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Journal ArticleDOI

Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids

Zhanrong Zhang, +2 more
- 24 May 2017 - 
- Vol. 117, Iss: 10, pp 6834-6880
TLDR
This review focuses on the catalytic chemical conversion of lignocellulose and its primary ingredients into value-added chemicals and fuel products using ILs as the reaction media.
Abstract
Innovative valorization of naturally abundant and renewable lignocellulosic biomass is of great importance in the pursuit of a sustainable future and biobased economy. Ionic liquids (ILs) as an important kind of green solvents and functional fluids have attracted significant attention for the catalytic transformation of lignocellulosic feedstocks into a diverse range of products. Taking advantage of some unique properties of ILs with different functions, the catalytic transformation processes can be carried out more efficiently and potentially with lower environmental impacts. Also, a new product portfolio may be derived from catalytic systems with ILs as media. This review focuses on the catalytic chemical conversion of lignocellulose and its primary ingredients (i.e., cellulose, hemicellulose, and lignin) into value-added chemicals and fuel products using ILs as the reaction media. An outlook is provided at the end of this review to highlight the challenges and opportunities associated with this interes...

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Citations
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Journal ArticleDOI

Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability

TL;DR: Recent advances and developments in catalytic transformations of the carbohydrate content of lignocellulosic biomass to IPCs (i.e., ethanol, 3-hydroxypropionic acid, isoprene, succinic and levulinic acids, furfural, and 5-hydroxymethylfurfural) are overviewed.
Journal ArticleDOI

Ionic liquids: a brief history

TL;DR: In this article, a little of how interest in ionic liquids grew and developed is shown.
Journal ArticleDOI

Ionic liquids synthesis and applications: An overview

TL;DR: The comprehensive study summarizes the latest progress on assorted classes of ILs along with discussing their prospective applications in the first half and the synthesis of homo/heterogeneous ILs is thoroughly elaborated in the second half.
Journal ArticleDOI

Recent catalytic routes for the preparation and the upgrading of biomass derived furfural and 5-hydroxymethylfurfural

TL;DR: The conversion of biomass derived FUR and HMF through unconventional (transfer hydrogenation, photocatalytic and electrocatalytic) catalytic processes promoted by heterogeneous catalytic systems are discussed.
References
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Journal ArticleDOI

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Journal ArticleDOI

Features of promising technologies for pretreatment of lignocellulosic biomass.

TL;DR: This paper reviews process parameters and their fundamental modes of action for promising pretreatment methods and concludes that pretreatment processing conditions must be tailored to the specific chemical and structural composition of the various, and variable, sources of lignocellulosic biomass.
Journal ArticleDOI

Ionic Liquids-New "Solutions" for Transition Metal Catalysis.

TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
Journal ArticleDOI

Chemical Routes for the Transformation of Biomass into Chemicals

TL;DR: Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481 4.2.1.
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