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Journal ArticleDOI

Ceramic Fuel Cells

Nguyen Q. Minh
- 01 Mar 1993 - 
- Vol. 76, Iss: 3, pp 563-588
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TLDR
Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications as mentioned in this paper, and the critical issues posed by the development of this type of fuel cell are discussed.
Abstract
A ceramic fuel cell in an all solid-state energy conversion device that produces electricity by electrochemically combining fuel and oxidant gases across an ionic conducting oxide. Current ceramic fuel cells use an oxygen-ion conductor or a proton conductor as the electrolyte and operate at high temperatures (>600°C). Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications. This paper reviews the science and technology of ceramic fuel cells and discusses the critical issues posed by the development of this type of fuel cell. The emphasis is given to the discussion of component materials (especially, ZrO2 electrolyte, nickel/ZrO2 cermet anode, LaMnO3 cathode, and LaCrO3 interconnect), gas reactions at the electrodes, stack designs, and processing techniques used in the fabrication of required ceramic structures.

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Citations
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Journal ArticleDOI

Effect of microstructure on oxygen permeation in SrCo0.8Fe0.2O3-δ

TL;DR: In this paper, the effect of microstructure on oxygen permeation in SrCo0.8Fe0.2O3−δ membranes was investigated using disc samples fabricated under different processing conditions of applied pressure and sintering temperature.
Journal ArticleDOI

Composite cathode La0.6Sr0.4Co0.2Fe0.8O3-Sm0.1Ce0.9O1.95-Ag for intermediate-temperature solid oxide fuel cells

TL;DR: In this paper, a composite LSCF-SDC-Ag cathode was prepared and its structure was analyzed by X-ray diffraction, and it was found that adding Ag in the cathode improved the SOFC performance significantly.
Journal ArticleDOI

Evaluation of commercial nickel oxide powders for components in solid oxide fuel cells

TL;DR: In this article, various commercial nickel oxides were examined with respect to their relevant powder properties for application as anodes or anode substrates in solid oxide fuel cells (SOFC).
Journal ArticleDOI

Fabrication and performance of Ni/3 mol% Y2O3–ZrO2 cermet anodes for solid oxide fuel cells

TL;DR: In this article, a fabrication method for the preparation of Ni/3 mol% Y 2 O 3 -ZrO 2 (Ni/TZ3Y) cermet electrodes from various commercial powders has been described.
Journal ArticleDOI

Rapid synthesis of perovskite-type LaFeO3 nanoparticles by microwave-assisted decomposition of bimetallic La[Fe(CN)6]·5H2O compound

TL;DR: In this article, nano-sized and pure single-phase perovskite-type LaFeO3 powders were synthesized within a very short reaction time of 4min via the decomposition of bimetallic La[Fe(CN)6]·5H2O compound using microwave irradiation (2.45 GHz, 900 W).
References
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Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Study of solid electrolyte polarization by a complex admittance method

TL;DR: In this paper, the polarization behavior of zirconia-yttria solid electrolyte specimens with platinum electrodes has been studied over a temperature range of 400° to 800°C and a wide range of oxygen partial pressures.
Journal ArticleDOI

Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production

TL;DR: In this article, sintered oxides based on SrCeO3 were found to exhibit proton conduction on exposing them to a hydrogen-containing atmosphere at high temperature.
Journal ArticleDOI

Perovskite-type oxides as oxygen electrodes for high temperature oxide fuel cells

TL;DR: Polarization and electrical conductivity measurements were made at 800°C in open air using the perovskite-type oxides La 1− x Sr x MO 3 (M  Cr, Mn, Fe, Co) sputtered on ytteia stabilized zirconia electrolyte.
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