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Journal ArticleDOI

Ceramic Fuel Cells

Nguyen Q. Minh
- 01 Mar 1993 - 
- Vol. 76, Iss: 3, pp 563-588
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TLDR
Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications as mentioned in this paper, and the critical issues posed by the development of this type of fuel cell are discussed.
Abstract
A ceramic fuel cell in an all solid-state energy conversion device that produces electricity by electrochemically combining fuel and oxidant gases across an ionic conducting oxide. Current ceramic fuel cells use an oxygen-ion conductor or a proton conductor as the electrolyte and operate at high temperatures (>600°C). Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications. This paper reviews the science and technology of ceramic fuel cells and discusses the critical issues posed by the development of this type of fuel cell. The emphasis is given to the discussion of component materials (especially, ZrO2 electrolyte, nickel/ZrO2 cermet anode, LaMnO3 cathode, and LaCrO3 interconnect), gas reactions at the electrodes, stack designs, and processing techniques used in the fabrication of required ceramic structures.

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Citations
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Journal ArticleDOI

LnBaCo2O5+δ oxides as cathodes for intermediate-temperature solid oxide fuel cells

TL;DR: In this paper, the LnBaCo 2 O 5+δ oxides with a cation ordered perovskite structure have been investigated as cathode materials for intermediate-temperature solid oxide fuel cells (SOFCs).
Journal ArticleDOI

Applications of metal–organic coordination polymers as precursors for preparation of nano-materials

TL;DR: A review of the literature concludes that coordination polymers are suitable precursors for production of nanoscale materials with optimized morphologies and properties as mentioned in this paper, and summarizes the effects of various factors such as structure, temperature, morphology and size of precursor on the morphology and the size of the nano-materials produced.
Journal ArticleDOI

Quantification of SOFC anode microstructure based on dual beam FIB-SEM technique

TL;DR: In this article, the three-dimensional microstructure of an SOFC anode is quantified using a dual beam focused ion beam scanning electron microscopy (FIB-SEM) system equipped with an energy dispersive X-ray spectroscopy (EDX) unit.
Journal ArticleDOI

Synthesis and Characterization of ( La0.75Sr0.25 ) Cr0.5Mn0.5 O 3 − δ , a Redox-Stable, Efficient Perovskite Anode for SOFCs

TL;DR: In this paper, the anode of the solid oxide fuel cells (SOFCs) was shown to be chemically compatible with yttria-stabilized zirconia (YSZ) to at least 1300°C.
Journal ArticleDOI

Thermal expansion coefficient of yttria stabilized zirconia for various yttria contents

TL;DR: In this article, the thermal expansion coefficient of yttria stabilized zirconia (YSZ) with the Y 2 O 3 content of 3, 6, 8 and 10 mol% were measured using a push-rod type dilatometer in the temperature range from 103 to 876 K.
References
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Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Study of solid electrolyte polarization by a complex admittance method

TL;DR: In this paper, the polarization behavior of zirconia-yttria solid electrolyte specimens with platinum electrodes has been studied over a temperature range of 400° to 800°C and a wide range of oxygen partial pressures.
Journal ArticleDOI

Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production

TL;DR: In this article, sintered oxides based on SrCeO3 were found to exhibit proton conduction on exposing them to a hydrogen-containing atmosphere at high temperature.
Journal ArticleDOI

Perovskite-type oxides as oxygen electrodes for high temperature oxide fuel cells

TL;DR: Polarization and electrical conductivity measurements were made at 800°C in open air using the perovskite-type oxides La 1− x Sr x MO 3 (M  Cr, Mn, Fe, Co) sputtered on ytteia stabilized zirconia electrolyte.
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