Crystallization of Poly (ethylene glycol) in Poly (methyl methacrylate) Networks
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In this paper, the crystallization of poly(ethylene glycol) (PEG) in poly(methyl methacrylate) (PMMA) networks was studied, which was compared with that of PEG homopolymer.Abstract:
The crystallization of poly(ethylene glycol) (PEG) in poly(methyl methacrylate) (PMMA) networks were studied, which was compared with that of PEG homopolymer. Melting point ( T m ) of PEG in PMMA networks is lower than that of pure PEG; the crystallinity and T m s of PEG in PMMA networks somewhat increase with increasing of PEG content; the cross-linker content of PMMA networks plays an important role for the crystallization of PEG. When the cross-linker content is between 3.5 wt% and 5.8 wt%, the distinct endothermic peak of PEG crystal fusion can be observed. Optical microscopic observation of the crystallized PEG in PMMA networks showed spherulite formation, indicating there was the co-continuous crystalline PEG in PMMA networks. DOI: http://dx.doi.org/10.5755/j01.ms.19.2.4430read more
Citations
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Membranes of Polymers of Intrinsic Microporosity (PIM-1) Modified by Poly(ethylene glycol)
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Ion Etching Induced Surface Patterns of Blend Polymer (Poly Ethylene Glycol – Poly Methyl Methacrylate) Irradiated with Gamma Rays
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Suitability of PEG/PMMA-based metal injection moulding feedstock: an experimental study
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Cross-linking of poly (ether-block-amide) by poly (ethylene glycol) diacrylate to prepare plasticizing-resistant CO2-selective membranes
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References
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H. D. Keith,F. J. Padden +1 more
TL;DR: In this paper, the authors analyzed the factors leading to twisting crystallographic orientation in banded polymer spherulites, both from the standpoint of qualitative morphology and of more quantitative measurement and calculation.
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Kinetics of crystallization in semicrystalline/amorphous polymer mixtures
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Xinya Lu,Robert Weiss +1 more
TL;DR: In this paper, an equation that relates the transition temperature, TE, and a binary interaction parameter, x, for miscible binary polymer blends was derived, including no adjustable parameters, based on a thermodynamic mixing formalism using enthalpy as the thermodynamic parameter.