Journal ArticleDOI
Designer magnets containing cyanides and nitriles.
Joel S. Miller,Jamie L. Manson +1 more
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TLDR
Three-dimensional network solids exhibiting magnetic ordering have been made from several first-row metal ions and bridging unsaturated cyanide, tricyanomethanide, and/or dicyanamide ligands, which possess several different structural motifs, and the shorter the bridge, the stronger the interaction.Abstract:
Magnets synthesized from molecules have contributed to the renaissance in the study of magnetic materials. Three-dimensional network solids exhibiting magnetic ordering have been made from several first-row metal ions and bridging unsaturated cyanide, tricyanomethanide, and/or dicyanamide ligands. These materials possess several different structural motifs, and the shorter the bridge, the stronger the interaction (i.e., C⋮N > N⋮CN ≫ N⋮CNC⋮N = N⋮CCC⋮N). Cyanide additionally has the ability to discriminate between C- and N-bonding to form ordered heterobimetallic magnets, and the strong coupling can lead to ferro- or ferrimagnetic ordering substantially above room temperature. Tricoordination of tricyanomethanide results in spin-frustrated systems, which possess interpenetrating rutile-like networks. In contrast, single rutile-like frameworks are formed by μ3-bonded dicyanamide, which leads to ferromagnetics and weak ferromagnetics.read more
Citations
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Synthesis of Heavy Dicyanamide Homologues from Air-Stable Precursors.
TL;DR: These heavy homologues of the long-known and fundamentally important dicyanamide anion were formed through the nucleophilic displacement of bis(diphenylphosphino)ethane from the pnictogen+ transfer agents [dppePn][BPh4 ] by exposure to cyanide salts.
Journal ArticleDOI
Copper‐Mediated Cyanation of Aryl C—H Bond with Removable Bidenate Auxiliary Using Acetonitrile as the Cyano Source
Journal ArticleDOI
Silica supported heteropolyacid catalyzed dehydration of aldoximes to nitriles and alcohols to alkenes
TL;DR: In this article, an expedient method of silica supported heteropolyacid (HPA) catalyzed liquid phase dehydration of aldoxime to nitrile and secondary alcohols to alkenes were developed.
Journal ArticleDOI
A base-catalyzed cycloisomerization of 5-cyano-pentyne derivatives: an efficient synthesis of 3-cyano-4,5-dihydro-1H-pyrroles.
TL;DR: A base-catalyzed cycloisomerization of 5-cyano-pentyne bearing a terminal alkyne group has been developed under metal-free conditions, providing efficient access to 3- Cyano-4,5-dihydro-1H-pyrroles in good to excellent yields in an atom-economic manner.
Journal ArticleDOI
A mixed-spin Fe(II) tetranuclear cluster: Preparation, structure and magnetic property
TL;DR: In this article, a tetranuclear cyanide-bridged ferrous cluster, 1(PF6)4, was synthesized via self-assembly via selfassembly reaction.
References
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Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2
B. F. Hoskins,Richard Robson +1 more
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A room-temperature organometallic magnet based on Prussian blue
TL;DR: In this paper, a room-temperature organometallic magnet was synthesized by combining a hexa-cyanometalate [M(CN)6]q− with a Lewis acid Lp+.
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Strongly Geometrically Frustrated Magnets
TL;DR: The study of cooperative phenomena in magnetism has provided fertile ground for testing theories of interacting systems that possess different spatial dimensions, ranges, and sign of interactions, and that exhibit local anisotropy of the basic interacting unit, the magnetic spin this paper.
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Sol−Gel Synthesis of KVII[CrIII(CN)6]·2H2O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 °C
TL;DR: In this paper, the use of sol-gel methods was described to synthesize several crystalline molecule-based magnets with the Prussian blue structure, including KV II[CrIII (CN)6]‚2H2O, with an ordering temperature of 376 K (103°C).