Journal ArticleDOI
Solutions of Long Chain Compounds
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This article is published in Journal of Chemical Physics.The article was published on 1941-05-01. It has received 1502 citations till now.read more
Citations
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Journal ArticleDOI
Thermodynamics of High Polymer Solutions
TL;DR: In this paper, a statistical treatment of high polymer solutions has been carried out on the basis of an idealized model, originally proposed by Meyer, which is analogous to the one ordinarily assumed in the derivation of the ''ideal'' solution laws for molecules of equal size.
Journal ArticleDOI
Biomolecular condensates: organizers of cellular biochemistry
TL;DR: This work has shown that liquid–liquid phase separation driven by multivalent macromolecular interactions is an important organizing principle for biomolecular condensates and has proposed a physical framework for this organizing principle.
Journal ArticleDOI
Phase transitions in the assembly of multivalent signalling proteins
Pilong Li,Sudeep Banjade,Hui-Chun Cheng,Soyeon Kim,Baoyu Chen,Liang Guo,Marc C. Llaguno,Javoris Hollingsworth,David S. King,Salman F. Banani,Paul S. Russo,Qiu-Xing Jiang,B. Tracy Nixon,Michael K. Rosen +13 more
TL;DR: Interactions between diverse synthetic, multivalent macromolecules (including multi-domain proteins and RNA) produce sharp liquid–liquid-demixing phase separations, generating micrometre-sized liquid droplets in aqueous solution.
Journal ArticleDOI
Preparation and Characterization of Membranes Formed by Nonsolvent Induced Phase Separation: A Review
TL;DR: A review of nonsolvent induced phase separation membrane preparation and characterization for many commonly used membrane polymers is presented in this article, which includes membrane porosity and pore size distribution characterization, membrane physical and chemical properties characterization, and thermodynamic and kinetic evaluation of phase inversion process.
Book ChapterDOI
Energetics of protein structure.
TL;DR: This chapter summarizes the experimental information on protein energetics and investigates the correlation between thermodynamic and structural characteristics of protein, including the water-ASA of various groups in the native and unfolded states, the number of hydrogen bonds, and the extent of van der Waals contacts in thenative state.
References
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Journal ArticleDOI
An attempt to extend the statistical theory of perfect solutions
R. H. Fowler,G. S. Rushbrooke +1 more
Journal ArticleDOI
Erratum: Spectroscopic Evidence for Hydrogen Bonds: Comparison of Proton‐Attracting Properties of Liquids. IV
Walter Gordy,Spencer C. Stanford +1 more
TL;DR: In this paper, the strengths of deuterium bridges formed between heavy water and forty-two basic solvents are compared by measurements of the perturbations which the solvants produce on the OD vibrational band of heavy water which occurs at 3.59 μ in heavy water vapor and at 4.00 μ in liquid heavy water.
Journal ArticleDOI
Molekülgestalt und Solvatation
TL;DR: Das wesentlichste der vorliegenden Betrachtungen uber die Solvatation konnen wir folgendermasen zusammenfassen:
Journal ArticleDOI
A Theory of the Thermodynamic Properties of Large Molecules
TL;DR: In this article, it was shown that the theory of motion of segments provides an explanation for a variety of thermodynamic properties of linear polymers, such as the change of melting temperature with chain length, the abnormally large increase in the osmotic pressure of large linear polymer with concentration, and abnormally high vapor pressure of solvent above concentrated solutions of such polymers; and the fact that surface tension becomes independent of the molecular weight for long molecules.