Book ChapterDOI
Cleavage of Carbon—Carbon Single Bonds by Transition Metals
Masahiro Murakami,Yoshihiko Ito +1 more
TLDR
In this article, an overview of the field of carbon-carbon bond breaking is presented, including stoichiometric and catalytic reactions, especially those related to organic synthesis, and the first part deals with stochastic reactions involving carbon carbon bond breaking.Abstract:
Cleavage of carbon-carbon bonds by transition metals under homogeneous conditions has recently received much scientific and technological interest. In this review, an overview of this field is presented. The first part deals with stoichiometric reactions involving carbon-carbon bond breaking. The second part features catalytic reactions, especially those related to organic synthesis.read more
Citations
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Journal ArticleDOI
Catalytic C-C Bond Activations via Oxidative Addition to Transition Metals.
TL;DR: The cleavage and subsequent functionalization of the C-CN bonds and decarbonylation processes operating by an excision of carbon monoxide from ketone derivatives have witnessed a large progress.
Journal ArticleDOI
Chemical recycling to monomer for an ideal, circular polymer economy
TL;DR: In this paper, the authors present a vision for realizing a circular polymer economy based on Chemical Recycling to Monomer (CRM) and examine the energy efficiency of polymerization and other challenges in developing practical and scalable CRM processes.
Journal ArticleDOI
Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen
Wanqing Wu,Huanfeng Jiang +1 more
TL;DR: This work focuses on developing simple and efficient methods to construct new carbon-carbon and carbon-heteroatom bonds with O(2) as the oxidant and/or reactant and proposes several mechanistic scenarios that describe the in situ generation of different intermediates and discuss the plausible reaction pathways.
Journal ArticleDOI
Enantioselective palladium-catalyzed transformations
Journal ArticleDOI
"Cut and Sew" Transformations via Transition-Metal-Catalyzed Carbon-Carbon Bond Activation.
TL;DR: The transition metal-catalyzed "cut and sew" transformation has recently emerged as a useful strategy for preparing complex molecular structures.
References
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Journal ArticleDOI
Pentamethylcyclopentadienylrhodium and -iridium halides. I. Synthesis and properties
Journal ArticleDOI
CH and CC Bond Activation by Bare Transition‐Metal Oxide Cations in the Gas Phase
Detlef Schröder,Helmut Schwarz +1 more
TL;DR: In this paper, the gas-phase chemistry of bare transition-metal oxide cations MO+ has received considerable attention, mainly due to the particular role of metal oxides in the oxidation of organic compounds in a variety of chemical and biochemical transformations.
Journal ArticleDOI
Olefin polymerization at bis(pentamethylcyclopentadienyl)zirconium and -hafnium centers: chain-transfer mechanisms
TL;DR: In this article, a chain transfer via {beta}-CH{sub 3} elimination by a homogeneous bimetallic Ziegler-Natta propylene polymerization catalyst is reported.
Book ChapterDOI
Cyclopropenes and methylenecylopropanes as multifunctional reagents in transition metal catalyzed reactions
Paul Binger,Holger Michael Büch +1 more
TL;DR: The use of transition metal catalysts allows an effective control of their transformations enabling highly selecitive syntheses ranging from three-to seven-membered carbocycles as mentioned in this paper.