Journal ArticleDOI
Controlled RAFT Polymerization in a Continuous Flow Microreactor
Christian H. Hornung,Carlos Guerrero-Sanchez,Malte Brasholz,Simon Saubern,John Chiefari,Graeme Moad,Ezio Rizzardo,San H. Thang +7 more
Reads0
Chats0
TLDR
In this paper, a series of different monomers, including acrylamides, acrylates, and vinyl acetate, were polymerized to high conversions at temperatures between 70 and 100 °C using various initiators, solvents, and RAFT agents.About:
This article is published in Organic Process Research & Development.The article was published on 2011-03-10. It has received 121 citations till now. The article focuses on the topics: Reversible addition−fragmentation chain-transfer polymerization & Chain transfer.read more
Citations
More filters
Journal ArticleDOI
50th Anniversary Perspective: RAFT Polymerization—A User Guide
TL;DR: The authors summarizes the features and limitations of reversible addition-fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and weaknesses, as our understanding of the process from both a mechanistic and an application point of view has matured over the past 20 years.
Journal ArticleDOI
Continuous flow reactors: a perspective
Charlotte Wiles,Paul Watts +1 more
TL;DR: In this paper, the development made into the application of continuous flow reactors for sustainable chemical research and production is discussed, with aspects of continuous processing featuring heavily in efforts towards increasing the green prospects of pharmaceutical and fine chemical manufacturing.
Journal ArticleDOI
Formamidinium tin-based perovskite with low Eg for photovoltaic applications
Teck Ming Koh,Thirumal Krishnamoorthy,Natalia Yantara,Chen Shi,Wei Lin Leong,Pablo P. Boix,Andrew C. Grimsdale,Subodh Mhaisalkar,Nripan Mathews +8 more
TL;DR: A lead-free low bandgap organic-inorganic hybrid perovskite, formamidinium tin iodide, is utilized as a light absorbing layer in photovoltaics.
Journal ArticleDOI
Up in the air: oxygen tolerance in controlled/living radical polymerisation
TL;DR: This review highlights several strategies for achieving oxygen tolerant CLRP including: "polymerising through" oxygen, enzyme mediated deoxygenation and the continuous regeneration of a redox-active catalyst.
Journal ArticleDOI
RAFT polymerization and some of its applications.
TL;DR: This Focus Review describes how the development of RAFT and RAFT application has been facilitated by the adoption of continuous flow techniques using tubular reactors and through the use of high-throughput methodology.
References
More filters
Journal ArticleDOI
Living radical polymerization by the RAFT process
TL;DR: A review of living radical polymerization achieved with thiocarbonylthio compounds by a mechanism of reversible addition-fragmentation chain transfer (RAFT) is presented in this article.
Journal ArticleDOI
Living Radical Polymerization by the RAFT Process - A Second Update
TL;DR: The authors provides a third update to the review of reversible deactivation radical polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC(S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005.
Journal ArticleDOI
Radical addition-fragmentation chemistry in polymer synthesis
TL;DR: In this paper, a review of the development of addition-fragmentation chain transfer agents and related ring-opening monomers highlighting recent innovation in these areas is presented, including dithioesters, trithiocarbonates, dithioco-baramates and xanthates.
Journal ArticleDOI
Chemistry in microstructured reactors.
TL;DR: This Review aims to address the lack of attention given to microstructured reaction techniques in organic chemistry by providing an overview of the chemistry in microstructures, grouped into liquid-phase, gas- phase, and gas-liquid reactions.