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Classification and consequences of complex lead perovskite ferroelectrics with regard to B-site cation order

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TLDR
In this paper, a classification of complex lead perovskites is presented based on the relative scale of long-range cation order, and the implications of Cation order in relation to relaxor and normal ferroelectric behavior are discussed.
Abstract
From a number of studies on ferroelectric and related materials based on complex lead perovskites [Pb(Bx′B1−x″)O3], it is apparent that the B-site cation order influences the crystallography, phase transitions, and other physical properties. A classification of complex lead perovskites is presented based on the relative scale of long-range cation order. In particular, we discuss the implications of cation order in relation to relaxor and normal ferroelectric behavior.

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Citations
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Journal ArticleDOI

Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals

TL;DR: In this article, the piezoelectric properties of relaxor based ferroelectric single crystals, such as Pb(Zn1/3Nb2/3)O3 and PbTiO3, were investigated for electromechanical actuators.
Journal ArticleDOI

Organometal halide perovskite solar cells: degradation and stability

TL;DR: In this paper, the causes of failure and associated mechanisms of device degradation, approaches to improve stability, and methods and protocols are discussed in detail and form the main focus of the review article.
Journal ArticleDOI

Freezing of the polarization fluctuations in lead magnesium niobate relaxors

TL;DR: In this article, the dielectric relaxation of a solid solution of lead titanate in lead magnesium niobate is found to be similar to the magnetic relaxation in spin-glass systems.
Journal ArticleDOI

A2B′B″O6 perovskites: A review

TL;DR: A survey of the literature for ca. one thousand B-site substituted perovskite oxides can be found in this article, together with their electronic and magnetic properties and properties.
Journal ArticleDOI

Characteristics of relaxor-based piezoelectric single crystals for ultrasonic transducers

TL;DR: In this article, relaxor-based materials with the general formula, Pb(B/sub 1/3/Nb/sub 2/3/)O/sub 3/PbTiO/Sub 3/ (PZN-PT), have been shown to have superior dielectric and piezoelectric performance compared to that of PZT materials.
References
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Book

Principles and Applications of Ferroelectrics and Related Materials

TL;DR: In this paper, the theory of ferroelectricity in terms of soft modes and lattice dynamics is developed and modern techniques of measurement, including X-ray, optic, and neutron scattering, infra-red absorption, and magnetic resonance.
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Dielectric and Piezoelectric Properties of 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 Single Crystals

TL;DR: In this article, the dielectric, piezoelectric and elastic properties of 0.91(PbZn1/3Nb2/3)O3−0.09PbTiO3 single crystals have been investigated as functions of temperature and applied electric field.
Journal ArticleDOI

Ordering Structure and Dielectric Properties of Undoped and La/Na-Doped Pb(Mg1/3Nb2/3)O3

TL;DR: In this article, transmission electron microscopy was used to study the ordered domain structures in undoped and La/Na-doped Pb(Mg1/3Nb2/3)O3 (PMN), where the compositions of the doped samples were specifically chosen so as to elucidate the ordering mechanism.
Journal ArticleDOI

Crystal structure of double oxides of the perovskite type

Helen D Megaw
TL;DR: The cell dimensions of double oxides belonging to the perovskite type have been accurately determined from examination of high-angle lines on x-ray powder photographs as discussed by the authors, and the structures found fall into groups, as follows: Cubic, tritone, and tritone.
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