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Journal ArticleDOI

Ceramic Fuel Cells

Nguyen Q. Minh
- 01 Mar 1993 - 
- Vol. 76, Iss: 3, pp 563-588
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TLDR
Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications as mentioned in this paper, and the critical issues posed by the development of this type of fuel cell are discussed.
Abstract
A ceramic fuel cell in an all solid-state energy conversion device that produces electricity by electrochemically combining fuel and oxidant gases across an ionic conducting oxide. Current ceramic fuel cells use an oxygen-ion conductor or a proton conductor as the electrolyte and operate at high temperatures (>600°C). Ceramic fuel cells, commonly referred to as solid-oxide fuel cells (SOFCs), are presently under development for a variety of power generation applications. This paper reviews the science and technology of ceramic fuel cells and discusses the critical issues posed by the development of this type of fuel cell. The emphasis is given to the discussion of component materials (especially, ZrO2 electrolyte, nickel/ZrO2 cermet anode, LaMnO3 cathode, and LaCrO3 interconnect), gas reactions at the electrodes, stack designs, and processing techniques used in the fabrication of required ceramic structures.

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Citations
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Journal ArticleDOI

Effect of Ni content in SOFC Ni-YSZ cermets: A three-dimensional study by FIB-SEM tomography

TL;DR: In this paper, serial sectioning using focused ion beam-scanning electron microscopy (FIB-SEM) has been implemented to reconstruct the three-dimensional microstructure of SOFC anodic cermets with varying Ni concentrations.
Journal ArticleDOI

Estimation of Charge-Transfer Resistivity of La0.8Sr0.2MnO3 Cathode on Y 0.16Zr0.84 O 2 Electrolyte Using Patterned Electrodes

TL;DR: In this article, the authors used photomicrolithography to obtain the impedance spectra for half-cells under oxygen partial pressures; p O 2, ranging from 10 - 3 to 1 atm and temperatures from 650 to 800°C.
Journal ArticleDOI

Preparation of NiO–YSZ tubular support with radially aligned pore channels

TL;DR: In this article, a porous NiO-YSZ tubular support with radially aligned pore channels was prepared by freeze-drying of a water-based slurry, controlling the growth direction of the ice, and it was sublimated at a reduced pressure.
Journal ArticleDOI

Characterization and evaluation of double perovskites LnBaCoFeO 5+δ (Ln = Pr and Nd) as intermediate-temperature solid oxide fuel cell cathodes

TL;DR: In this paper, double perovskites LnBaCoFeO5+δ (Ln=Pr and Nd, PBCF and NBCF) are comparatively investigated as potential cathode materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs).
Journal ArticleDOI

Dopants to enhance SOFC cathodes based on Sr-doped LaFeO3 and LaMnO3

TL;DR: The influence of various infiltrated dopants on the performance of solid oxide fuel cell (SOFC) cathodes was examined in this paper, where the cathodes were prepared by infiltration of nitrate salts into porous yttria-stabilized zirconia (YSZ) to produce composites with 40-wt% of either La 0.8 Sr 0.2 FeO 3 (LSF) or La 1.2 MnO 3(LSM) and were then calcined to either 1123 or 1373 K. The addition of dopants had little
References
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Journal ArticleDOI

Theory of the role of covalence in the perovskite-type manganites [La,M(II)]MnO3

TL;DR: In this article, the theory of double exchange was applied to perovskite-type manganites and detailed qualitative predictions about the magnetic lattice, the crystallographic lattice and the electrical resistivity were made.
Journal ArticleDOI

Study of solid electrolyte polarization by a complex admittance method

TL;DR: In this paper, the polarization behavior of zirconia-yttria solid electrolyte specimens with platinum electrodes has been studied over a temperature range of 400° to 800°C and a wide range of oxygen partial pressures.
Journal ArticleDOI

Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production

TL;DR: In this article, sintered oxides based on SrCeO3 were found to exhibit proton conduction on exposing them to a hydrogen-containing atmosphere at high temperature.
Journal ArticleDOI

Perovskite-type oxides as oxygen electrodes for high temperature oxide fuel cells

TL;DR: Polarization and electrical conductivity measurements were made at 800°C in open air using the perovskite-type oxides La 1− x Sr x MO 3 (M  Cr, Mn, Fe, Co) sputtered on ytteia stabilized zirconia electrolyte.
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