Journal ArticleDOI
Chemical conversion pathways for carbohydrates
TLDR
A review of the recent developments in liquid phase chemical conversions of monosaccharides, disaccharide, and polysaccharides can be found in this paper, followed by a process-driven approach where the existing carbohydrate conversion pathways are classified according to the types of chemical processes involved.About:
This article is published in Green Chemistry.The article was published on 2015-01-01. It has received 271 citations till now.read more
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Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids
TL;DR: This review focuses on the catalytic chemical conversion of lignocellulose and its primary ingredients into value-added chemicals and fuel products using ILs as the reaction media.
Journal ArticleDOI
Adsorption Behavior of Glucosamine-Based, Pyrimidine-Fused Heterocycles as Green Corrosion Inhibitors for Mild Steel: Experimental and Theoretical Studies
TL;DR: In this article, the effects of electron donating (−CH3 and −OH) and electron withdrawing (−NO2) substituents on the corrosion inhibition efficiency of four glucosamine-based, substituted, pyrimidine-fused heterocycles (CARBs) on mild steel corrosion in 1 M HCl have been investigated using gravimetric, electrochemical, surface morphology (SEM, AFM, and EDX), and computational techniques.
Journal ArticleDOI
Recent advances in hydrodeoxygenation of biomass-derived oxygenates over heterogeneous catalysts
Soosan Kim,Eilhann E. Kwon,Yong Tae Kim,Sungyup Jung,Hyung Ju Kim,George W. Huber,Jechan Lee +6 more
TL;DR: In this paper, the roles of different catalytic sites in Hydrodeoxygenation (HDO) and strategies to stabilize these active sites are discussed, and points to be considered for further research into HDO over heterogeneous catalysts and pending challenges are discussed.
Journal ArticleDOI
Organic Solvent Effects in Biomass Conversion Reactions.
Li Shuai,Jeremy S. Luterbacher +1 more
TL;DR: A holistic view of solvent effects, the mechanistic elucidation of these effects, and the careful consideration of the challenges associated with solvent use could assist researchers in choosing and designing improved solvent systems for targeted biomass conversion processes.
Journal ArticleDOI
An overview of biorefinery-derived platform chemicals from a cellulose and hemicellulose biorefinery
TL;DR: This review article provides an overview of the techniques developed for the valorization of biomass in the production of platform chemicals within a biorefinery and the status for commercialization.
References
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Selective production of chemicals from biomass pyrolysis over metal chlorides supported on zeolite.
TL;DR: The synergistic effect of HZSM-5 and ZnCl2, which combines pyrolysis, zeolite cracking, and Lewis acid-selective catalysis results in highly efficient bagasse conversion into FF and AC.
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One‐Pot Conversions of Raffinose into Furfural Derivatives and Sugar Alcohols by Using Heterogeneous Catalysts
TL;DR: The one-pot synthesis of furan derivatives and sugar alcohols from raffinose by using heterogeneous acid, base, and/or metal-supported catalysts is demonstrated and it is suggested that r Affinose has great potential for the synthesis of important industrial intermediates under mild reaction conditions.
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Recycling in telomerization of butadiene withD-xylose: Pd(TPPTS)n-KF/Al2O3 as an active catalyst
TL;DR: A palladium-TPPTS catalyst heterogenized on KF/alumina has been shown to be effective and recyclable for the selective formation of monooctadienylxylopyranosides via the telomerization of butadiene with D-xylose as mentioned in this paper.
Journal ArticleDOI
An unexpected reaction between 5-hydroxymethylfurfural and imidazolium-based ionic liquids at high temperatures.
TL;DR: The results provided new insights in terms of side reactions between HMF and imidazolium-based ionic liquids, which should be valuable for designing better processes for the production of furans using biomass and related materials.
Journal ArticleDOI
Hydrophobication and characterisation of O-acetyl-galactoglucomannan for papermaking and barrier applications
Victor Kisonen,Patrik Eklund,Markku Auer,Rainer Sjöholm,Andrey Pranovich,Jarl Hemming,Anna Sundberg,Vladimir Aseyev,Stefan Willför +8 more
TL;DR: Novel substances with adjusted hydrophobicity can be prepared on one step synthesis from natural hemicelluloses, which then showed a slight increase in the molar mass upon esterification.