scispace - formally typeset
Book ChapterDOI

Chemical Modifications of Chitin and Chitosan

Keisuke Kurita
- 01 Jan 1986 - 
- Vol. 18, Iss: 42, pp 287-293
TLDR
Chitin can be regarded as a new type of polymeric material having greater possibilities than cellulose in many respects as discussed by the authors, since it is an amino polysaccharide, it is capable of undergoing many additional modification reactions.
Abstract
Although chitin may be less advanced than cellulose with regard to research and utilization, it has recently begun to attract much attention in both basic and applied research fields, including not only biology and biochemistry but also organic and polymer chemistry, pharmacology, and medicine. The number of reports and patents is increasing at a remarkable rate. Besides basic research, many attempts have been made to find new applications for chitin. Further basic studies, however, seem to be necessary to realize its full potential. One possible breakthrough in chitin chemistry and technology is the development of chemical modifications of chitin which are being studied more and more actively to explore highly sophisticated functions. Chitin can be regarded as a new type of polymeric material having greater possibilities than cellulose in many respects. Since it is an amino polysaccharide, chitin is capable of undergoing many additional modification reactions. It is anticipated that widespread applications will be found in the near future.

read more

Citations
More filters
Journal ArticleDOI

Chitin and chitosan polymers: Chemistry, solubility and fiber formation

TL;DR: In this paper, a review discusses the various attempts reported on solving this problem from the point of view of the chemistry and the structure of these polymers highlighting the drawbacks and advantages of each method and proposes that based on considerations of structure-property relations, it is possible to obtain chitin fibers with improved strength by making use of their nanostructures and/or mesophase properties of chitins.
Journal ArticleDOI

Food applications of chitin and chitosans

TL;DR: Application of chitinous products in foods and pharmaceuticals as well as processing aids has received considerable attention in recent years as exotic synthetic compounds are losing their appeal.
Journal ArticleDOI

Chitosan-based gastrointestinal delivery systems

TL;DR: Chitosan appears to be a promising material for GI drug and gene delivery applications as many derivatives and formulations are being examined.
Journal ArticleDOI

Marine Derived Polysaccharides for Biomedical Applications: Chemical Modification Approaches

TL;DR: The results of the recent work concerning various different approaches and applications of polysaccharide-based biomaterials are reported, such as the realization of novel composites based on calcium sulphate blended with alginate and with a chemically modified chitosan, the synthesis of novelAlginate-poly(ethylene glycol) copolymers and the development of a family of materials based on alginates and acrylic polymers of potential interest as drug delivery systems.
Journal ArticleDOI

A Biopolymer Chitosan and Its Derivatives as Promising Antimicrobial Agents against Plant Pathogens and Their Applications in Crop Protection

TL;DR: In this paper, the authors present an overview of the antimicrobial effects, mechanisms, and applications of a biopolymer chitosan and its derivatives in crop protection, and take a closer look at the physiochemical properties and chemical modifications of chitosa molecule.
References
More filters
Journal ArticleDOI

Studies on chitin, 2. Effect of deacetylation on solubility

TL;DR: A reproducible method for obtaining water-soluble chitin and a relationship between solubility and degree of deacetylation of chitins were studied in this article.
Journal ArticleDOI

N-(carboxymethylidene)chitosans and N-(carboxymethyl)chitosans: Novel chelating polyampholytes obtained from chitosan glyoxylate

TL;DR: In this article, a series of N -(carboxymethyl)chitosans having various degrees of acetylation and N -carboxyethylation was obtained, and characterized by viscometry, elemental analysis, and i.r. spectrometry.
Journal ArticleDOI

Preparation and characterization of fully deacetylated chitosan

TL;DR: In this article, a new method for N-deacetylation of chitosan is proposed in which a polymer free of N-acetyl groups is obtained without much decrease in molecular weight.
Journal ArticleDOI

Studies on chitin, 4. Evidence for formation of block and random copolymers of N‐acetyl‐D‐glucosamine and D‐glucosamine by hetero‐ and homogeneous hydrolyses

TL;DR: In this paper, it was shown that the deacetylation under the heterogeneous conditions proceeded preferentially in the amorphous region to give block-type copolymers of N-acetyle-D-glucosamine and D-GLU units.