Journal ArticleDOI
Coarsening in Sintering: Grain Shape Distribution, Grain Size Distribution, and Grain Growth Kinetics in Solid-Pore Systems
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Sintering occurs when packed particles are heated to a temperature where there is sufficient atomic motion to grow bonds between the particles as mentioned in this paper, and the conditions that induce sintering depend on the material, its melting temperature, particle size, and a host of processing variables.Abstract:
Sintering occurs when packed particles are heated to a temperature where there is sufficient atomic motion to grow bonds between the particles The conditions that induce sintering depend on the material, its melting temperature, particle size, and a host of processing variables It is common for sintering to produce a dimensional change, typically shrinkage, where the powder compact densifies, leading to significant strengthening Microstructure coarsening is inherent to sintering, most evident as grain growth, but it is common for pore growth to occur as density increases During coarsening, the grain structure converges to a self-similar character seen in both the grain shape distribution and grain size distribution Coarsening behavior during sintering conforms to classic grain growth kinetics, modified to reflect the evolving microstructure These modifications involve the grain boundary coverage due to pores, liquid films, or second phases and the altered grain boundary mobility due to these phasesread more
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Journal ArticleDOI
Binder jet 3D printing—Process parameters, materials, properties, modeling, and challenges
Amir Mostafaei,Amy M. Elliott,John E. Barnes,Fangzhou Li,Wenda Tan,Corson L. Cramer,Peeyush Nandwana,Markus Chmielus +7 more
TL;DR: In this paper, a detailed review of the physical processes during 3D printing and the fundamental science of densification after sintering and post-heat treatment steps are provided to understand the microstructural evolution and properties of binder jetted parts.
Journal ArticleDOI
Current understanding and future research directions at the onset of the next century of sintering science and technology
TL;DR: Sintering and accompanying microstructural evolution is inarguably the most important step in the processing of ceramics and hard metals as mentioned in this paper, where an ensemble of particles is converted into a coherent object of controlled density and microstructure at an elevated temperature (but below the melting point) due to the thermodynamic tendency of the particle system to decrease its total surface and interfacial energy.
Journal ArticleDOI
A perspective on single-crystal layered oxide cathodes for lithium-ion batteries
Jayse Langdon,Arumugam Manthiram +1 more
TL;DR: In this paper, the authors review the literature on single-crystal cathode synthesis through the lens of classic grain growth theories, providing insight and hopefully accelerating the adoption of the promising single crystal cathode morphology.
Journal ArticleDOI
Effect of powder size distribution on densification and microstructural evolution of binder-jet 3D-printed alloy 625
TL;DR: The results in this article suggest that particle size distribution is a determining factor for supersolidus liquid phase sintering, pore removal and final microstructure, if printing parameters such as layer thickness, binder saturation, printhead binder droplet size and drying time are similar.
Journal ArticleDOI
Gd2Zr2O7 and Nd2Zr2O7 pyrochlore prepared by aqueous chemical synthesis
Linggen Kong,Inna Karatchevtseva,Daniel J. Gregg,Mark G. Blackford,Rohan L. Holmes,Gerry Triani +5 more
TL;DR: In this paper, pyrochlore-structured Gd2Zr2O7 is produced via complex precipitation processing, which allows the formation of dense materials at relatively low temperature, with bulk densities over 92% of the theoretical values achieved after sintering at 1400°C for 50h.
References
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Journal ArticleDOI
The kinetics of precipitation from supersaturated solid solutions
I.M. Lifshitz,V.V. Slyozov +1 more
TL;DR: In this paper, an analysis is made of the process whereby diffusion effects can cause the precipitation of grains of a second phase in a supersaturated solid solution, and the kinetics of this type of grain growth are examined in detail.
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Journal ArticleDOI
On the theory of normal and abnormal grain growth
TL;DR: In this article, a growth equation for individual grains in single-phase materials is suggested, which is used to calculate a rate equation for normal grain growth and the size distribution in the material.
Journal ArticleDOI
The Theory of Ostwald Ripening
TL;DR: In this paper, the role of elastic fields during Ostwald ripening in solid-solid mixtures is reviewed, and it is shown that these fields can play a dominant role in determining the coarsening behavior of a solid solid system.
Journal ArticleDOI
Sintering dense nanocrystalline ceramics without final-stage grain growth
I-Wei Chen,Xiaohui Wang +1 more
TL;DR: It is shown that fully dense cubic Y2O3 with a grain size of 60 nm can be prepared by a simple two-step sintering method, at temperatures of about 1,000 °C without applied pressure, and the suppression of the final-stage grain growth is achieved by exploiting the difference in kinetics between grain- boundary diffusion and grain-boundary migration.
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