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Journal ArticleDOI

Ceramic Fuel Cells

Nguyen Q. Minh
- 01 Mar 1993 - 
- Vol. 76, Iss: 3, pp 563-588
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TLDR
Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications as mentioned in this paper, and the critical issues posed by the development of this type of fuel cell are discussed.
Abstract
A ceramic fuel cell in an all solid-state energy conversion device that produces electricity by electrochemically combining fuel and oxidant gases across an ionic conducting oxide. Current ceramic fuel cells use an oxygen-ion conductor or a proton conductor as the electrolyte and operate at high temperatures (>600°C). Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications. This paper reviews the science and technology of ceramic fuel cells and discusses the critical issues posed by the development of this type of fuel cell. The emphasis is given to the discussion of component materials (especially, ZrO2 electrolyte, nickel/ZrO2 cermet anode, LaMnO3 cathode, and LaCrO3 interconnect), gas reactions at the electrodes, stack designs, and processing techniques used in the fabrication of required ceramic structures.

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Citations
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Journal ArticleDOI

A screen-printed Ce0.8Sm0.2O1.9 film solid oxide fuel cell with a Ba0.5Sr0.5Co0.8Fe0.2O3−δ cathode

TL;DR: In this paper, screenprinting technology was developed to fabricate Ce 0.8 Sm 0.2 O 1.9 (SDC) electrolyte films onto porous NiO-SDC green anode substrates.
Journal ArticleDOI

Optimisation parameters for the extrusion of thin YSZ tubes for SOFC electrolytes

TL;DR: In this article, an economic and practical process was developed to achieve smooth, linear, and dense ceramic tubes with 2.7-2.8 mm diameter, and the microstructures of the selected tubes were examined.
Journal ArticleDOI

Synthesis and characterization of electrolytes based on BaO–CeO2–GdO1.5 system for Intermediate Temperature Solid Oxide Fuel Cells

TL;DR: In this article, composite electrolytes for Intermediate Temperature Solid Oxide Fuel Cell (ITSOFC) based on BaO-CeO 2 -GdO 1.5 ternary system have been synthesized through conventional solid state reaction route.
Journal ArticleDOI

Processing microstructure property correlation of porous Ni-YSZ cermets anode for SOFC application

TL;DR: In this paper, microstructural properties and electrical conductivity of cermets prepared by a solid-state technique, a liquid-dispersion technique and a novel electroless coating technique were investigated.
Journal ArticleDOI

Assessment of nickel cermets and La0.8Sr0.2Sc0.2Mn0.8O3 as solid-oxide fuel cell anodes operating on carbon monoxide fuel

TL;DR: In this article, the phase instability of LSSM in pure CO atmosphere was investigated for SOFCs operating on CO, and the degradation was observed for all three cells operating on pure CO which is irreversible for the cell with Ni-SDC anode while largely reversible for Ni-ScSZ anode.
References
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Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Study of solid electrolyte polarization by a complex admittance method

TL;DR: In this paper, the polarization behavior of zirconia-yttria solid electrolyte specimens with platinum electrodes has been studied over a temperature range of 400° to 800°C and a wide range of oxygen partial pressures.
Journal ArticleDOI

Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production

TL;DR: In this article, sintered oxides based on SrCeO3 were found to exhibit proton conduction on exposing them to a hydrogen-containing atmosphere at high temperature.
Journal ArticleDOI

Perovskite-type oxides as oxygen electrodes for high temperature oxide fuel cells

TL;DR: Polarization and electrical conductivity measurements were made at 800°C in open air using the perovskite-type oxides La 1− x Sr x MO 3 (M  Cr, Mn, Fe, Co) sputtered on ytteia stabilized zirconia electrolyte.
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