Journal ArticleDOI
Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OEt)3]4+. II. Reaction with 1,3-butadiene. Catalytic formation of hexadienes
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This article is published in Journal of the American Chemical Society.The article was published on 1970-11-01. It has received 85 citations till now. The article focuses on the topics: Nickel hydride & Catalysis.read more
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The production of man-made fibres
A. J. Hughes,J. E. McIntyre,G. Clayton,P. Wright,D. J. Poynton,J. Atkinson,P. E. Morgan,L. Rose,Patricia A. Stevenson,A. A. Mohajer,W. J. Ferguson +10 more
TL;DR: The manufacture and production of viscose rayon, acetate, nylon, polyester, acrylic, modacrylic, carbon, polyolefin, chlorofibers, alginate, polyvinyl alcohol, elastomeric and organic fibers are reviewed in this paper.
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Synthesis of cationic allyl- and dienecarbonyl complexes of group VI-VIII metals in the presence of strong protonic acid
TL;DR: Cationic diene complexes have been formed by the action of dienes and acid on compounds with a metal-metal bond or on neutral allyl complexes as mentioned in this paper, which is promoted by an increase in basicity of the initial complex and an increae in acidity.
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The Nickel-catalyzed Cyclodimerization of Butadiene. The Synthesis of 2-Methylenevinylcyclopentane and the Isomerization of 1,3,7-Octatriene
TL;DR: In this article, a NiX2(R3P)2-NaBH4 or R′ONa (X=halogen, R and R′=alkyl) was found to yield 2-methylenevinylcyclopentane (MVCP) and n-octatrienes (OT), depending on the amount of NaBH 4 or RNAONa which act as a reducing agent for the nickel halide.
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Mechanism of the Chain Termination of the Allylnickel(II)-Catalyzed Polymerization of 1,3-Butadiene. A Density Functional Investigation for the Cationic [NiII(RC3H4)(cis-C4H6)L]+Active Catalyst
TL;DR: In this paper, alternative mechanisms of chain termination of the allylnickel (II)-catalyzed polymerization of 1,3-dienes were investigated by employing a gradient-corrected DFT method.
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Komplexkatalyse. XV. Kationische η3‐Allyl‐bis(triorganylphosphit)nickel(II)‐Komplexe als Katalysatoren für die stereoreguläre Butadienpolymerisation
TL;DR: In this article, the properties of PF6 complexes with tri-ethyl-, isopropyl-,phenyl-, -o-tolyl-, -thymyl- and o-biphenylylphosphite are described.