Journal ArticleDOI
Chemistry of tetrakis(triethyl phosphite) nickel hydride, HNi[P(OEt)3]4+. II. Reaction with 1,3-butadiene. Catalytic formation of hexadienes
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This article is published in Journal of the American Chemical Society.The article was published on 1970-11-01. It has received 85 citations till now. The article focuses on the topics: Nickel hydride & Catalysis.read more
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Book ChapterDOI
Organometallic Reactions Involving Hydro-Nickel, -Palladium, and -Platinum Complexes
TL;DR: In this article, the authors discuss the involvement of hydro complexes in reactions, such as the isomerization, oligomerization and hydrogenation of unsaturated hydrocarbons, and discuss the reduction with hydrazine method, which was the first one used in the preparation of PtHCl(PEt3)2 from PtCl2(CAac)2.
Journal ArticleDOI
Lewis Acid Controlled Regioselectivity in Styrene Hydrocyanation
TL;DR: The mechanism of the Ni-catalyzed reaction and the influence of additional Lewis acids have been investigated by means of deuterium labeling experiments, NMR studies, and DFT calculations and the behavior of different Lewis acids could be rationalized and predicted by DFT calculation.
Journal ArticleDOI
Chemoselective reactions of (E)-1,3-dienes: cobalt-mediated isomerization to (Z)-1,3-dienes and reactions with ethylene.
TL;DR: A mechanism that involves an intramolecular hydride addition via an [η4-(diene)(LCo–H)]+ complex, followed by π–σ–π isomerization of the intermediate Co(allyl) species, is proposed for this reaction.
Journal ArticleDOI
Nickel-catalyzed amination of 1,3-dienes Evidence for a π-allyl intermediate
TL;DR: In this article, π-allyl intermediates are proposed as intermediates in the amination of 1,3-dienes, based on the stability of πallyl complexes which are assumed to be key intermediates.