Journal ArticleDOI
Cage effects in organotransition metal chemistry: their importance in the kinetic estimation of bond dissociation energies in solution
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TLDR
In this paper, a review of the literature of radical cage effects in solution is presented, and the available evidence for the operation of solvent cage effect in organotransition metal chemistry is summarized.About:
This article is published in Polyhedron.The article was published on 1988-01-01. It has received 75 citations till now. The article focuses on the topics: Cage effect & Solvation.read more
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Journal ArticleDOI
Catalytic chain transfer in free-radical polymerizations.
Journal ArticleDOI
Theoretical Prediction of the Co−C Bond Strength in Cobalamins
Kasper P. Jensen,Ulf Ryde +1 more
TL;DR: In this paper, the authors investigate why earlier density functional estimations of the BDE in methylcobalamin have given so poor results (91−117 kJ/mol) compared to the experimental estimate (155 ± 13 kj/mol).
Journal ArticleDOI
Theoretical Study on Monoligated Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides and Bromides
TL;DR: In this paper, the mechanism of aryl halides addition to Pd(PR3)2 (R = Me, Et, iPr, tBu, Ph) was investigated by using density functional theory methods enhanced with a polarized continuum solvation model.
Journal ArticleDOI
A review of the kinetics and mechanisms of formation of supported-nanoparticle heterogeneous catalysts
TL;DR: A review of the existing literature of the mechanisms of formation of practical, non-ultra high vacuum, supported-nanoparticle heterogeneous catalysts can be found in this paper.
References
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Journal ArticleDOI
Hydrocarbon Bond Dissociation Energies
TL;DR: The best available values for homolytic bond dissociation energies (BDEs) of various classes of neutral compounds are considered in a review as mentioned in this paper, focusing on prototypical radicals whose heats of formation, formerly thought to be well in hand, have recently been called into serious question.
Book
Principles and applications of organotransition metal chemistry
TL;DR: A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
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