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Journal ArticleDOI

Curing kinetics and morphology of IPNs from a flexible dimethacrylate and a rigid epoxy via sequential photo and thermal polymerization

Fei Chen, +1 more
- 01 Jun 2008 - 
- Vol. 44, Iss: 6, pp 1796-1813
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TLDR
In this paper, the curing kinetics and morphology of interpenetrating polymer networks (IPNs) formed from a rigid epoxy resin thermally cured by an anhydride, and a photocured flexible dimethacrylate resin, have been studied by temperature ramping differential scanning calorimetry (DSC), near-infrared (NIR), and dynamic mechanical thermal analyzer (DMTA).
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This article is published in European Polymer Journal.The article was published on 2008-06-01. It has received 44 citations till now. The article focuses on the topics: Curing (chemistry) & Thermosetting polymer.

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Journal ArticleDOI

State of the art in dual-curing acrylate systems

TL;DR: A survey of recent and breakthrough research in acrylate dual-curing materials for shape memory polymers, optical materials, photolithography, protective coatings, structured surface topologies, and holographic materials is finished.
Journal ArticleDOI

Delayed Gelation Through Chain-Transfer Reactions: Mechanism For Stress Reduction In Methacrylate Networks.

TL;DR: This approach does not require any modification in the bonding/photoactivation procedures, and seems promising for stress management not only in polymeric dental materials, but also for other applications of glassy, crosslinked photopolymers, as long as thiol volatility is addressed.
Journal ArticleDOI

Photochemical Production of Interpenetrating Polymer Networks; Simultaneous Initiation of Radical and Cationic Polymerization Reactions

TL;DR: In this paper, a review of the ways to produce, through photopolymerization, interpenetrating polymer networks (IPN) based on acrylate/epoxide or acrylar/vinylether blends is presented.
Journal ArticleDOI

A new approach to network heterogeneity: Polymerization Induced Phase Separation in photo-initiated, free-radical methacrylic systems.

TL;DR: This investigation utilizes purely photo-initiated, free-radical systems, broadening the scope of applications for PIPS since these processing conditions have not been studied previously.
Journal ArticleDOI

Synthesis and characterization of photosensitive benzocyclobutene‐functionalized siloxane thermosets

TL;DR: In this paper, two methylphenylsiloxane monomers with crosslinkable benzocyclobutene functionalities at the terminal positions, 1,1,5,5-dimethyldiphenyl-1,1.5, 5, 5-dimethyl-diphenynyl]-3,3, 3-dimdimethyltrisiloxane (BCB-1) and 1, 1.1, 3, 3 -dimethyl trisiloxideane (1, 1-3)-disiloxANE(BCB
References
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Thermodynamics of High Polymer Solutions

TL;DR: In this paper, a statistical treatment of high polymer solutions has been carried out on the basis of an idealized model, originally proposed by Meyer, which is analogous to the one ordinarily assumed in the derivation of the ''ideal'' solution laws for molecules of equal size.
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Mechanical Properties of Polymers and Composites

TL;DR: In this article, the authors discuss various mechanical properties of fiber-filled composites, such as elastic moduli, creep and stress relaxation, and other mechanical properties such as stress-strain behavior and strength.
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