-functionalized Bronsted acid ionic liquid as a catalyst as mentioned in this paper.
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This article is published in Green Chemistry.The article was published on 2015-02-09. It has received 106 citations till now. The article focuses on the topics: Friedel–Crafts reaction & Alkylation.

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Acidic Ionic Liquids.

TL;DR: This article provides a comprehensive review on applications of acidic ionic liquids in a wide array of fields including catalysis, CO2 fixation, ionogel, electrolyte, fuel-cell, membrane, biomass processing, biodiesel synthesis, desulfurization of gasoline/diesel, metal processing, and metal electrodeposition.
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Recent advances in the application of deep eutectic solvents as sustainable media as well as catalysts in organic reactions

TL;DR: Deep eutectic solvents (DESs) have become more and more attractive in recent years due to their interesting properties and benefits, such as low cost of components, easy to prepare, tunable physicochemical properties, negligible vapor pressure, non-toxicity, biorenewability and biodegradability as mentioned in this paper.
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Carbon-Increasing Catalytic Strategies for Upgrading Biomass into Energy-Intensive Fuels and Chemicals

TL;DR: In this article, the authors systematically describe the recent examples on the selective synthesis of long-chain oxygenates via different C-C coupling catalytic processes, such as Aldol condensation, hydroalkylation/alkylization, oligomerization, keto...
Journal ArticleDOI

Brønsted acidic ionic liquids: Green catalysts for essential organic reactions

TL;DR: In this article, a review of the applications of BAILs as clean and versatile replacements for the traditional homogeneous acid catalysts such as H2SO4, HCl and H3PO4 is presented.
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Hydrophilic mesoporous poly(ionic liquid)-supported Au–Pd alloy nanoparticles towards aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions

TL;DR: In this article, an Au-Pd alloy NPs supported on hydrophilic mesoporous poly(ionic liquid) (MPIL) exhibited encouragingly high performance in the aerobic oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) in water under mild conditions.
References
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Journal ArticleDOI

Catalytic Functionalization of Indoles in a New Dimension

TL;DR: This Review emphasizes the achievements in the selective catalytic functionalization of indoles (C-C bond-forming processes) over the last four years.
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Bis- and Trisindolylmethanes (BIMs and TIMs)†

TL;DR: The main purpose of this review is to provide a comprehensive summary of the various synthetic strategies to synthesize BIMs and TIMs.
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Faldaprevir and deleobuvir for HCV genotype 1 infection.

TL;DR: The rate of a sustained virologic response 12 weeks after the completion of therapy was 52 to 69% among patients who received interferon-free treatment with faldaprevir in combination with deleobuvir plus ribavirin.
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