Journal ArticleDOI
Chemoselective Derivatization of Folded Synthetic Insulin Variants with Potassium Acyltrifluoroborates (KATs)
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This article is published in Helvetica Chimica Acta.The article was published on 2018-12-13. It has received 8 citations till now. The article focuses on the topics: Derivatization & Chemoselectivity.read more
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Journal ArticleDOI
Synthesis of Acylboron Compounds
TL;DR: This Minireview provides an overview on the obstacles of acylboron synthesis and highlights notable advances within the last three years on new strategies to overcome the challenges posed by the formed acyl - boron bonds.
Journal ArticleDOI
Recent Advances in the Synthesis of Acylboranes and Their Widening Applicability.
TL;DR: An expanding array of their applications has been discovered, based on either the ability of acylboranes to enter rapid amide-forming ligations or the retained ketone-like character of the carbonyl group.
Journal ArticleDOI
Catalytic Synthesis of Potassium Acyltrifluoroborates (KATs) from Boronic Acids and the Thioimidate KAT Transfer Reagent.
TL;DR: The synthesis of potassium acyltrifluoroborates (KATs) is reported by a palladium-catalyzed cross-coupling of boronic acids and the thioimidate KAT transfer reagent, enabling the preparation of KATs in high yields and with good functional group tolerance.
Journal ArticleDOI
One-Step Synthesis of Acylborons from Acyl Chlorides through Copper-Catalyzed Borylation with Polystyrene-Supported PPh3 Ligand.
TL;DR: In this article , a one-step synthesis of acylborons from both readily available acyl chlorides and bis(pinacolato)diboron through copper(I)-catalyzed borylation was developed.