Journal ArticleDOI
Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OEt)3]4+. II. Reaction with 1,3-butadiene. Catalytic formation of hexadienes
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This article is published in Journal of the American Chemical Society.The article was published on 1970-11-01. It has received 85 citations till now. The article focuses on the topics: Nickel hydride & Catalysis.read more
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Journal ArticleDOI
Investigation of the individual stages of 2-alkylbutadiene polymerization with bis-(π-crotylnickel iodide)—II
TL;DR: In this article, the reaction orders with respect to the nickel complex were found to be close to unity and the rate constants of the formation and the anti-syn isomerization of 1,2-disubstituted π-allyl 1:1 adducts were determined and the activation energies of these reactions calculated.
Journal ArticleDOI
FAB and FD mass spectrometry of transition metal complexes
TL;DR: The FD and FAB mass spectra were obtained for the first time from a number of cationic η3-allylic complexes of palladium and nickel.
Journal ArticleDOI
Nickel-catalyzed reaction of butadiene with strained ring olefins
Book ChapterDOI
Mechanistic Studies of Catalytic Reactions Using Spectroscopic and Kinetic Techniques
Chad A. Tolman,Jack W. Faller +1 more
TL;DR: The rapid growth of the organometallic chemistry of the transition metals during the last 15-20 years owes much to the development of homogeneous catalyst systems which are capable of synthesizing organic molecules under mild conditions and occasionally with remarkable selectivities as mentioned in this paper.