Journal ArticleDOI
Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OEt)3]4+. II. Reaction with 1,3-butadiene. Catalytic formation of hexadienes
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This article is published in Journal of the American Chemical Society.The article was published on 1970-11-01. It has received 85 citations till now. The article focuses on the topics: Nickel hydride & Catalysis.read more
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Ni[P(OPh)3]4 Catalyzed Transfer Hydrogenation Using Hcoonh4
Suresh Iyer,Aruna K. Sattar +1 more
TL;DR: Ni[P(OPh)3]4 was found to catalyze the transfer hydrogenation of various organic functional groups using HCOONH4 in this article, which was considered a breakthrough.
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Transition-metal complexes containing phosphorus ligands. Part XI. Cationic trialkyl phosphite derivatives of gold, silver and the platinum metals
D.A. Couch,Stephen D. Robinson +1 more
TL;DR: In this paper, a qualitative description of the coupling patterns observed in the proton n.m.r. spectra of these cations is given, and is interpreted in terms of ligand rearrangement, exchange and dissociation processes.
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Reaction Mechanism and Structure–Reactivity Relationships in the Stereospecific 1,4‐Polymerization of Butadiene Catalyzed by Neutral Dimeric Allylnickel(II) Halides [Ni(C3H5)X]2 (X−=Cl−, Br−, I−): A Comprehensive Density Functional Theory Study
Sven Tobisch,Rudolf Taube +1 more
TL;DR: The present investigation examines, in terms of located structures, energies and activation barriers, the participation of postulated intermediates and aimed to clarify whether monomeric or dimeric species are the catalytically active species.
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Intermediates in the palladium-catalysed reaction of 1,3-dienes Part 8. The reaction of palladium-butadiene complexes with ethyl methylacetoacetate
TL;DR: In this paper, the catalytic reaction of 1,3-butadiene with ethyl methylacetoacetate in the presence of Pd(R 2 P(CH 2 ) n PR 2 ) compounds has been investigated.